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Membrane Separation Technology on Pharmaceutical Wastewater by Using MBR (Membrane Bioreactor) 被引量:6
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作者 Saima Fazal Beiping Zhang +2 位作者 Zhengxing Zhong Lan Gao Xiejuan Lu 《Journal of Environmental Protection》 2015年第4期299-307,共9页
This study demonstrated the feasibility of implementing of MBR in pharmaceutical wastewater independently, and concluded different applications of MBR in industries. Membrane bioreactor (MBR) technology was a new wast... This study demonstrated the feasibility of implementing of MBR in pharmaceutical wastewater independently, and concluded different applications of MBR in industries. Membrane bioreactor (MBR) technology was a new wastewater treatment technology with a combination of membrane separation technology and biological treatment technology, which had unique advantages on pharmaceutical wastewater treatment. The modified membrane rector design provided a significantly lower concentration of NH3-N, Phosphorous, Total Nitrogen and COD around the membranes, and subsequently a more sustainable membrane performance due to much lower overall fouling rates. In this paper, the classification and structure of biological waste water treatment by using MBR technology were summed up along with some examples of MBR in industrial wastewater treatment, which was emphatically analyzed and discussed. Finally, the prospect of MBR in industrial wastewater treatment was described. The industrial wastewater was a high-strength wastewater which had characteristics of complicated constituents, high organics concentration, highly toxic. 展开更多
关键词 MEMBRANE BIOREACTOR PHARMACEUTICAL WASTEWATER MEMBRANE separation technology
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Breakthrough in the China's Separation Technology for Extraction of Rare Earth Elements
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作者 HAO Ziguo FEI Hongcai +1 位作者 LIU Lian Susan TURNER 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2013年第6期1743-1744,共2页
Separation technology of rare earth elements (REEs), as the critical step in the separation process, had long been fraught with technical difficulty. A research project conducted by Baotou Shibo Rare Earth Extracti... Separation technology of rare earth elements (REEs), as the critical step in the separation process, had long been fraught with technical difficulty. A research project conducted by Baotou Shibo Rare Earth Extraction & Equipment Co. Ltd., Baotou REE Research Institute, and Baotou Steel & REE Group Hi-Tech Co. Ltd (Inner Mongolia), has successfully solved the problem using a centrifugal extractor and advanced techniques to achieve a key breakthrough. 展开更多
关键词 LINE Breakthrough in the China’s separation technology for Extraction of Rare Earth Elements REE
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New Technology “Flotation to Form Agglomerates and Magnetic Separation” Allows Great Breakthrough for World Low-Grade Light Rare Earth Ores
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作者 HAO Ziguo FEI Hongcai +1 位作者 HAO Qingqing LIU Lian 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2015年第5期1764-1765,共2页
Rare earth resources are relatively scarce worldwide, but their global consumption is increasing year-by-year. At present, China has about 36% of the global rare earth reserves, but provides 90% of the world's supply... Rare earth resources are relatively scarce worldwide, but their global consumption is increasing year-by-year. At present, China has about 36% of the global rare earth reserves, but provides 90% of the world's supply, which has generally met world demand and promoted the development of the world economy. In order to continuously and stably supply rare earths to international markets, the Chinese Government has financially supported the Institute of Multipurpose Utilization of Mineral Resources within the China Geological Survey to study the utilization of low-grade rare earth ores. Following many years of experimental research, the project has developed a new technology entitled "Flotation to Form Agglomerates and then Magnetic Separation", which will bring a technological revolution to the world's light rare earth ore dressing. 展开更多
关键词 FORM Flotation to Form Agglomerates and Magnetic separation New technology Allows Great Breakthrough for World Low-Grade Light Rare Earth Ores
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Separation Technology of the World's Only Chambersite Deposit Has Achieved A Big Breakthrough
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作者 HAO Ziguo FEI Hongcai +1 位作者 HAO Qingqing LIU Lian 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2015年第5期1762-1763,共2页
