Effects of cloud,atmospheric water vapor,and dust on photosynthetically active radiation and total solar radiation in a Mongolian grassland

Photosynthetically active radiation （PAR） is an important input parameter for estimating plant produc- tivity due to its key role in the growth and development of plants. However, a worldwide routine network for sys- tematic PAR measurements is not yet established, and PAR is often calculated as a constant fraction of total solar radiation （SR）. Although the ratio of PAR to SR （PAR/SR） has been reported from many places, few studies have been performed for dry regions. The present study was therefore carried out in an arid region of Mongolia to obtain PAP-JSR and examine its dependency on sky clearness （the clearness index）, water vapor in the atmosphere and aeolian dust. Continuous measurements of PAR and SR were taken every one second using quantum and pyranometer sensors, respectively, and the readings were averaged and recorded at intervals of 30 minutes for a period of 12 months. The lowest monthly mean daily PAR/SR occurred in April （0.420）, while the highest ratio was observed in July （0.459）. Mean daily PAR/SR during plant growing season （May-August） was estimated to be 0.442, which could be useful for modeling plant productivity in the study area. The annual mean daily PAR/SR （0.435） was lower than the values reported in many previous studies. This difference could be explained with the regional variation in climate： i.e. drier climatic condition in the study area. PAR/SR was negatively correlated with the clearness index （r= -0.36, P〈0.001）, but positively with atmospheric water vapor pressure （r=0.47, P〈0.001）. The average PAR/SR was significantly lower （P=0.02） on the dusty days compared to the non-dust days. Water vapor in the atmosphere was shown to be the strongest factor in the variation of PAR/SR. This is the first study examining PAR/SR under a semi-arid condition in Mongolia.

Dispersion hydrophobic electrolyte enables lithium-oxygen battery enduring saturated water vapor

Li-O_(2) batteries gain widespread attention as a can didate for next-generati on energy storage devices due to their extraordinary theoretic specific energy.The semi-open structure of Li-O_(2) batteries causes many parasitic reactions,especially related to water.Water is a double-edged sword,which destroys Li anode and simultaneously triggers a solution-based pathway of the discharge product.In this work,hexamethyldisilazane(HMDS)is introduced into the electrolyte of an aprotic Li-O_(2) battery.HMDS has a strong ability to combine with a trace of water to gen erate a hydrophobic hexamethyldisiloxa ne(MM),which eliminates water from the electrolyte decomposition and then prevents the Li anode from producing the insulating LiOH with water.In this case,the hydrophobic MM disperses in the ether-based electrolyte,forming a dispersion hydrophobic electrolyte.This electrolyte can anchor water from the environment on the cathode side,which triggers a solution-based pathway and regulates the growth morphology of the discharge product and consequently increases the discharge capacity.Compared with the Li-O_(2) battery without the HMDS,the HMDS-containing Li-O_(2) battery contributes an about 13-fold increase of cyclability(400 cycles,1800 h)in the extreme environment of saturated water vapor.This work opens a new approach for directly operating aprotic Li-O_(2) batteries in ambient air.

Interactive response of photosynthetic characteristics in Haloxylon ammodendron and Hedysarum scoparium exposed to soil water and air vapor pressure deficits

C4 plants possess better drought tolerance than C3 plants. However, Hedysarum scoparium, a C3 species, is dominant and widely distributed in the desert areas of northwestern China due to its strong drought tolerance. This study compared it with Haloxylon ammodendron, a C4 species, regarding the interactive effects of drought stress and different leaf–air vapor pressure deficits. Variables of interest included gas exchange, the activity levels of key C4 photosynthetic enzymes, and cellular anatomy. In both species, gas exchange parameters were more sensitive to high vapor pressure deficit than to strong water stress, and the net CO2 assimilation rate（A n） was enhanced as vapor pressure deficits increased. A close relationship between A n and stomatal conductance（g s） suggested that the species shared a similar response mechanism. In H. ammodendron, the activity levels of key C4 enzymes were higher, including those of phosphoenolpyruvate carboxylase（PEPC） and nicotinamide adenine dinucleotide phosphate-malate enzyme（NADP-ME）, whereas in H. scoparium, the activity level of nicotinamide adenine dinucleotide-malate enzyme（NAD-ME） was higher.Meanwhile, H. scoparium utilized adaptive structural features, including a larger relative vessel area and a shorter distance from vein to stomata, which facilitated the movement of water. These findings implied that some C4 biochemical pathways were present in H. scoparium to respond to environmental challenges.

