Water soluble organic carbon （WSOC） is considered the most mobile and reactive soil carbon source and its characterization is an important issue for soil ecology study. A biodegradability test was set up to study WS...Water soluble organic carbon （WSOC） is considered the most mobile and reactive soil carbon source and its characterization is an important issue for soil ecology study. A biodegradability test was set up to study WSOC extracted from 7 soils differently managed. WSOC was extracted from soil with water （soil/water ratio of 1：2, W/V） for 30 min, and then tested for biodegradability by a liquid state respirometric test. Result obtained confirmed the finding that WSOC biodegradability depended on the both land use and management practice. These results suggested the biodegradability test as suitable method to characterize WSOC, and provided useful information to soil fertility.展开更多
Water soluble organic carbon （WSOC） in sediments plays an important role in transference and transformation of aquatic pollutants. This article investigated the inherent mechanisms of how sediemnt grain size affect ...Water soluble organic carbon （WSOC） in sediments plays an important role in transference and transformation of aquatic pollutants. This article investigated the inherent mechanisms of how sediemnt grain size affect the partitioning coeffcient （k） of WSOC. Influences of NaOH extracted humic substances were particularly focused on. Sediments were sampled from two cross-sections of the middle Yellow River and sieved into three size fractions （〈 63 μm, 63-100 μm, and 100-300 μm）. The total concentration of WSOC in sediments （Cwsoc） and k were estimated using multiple water-sediment ratio experiments. Results showed that Cwsoc ranged from 0.012 to 0.022 mg/g, while k ranged from 0.8 to 3.9 L/kg. Correlations between the spectrum characteristics of NaOH extracted humic substances and k were analyzed. Strong positive correlations are determined between k and the aromaticity indicators of NaOH extracted humic substances in different sediment size fractions. Comparing with finer fractions （〈 63 μm）, k is higher in larger size fractions （63- 100 μm and 100-300 μm） related to higher aromaticity degree of NaOH extracted humic substances mostly. While negative relationship between k and the area ratio of fourier transform infrared spectroscopy （FT-IR） at 3400 and 1430 cm^-1 implied that the lowest k was related to the highest concentration of acidic humic groups in particles 〈 63 μm. WSOC in finer fractions （〈 63 μm） is likely to enter into pore water, which may further accelerate the transportation of aquatic contaminants from sediment to water.展开更多
Fluorescence excitation and average molecular weight of 46 water soluble organic matter (WSOC) samples extracted from 20 soil types in eastern China were determined. It was found all samples shared similar spectrosco...Fluorescence excitation and average molecular weight of 46 water soluble organic matter (WSOC) samples extracted from 20 soil types in eastern China were determined. It was found all samples shared similar spectroscopy. A good linear relationship existed between total organic carbon and excitation in the range of 350 to 450 nm though the content of organic carbon and pH of the samples vary in a wide range. No significant correlation between relative excitation intensity and average molecular weight of WSOC and FA was found, but the partial correlation became significant with pH as the controlling factor for WSOC samples. The relative excitation intensity showed a general trend of increasing from south to north in the study area. The pH value might play an important role in regulating the fluorescent spatial variation of WSOC. S153 A展开更多