Chambersite is a rare mineral worldwide, a manganese chloride borate (Mn3BTO13C1), which was first discovered in the recovered brine from a salt dome at Chambers, Texas, USA. This rare mineral has been proven to hav... Chambersite is a rare mineral worldwide, a manganese chloride borate (Mn3BTO13C1), which was first discovered in the recovered brine from a salt dome at Chambers, Texas, USA. This rare mineral has been proven to have a great utilization value in anti-nuclear radiation, high- temperature friction materials, medicine and stealth materials, and can be used in aerospace and aviation fields. China has the world's only mineable chambersite deposit in Jixian County, Tianjin. 展开更多
关键词 In separation technology of the World’s Only Chambersite Deposit Has Achieved A Big Breakthrough
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Capillary Zone Electrophoretic Separation of Basic Proteins with Coated Columns Prepared by Sol-Gel Technology
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作者 Fang LI Hui JIN +2 位作者 Ruo Nong FU Jun Ling GU Guang Ju LU(Department of Chemical Engineering & Materials Science, Beijing Institute of Technology, Beijing 100081) 《Chinese Chemical Letters》 SCIE CAS CSCD 1997年第9期793-796,共4页
Coated capillary columns were prepared by sol-gel technology and used in the separation of basic proteins with capillary zone electrophoresis. The results indicated that a significant decrease in protein adsorption wa... Coated capillary columns were prepared by sol-gel technology and used in the separation of basic proteins with capillary zone electrophoresis. The results indicated that a significant decrease in protein adsorption was obtained and EOF was also diminished to zero in the pH range of 3-10. 展开更多
关键词 Basic Capillary Zone Electrophoretic separation of Basic Proteins with Coated Columns Prepared by Sol-Gel technology
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Application and Regulation of Legal Science and Technology on the Pilot Program of the Reform of Separation between Complicated Cases and Simple Ones in Civil Procedure in the Basic People’s Courts
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作者 Yang Hui Xu Yifei 《Contemporary Social Sciences》 2021年第5期68-82,共15页
Blockchain,artificial intelligence,and other technologies have been increasingly integrated with the law,and the construction of smart justice and Internet courts in various places has a prominent effect on court info... Blockchain,artificial intelligence,and other technologies have been increasingly integrated with the law,and the construction of smart justice and Internet courts in various places has a prominent effect on court informatization.The Supreme People’s Court is currently carrying out the pilot reform of separation between complicated and simple cases in civil procedure,and legal technology will inevitably become a major means to enable the reform.In the field of electronic litigation,legal technology itself has become a goal of the reform.Regarding the trials of pilot basic courts,legal technology has been more deeply applied in many links such as trial activities and trial management,playing an essential role in improving judicial efficiency,and becoming an important way to solve judicial dilemmas such as“litigation explosion.”However,the history of modern society reminds us that we should be reasonably optimistic about the development of technology,especially in the field of justice. 展开更多
关键词 legal science and technology the basic court civil litigation separation between complicated and simple cases in civil procedure
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Separation Technologies of Potassium from Salt Lakes 被引量:2
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作者 SHA Zuoliang LI Jibin +1 位作者 WANG Yanfei YUAN Jianjun 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2014年第S1期367-368,共2页
1 Introduction Salt Lake,as a kind of chemical resources,has been attracted to many researchers,especially the resources of lithium.As reported,many kinds of brines exist in the world depending on the compositions of ... 1 Introduction Salt Lake,as a kind of chemical resources,has been attracted to many researchers,especially the resources of lithium.As reported,many kinds of brines exist in the world depending on the compositions of the brine.Based on the chemical composition the brines can be classified as the types of chloride,carbonate,sulfate.For different 展开更多
关键词 separation technologies of Potassium from Salt Lakes CL SO
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Advances in Researches of Extraction, Separation, and Purification Technologies for Total Saponins of Panax notoginseng
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作者 Hongyi CHEN Changmin GAN Yunqi GONG 《Medicinal Plant》 CAS 2019年第4期1-4,共4页
