Corrosion of candidate materials for supercritical water-cooled reactor

Supercritical water reactor(SCWR) was proposed as a GenerationⅣconcept for building large capacity nuclear power plants.Comparing with the present GenerationⅡandⅢlight water reactors,SCWR possesses great advantages of 10%higher efficiency,simpler system design,better sustainability,and so on. However,the selection of materials for fuel cladding and reactor internals of SCWR is facing a great challenge. Corrosion in supercritical steam is of the first important issue to be solved to meet the stringent requirement of the reactor internal components.Corrosion screening tests were conducted on candidate materials for nuclear fuel cladding and reactor internals of supercritical water reactor(SCWR) in static and re-circulating autoclave at the temperatures of 550,600 and 650℃,pressure of about 25 MPa,deaerated or saturated dissolved hydrogen(STP). Nickel base alloy type Hastelloy C276,austenitic stainless steels type 304NG,AL-6XN,HR3C.NF709 and SAVE 25,ferritic/martensitic(F/M) steel type P92,P122 and 410,and oxide dispersion strengthened steel MA 956,are tested.This paper presents corrosion rate,and focuses on the formation and breakdown of corrosion oxide film,and proposes the future trend for the development of SCWR internal structure materials.

An old issue and a new challenge for nuclear reactor safety

Nuclear reactor safety(NRS)and the branch accident analysis(AA)constitute proven technologies:these are based on,among the other things,long lasting research and operational experience in the area of water cooled nuclear reactors(WCNR).Large break loss of coolant accident(LBLOCA)has been,so far,the orienting scenario within AA and a basis for the design of reactors.An incomplete vision for those technologies during the last few years is as follows:Progress in fundamentals was stagnant,namely in those countries where the WCNR were designed.Weaknesses became evident,noticeably in relation to nuclear fuel under high burn-up.Best estimate plus uncertainty(BEPU)techniques were perfected and available for application.Electronic and informatics systems were in extensive use and their impact in case of accident becomes more and more un-checked(however,quite irrelevant in case of LBLOCA).The time delay between technological discoveries and applications was becoming longer.The present paper deals with the LBLOCA that is inserted into the above context.Key conclusion is that regulations need suitable modification,rather than lowering the importance and the role of LBLOCA.Moreover,strengths of emergency core cooling system(ECCS)and containment need a tight link.