Gas exchange of Populus euphratica leaves in a riparian zone

Riparian vegetation belts in arid regions of Central Asia are endangered to lose their ecosystem services due to intensified land use.For the development of sustained land use,management knowledge of plant performance in relation to resource supply is needed.We estimated productivity related functional traits at the edges of the habitat of Populus euphratica Oliv.Specific leaf area （SLA） and carbon/nitrogen （C/N） ratio of P.euphratica leaves growing near a former river bank and close to moving sand dunes in the Ebinur Lake National Nature Reserve in Xinjiang,Northwest China （near Kazakhstan） were determined and daily courses of CO2 net assimilation （PN）,transpiration （E）,and stomatal conductance （gs） of two consecutive seasons were measured during July-August 2007 and June-July 2008.Groundwater level was high （1.5-2.5 m below ground） throughout the years and no flooding occurred at the two tree stands.SLA was slightly lower near the desert than at the former river bank and leaves contained less N in relation to C.Highest E and gs of P.euphratica were reached in the morning before noon on both stands and a second low maximum occurred in the afternoon despite of the unchanged high levels of air to leaf water vapor pressure deficit （ALVPD）.Decline of gs in P.euphratica was followed by decrease of E.Water use efficiency （WUE） of leaves near the desert were higher in the morning and the evening,in contrast to leaves from the former river bank that maintained an almost stable level throughout the day.High light compensation points and high light saturation levels of PN indicated the characteristics of leaves well-adapted to intensive irradiation at both stands.In general,leaves of P.euphratica decreased their gs beyond 20 Pa/kPa ALVPD in order to limit water losses.Decrease of E did not occur in both stands until 40 Pa/kPa ALVPD was reached.Full stomatal closure of P.euphratica was achieved at 60 Pa/kPa ALVPD in both stands.E through the leaf surface amounted up to 30％ of the highest E rates,indicating dependence on water recharge from the ground despite of obviously closed stomata.A distinct leaf surface temperature （Tleaf） threshold of around 30℃ also existed before stomata started to close.Generally,the differences in gas exchange between both stands were small,which led to the conclusion that micro-climatic constraints to E and photosynthesis were not the major factors for declining tree density with increasing distance from the river.

Analysis of Precipitation Resource and Weather Modification Potential in Anyang

Using ground water vapor pressure and precipitation data at four times of one day during 1985- 2014 in each county（ city） of Anyang,precipitable water at each station was calculated,and temporal-spatial distribution of atmospheric maximum precipitable water and its change trend over the years in the city were analyzed. Results showed that atmospheric maximum precipitable water in Anyang City had the characteristics of summer far more than winter,autumn slightly higher than spring,west and south more,and east and north less,and presented the increasing trend year by year. We further analyzed the characteristic of monthly rainfall enhancement potential in each county,and mean in whole year was 80%. In spring and winter,rainfall enhancement potential in the west was bigger than east,while rainfall enhancement potential in the east was bigger than west in summer and autumn. The research provides reference basis for rationally carrying out artificial rainfall work,which could effectively ease uneven temporal-spatial distribution problem of water resource in Anyang City.

Selective Dealumination of ZSM-5 by Hydrothermal Treatment

We studied the factors affecting the framework aluminium distribution in the ZSM-5 structure by hydrothermal treatment under different conditions. (27)AlMASNMR, XPS and chemical analysis revealed that with steaming at lower water vapor pressure, the framework aluminium located at the external surface is less stable. Steaming at higher water vapor pressure is beneficial in removing the framework Al in HZSM-5, and especially helpful in removing that located at the internal surface of HZSM-5. By changing steaming conditions, one may control the framework aluminium distribution in the HZSM-5 structure.