Total saponins of Panax notoginseng have the functions of promoting blood circulation and removing phlegm, thus they have high medicinal value. There are many different extraction methods in the extraction and separat... Total saponins of Panax notoginseng have the functions of promoting blood circulation and removing phlegm, thus they have high medicinal value. There are many different extraction methods in the extraction and separation of total saponins of P. notoginseng . The extraction methods of total saponins of P. notoginseng are mainly divided into traditional extraction methods, modern extraction methods and compound extraction methods. 展开更多
关键词 Total SAPONINS of PANAX notoginseng separation and PURIFICATION technologIES EXTRACTION technologIES
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A water-fat separation imaging method for the brain on low field magnetic resonance imaging
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作者 Hong-jun Tian1,Si-ping Chen2,Tian-fu Wang2,Xian-fen Diao2,Chong-xun Zheng1 1.Key Laboratory of Biomedical Information Engineering of Education Ministry,Xi’an Jiaotong University,Xi’an 710049 2.College of Information Engineering,Shenzhen University,Shenzhen 518060,China 《Journal of Pharmaceutical Analysis》 SCIE CAS 2009年第4期272-276,共5页
Water-fat separation is a particularly important problem for magnetic resonance imaging.Although many methods have been proposed,the reliability is still challenging.In this work,we have presented a method based on th... Water-fat separation is a particularly important problem for magnetic resonance imaging.Although many methods have been proposed,the reliability is still challenging.In this work,we have presented a method based on the combination of the branch-cut method and multigrid algorithm to get a more robust performance of water-fat separation.First,the branch-cut method is applied to identify residues,which violates the requirement that the interacting phase gradient around a closed path be zero.Residues and branches are marked to be zeros and filled to the weighting factor array.Then,the unwrapped phase array can be given by the multigrid algorithm.Finally,the Dixon method for water-fat separation is applied to the unwrapped phase array.Experiments for brain scanning on the 0.3T low field MRI system demonstrate the successful application of the proposed method. 展开更多
关键词 water-fat separation DIXON weighted multigrid unwrapping
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Analysis on the Distribution of Main Physicochemical Parameters of Color Wheat and Study on its Layering Milling Technology
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作者 陈志成 《Agricultural Science & Technology》 CAS 2012年第4期766-770,882,共6页
[Objective] The aim was to promote color wheat industrialization and meet the demand of people on nutritious grain, making both natural and safe food possible. [Method] Hardness indices of wheat were measured and laye... [Objective] The aim was to promote color wheat industrialization and meet the demand of people on nutritious grain, making both natural and safe food possible. [Method] Hardness indices of wheat were measured and layering peeling and milling technology was adopted to explore nutrients distribution in color wheat and effect of hardness on milling of wheat layers. [Result] The results indicated that total content of amino acid in color wheat was higher than that of common wheat by 13.91%-23.32%; Zhongpu Black 1 and Zhongpu Green 1 exceeded common wheat in Zn, Fe and Ca, but Zhongpu Purple 1 was generally lower; Zhongpu Green 1 was significantly higher in Fe and Ca by 371.80% and 102.86%, respectively. Mean- while, it was found that nutrients distribution of color wheat was similar to that of common ,one, namely, pericarp, testa, aleurone layer and embryo were abundant with nutrients. In addition, color wheat was concluded nutritious one and milling in- dustrialization of wheat layers could be achieved through layer-milling and separation technology. Furthermore, wheat hardness was proved the key element influencing milling of wheat layers. [Conclusion] The research set an example for nutrition development and utilization of color wheat. 展开更多
关键词 Aleurone layer separation technology PEEL TESTA NUTRITION
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Conventional processes and membrane technology for carbon dioxide removal from natural gas:A review 被引量:19
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作者 Zee Ying Yeo Thiam Leng Chew +1 位作者 Abdul Rahman Mohamed Siang-Piao Chai 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2012年第3期282-298,共17页