Emissions from major agricultural residues were measured using a self-designed combustion system. Emission factors （EFs） of organic carbon （OC）, elemental carbon （EC）, and water-soluble ions （WSIs） （K＋, NH4...Emissions from major agricultural residues were measured using a self-designed combustion system. Emission factors （EFs） of organic carbon （OC）, elemental carbon （EC）, and water-soluble ions （WSIs） （K＋, NH4＋, Na＋, Mg2＋, Ca2＋, Cl-, NO3-, SO42–） in smoke from wheat and rice straw were measured under flaming and smoldering conditions. The OC1/TC （total carbon） was highest （45.8% flaming, 57.7% smoldering） among carbon fractions. The mean EFs for OC （EFOC） and EC （EFEC） were 9.2 ± 3.9 and 2.2 ± 0.7 g/kg for wheat straw and 6.4 ± 1.9 and 1.1 ± 0.3 g/kg for rice straw under flaming conditions, while they were 40.8 ± 5.6 and 5.8 ± 1.0 g/kg and 37.6 ± 6.3 and 5.0 ± 1.4 g/kg under smoldering conditions, respectively. Higher EC ratios were observed in particulate matter （PM） mass under flaming conditions. The OC and EC for the two combustion patterns were significantly correlated （p 〈 0.01, R = 0.95 for wheat straw; p 〈 0.01, R = 0.97 for rice straw）, and a higher positive correlation between OC3 and EC was observed under both combustion conditions. WSIs emitted from flaming smoke were dominated by Cl- and K＋, which contributed 3.4% and 2.4% of the PM mass for rice straw and 2.2% and 1.0% for wheat straw, respectively. The EFs of Cl- and K＋ were 0.73 ± 0.16 and 0.51 ± 0.14 g/kg for wheat straw and 0.25 ± 0.15 and 0.12 ± 0.05 g/kg for rice straw under flaming conditions, while they were 0.42 ± 0.28 and 0.12 ± 0.06 g/kg and 0.30 ± 0.27 and 0.05 ± 0.03 g/kg under smoldering conditions, respectively. Na＋, Mg2＋, and NH4＋ were vital components in PM, comprising from 0.8% （smoldering） to 3.1% （flaming） of the mass. Strong correlations of Cl- with K＋, NH4＋, and Na＋ ions were observed in rice straw and the calculated diagnostic ratios of OC/EC, K＋/Na＋ and Cl-/Na＋ could be useful to distinguishing crop straw burning from other sources of atmospheric pollution.展开更多
森林生态系统作为生物圈的重要组成部分,维持着全球植被碳库的86%和土壤碳库的40%（Houghton et al.,2001;胡会峰等,2006）。因此,森林在调节全球气候、维持全球碳平衡方面起着非常重要的作用（Fang et al.,2001;Woodbury et al.,2007;H...森林生态系统作为生物圈的重要组成部分,维持着全球植被碳库的86%和土壤碳库的40%（Houghton et al.,2001;胡会峰等,2006）。因此,森林在调节全球气候、维持全球碳平衡方面起着非常重要的作用（Fang et al.,2001;Woodbury et al.,2007;Hu et al.,2008）。然而,展开更多
文摘Water soluble organic carbon （WSOC） is considered the most mobile and reactive soil carbon source and its characterization is an important issue for soil ecology study. A biodegradability test was set up to study WSOC extracted from 7 soils differently managed. WSOC was extracted from soil with water （soil/water ratio of 1：2, W/V） for 30 min, and then tested for biodegradability by a liquid state respirometric test. Result obtained confirmed the finding that WSOC biodegradability depended on the both land use and management practice. These results suggested the biodegradability test as suitable method to characterize WSOC, and provided useful information to soil fertility.
基金supported by the Major State Basic Research Program of China (No. 2007CB407202)the National Natural Science Foundation of China (No. 40501063).
文摘Water soluble organic carbon （WSOC） in sediments plays an important role in transference and transformation of aquatic pollutants. This article investigated the inherent mechanisms of how sediemnt grain size affect the partitioning coeffcient （k） of WSOC. Influences of NaOH extracted humic substances were particularly focused on. Sediments were sampled from two cross-sections of the middle Yellow River and sieved into three size fractions （〈 63 μm, 63-100 μm, and 100-300 μm）. The total concentration of WSOC in sediments （Cwsoc） and k were estimated using multiple water-sediment ratio experiments. Results showed that Cwsoc ranged from 0.012 to 0.022 mg/g, while k ranged from 0.8 to 3.9 L/kg. Correlations between the spectrum characteristics of NaOH extracted humic substances and k were analyzed. Strong positive correlations are determined between k and the aromaticity indicators of NaOH extracted humic substances in different sediment size fractions. Comparing with finer fractions （〈 63 μm）, k is higher in larger size fractions （63- 100 μm and 100-300 μm） related to higher aromaticity degree of NaOH extracted humic substances mostly. While negative relationship between k and the area ratio of fourier transform infrared spectroscopy （FT-IR） at 3400 and 1430 cm^-1 implied that the lowest k was related to the highest concentration of acidic humic groups in particles 〈 63 μm. WSOC in finer fractions （〈 63 μm） is likely to enter into pore water, which may further accelerate the transportation of aquatic contaminants from sediment to water.
基金National Natural Science Foundation of China No. 40024101
文摘Fluorescence excitation and average molecular weight of 46 water soluble organic matter (WSOC) samples extracted from 20 soil types in eastern China were determined. It was found all samples shared similar spectroscopy. A good linear relationship existed between total organic carbon and excitation in the range of 350 to 450 nm though the content of organic carbon and pH of the samples vary in a wide range. No significant correlation between relative excitation intensity and average molecular weight of WSOC and FA was found, but the partial correlation became significant with pH as the controlling factor for WSOC samples. The relative excitation intensity showed a general trend of increasing from south to north in the study area. The pH value might play an important role in regulating the fluorescent spatial variation of WSOC. S153 A
基金This work was financially supported by the National Natural Science Foundation of China （41073019） and the Province Natural Science Foundation of Jiangsu （BK20130998）. The authors acknowledge Ke Huang, Huiyu Chen, Weizong Yang, and Jiawen Yuan for their help with the design of the combustion device, sample collection and preparation.
文摘Emissions from major agricultural residues were measured using a self-designed combustion system. Emission factors （EFs） of organic carbon （OC）, elemental carbon （EC）, and water-soluble ions （WSIs） （K＋, NH4＋, Na＋, Mg2＋, Ca2＋, Cl-, NO3-, SO42–） in smoke from wheat and rice straw were measured under flaming and smoldering conditions. The OC1/TC （total carbon） was highest （45.8% flaming, 57.7% smoldering） among carbon fractions. The mean EFs for OC （EFOC） and EC （EFEC） were 9.2 ± 3.9 and 2.2 ± 0.7 g/kg for wheat straw and 6.4 ± 1.9 and 1.1 ± 0.3 g/kg for rice straw under flaming conditions, while they were 40.8 ± 5.6 and 5.8 ± 1.0 g/kg and 37.6 ± 6.3 and 5.0 ± 1.4 g/kg under smoldering conditions, respectively. Higher EC ratios were observed in particulate matter （PM） mass under flaming conditions. The OC and EC for the two combustion patterns were significantly correlated （p 〈 0.01, R = 0.95 for wheat straw; p 〈 0.01, R = 0.97 for rice straw）, and a higher positive correlation between OC3 and EC was observed under both combustion conditions. WSIs emitted from flaming smoke were dominated by Cl- and K＋, which contributed 3.4% and 2.4% of the PM mass for rice straw and 2.2% and 1.0% for wheat straw, respectively. The EFs of Cl- and K＋ were 0.73 ± 0.16 and 0.51 ± 0.14 g/kg for wheat straw and 0.25 ± 0.15 and 0.12 ± 0.05 g/kg for rice straw under flaming conditions, while they were 0.42 ± 0.28 and 0.12 ± 0.06 g/kg and 0.30 ± 0.27 and 0.05 ± 0.03 g/kg under smoldering conditions, respectively. Na＋, Mg2＋, and NH4＋ were vital components in PM, comprising from 0.8% （smoldering） to 3.1% （flaming） of the mass. Strong correlations of Cl- with K＋, NH4＋, and Na＋ ions were observed in rice straw and the calculated diagnostic ratios of OC/EC, K＋/Na＋ and Cl-/Na＋ could be useful to distinguishing crop straw burning from other sources of atmospheric pollution.
文摘森林生态系统作为生物圈的重要组成部分,维持着全球植被碳库的86%和土壤碳库的40%（Houghton et al.,2001;胡会峰等,2006）。因此,森林在调节全球气候、维持全球碳平衡方面起着非常重要的作用（Fang et al.,2001;Woodbury et al.,2007;Hu et al.,2008）。然而,