Membrane technology is becoming more important for CO,_ separation from natural gas in the new era due to its process simplicity, relative ease of operation and control, compact, and easy to scale up as compared with ... Membrane technology is becoming more important for CO,_ separation from natural gas in the new era due to its process simplicity, relative ease of operation and control, compact, and easy to scale up as compared with conventional processes. Conventional processes such as absorption and adsorption for CO2 separation from natural gas are generally more energy demanding and costly for both operation and maintenance. Polymeric membranes are the current commercial membranes used for CO2 separation from natural gas. However, polymeric membranes possess drawbacks such as low permeability and selectivity, plasticization at high temperatures, as well as insufficient thermal and chemical stability. The shortcomings of commercial polymeric membranes have motivated researchers to opt for other alternatives, especially inorganic membranes due to their higher thermal stability, good chemical resistance to solvents, high mechanical strength and long lifetime. Surface modifications can be utilized in inorganic membranes to further enhance the selectivity, permeability or catalytic activities of the membrane. This paper is to provide a comprehensive review on gas separation, comparing membrane technology with other conventional methods of recovering CO2 from natural gas, challenges of current commercial polymeric membranes and inorganic membranes for CO2 removal and membrane surface modification for improved selectivity. 展开更多
关键词 membrane technology inorganic membrane CO2 separation natural gas: surface modification
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A review of intelligent ore sorting technology and equipment development 被引量:7
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作者 Xianping Luo Kunzhong He +2 位作者 Yan Zhang Pengyu He Yongbing Zhang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2022年第9期1647-1655,共9页
Under the background of increasingly scarce ore worldwide and increasingly fierce market competition,developing the mining industry could be strongly restricted.Intelligent ore sorting equipment not only improves ore ... Under the background of increasingly scarce ore worldwide and increasingly fierce market competition,developing the mining industry could be strongly restricted.Intelligent ore sorting equipment not only improves ore use and enhances the economic benefits of enterprises but also increases the ore grade and lessens the grinding cost and tailings production.However,long-term research on intelligent ore sorting equipment found that the factors affecting sorting efficiency mainly include ore information identification technology,equipment sorting actuator,and information processing algorithm.The high precision,strong anti-interference capability,and high speed of these factors guarantee the separation efficiency of intelligent ore sorting equipment.Color ore sorter,X-ray ore transmission sorter,dual-energy X-ray transmission ore sorter,X-ray fluorescence ore sorter,and near-infrared ore sorter have been successfully developed in accordance with the different characteristics of minerals while ensuring the accuracy of equipment sorting and improving the equipment sorting efficiency.With the continuous improvement of mine automation level,the application of online element rapid analysis technology with high speed,high precision,and strong anti-interference capability in intelligent ore sorting equipment will become an inevitable trend of equipment development in the future.Laser-induced breakdown spectroscopy,transientγneutron activation analysis,online Fourier transform infrared spectroscopy,and nuclear magnetic resonance techniques will promote the development of ore sorting equipment.In addition,the improvement and joint application of additional high-speed and high-precision operation algorithms(such as peak area,principal component analysis,artificial neural network,partial least squares,and Monte Carlo library least squares methods)are an essential part of the development of intelligent ore sorting equipment in the future. 展开更多
关键词 intelligent ore sorting technology sorting equipment separation efficiency online element rapid analysis technology
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Sprayed separation membranes: A systematic review and prospective opportunities 被引量:2
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作者 Guangjin Zhao Wenjing Han +4 位作者 Liangliang Dong Hongwei Fan Zhou Qu Jiahui Gu Hong Meng 《Green Energy & Environment》 SCIE EI CSCD 2022年第6期1143-1160,共18页
Membrane separation technology has been taken up for use in diverse applications such as water treatment,pharmaceutical,petroleum,and energy-related industries.Compared with the design of membrane materials,the innova... Membrane separation technology has been taken up for use in diverse applications such as water treatment,pharmaceutical,petroleum,and energy-related industries.Compared with the design of membrane materials,the innovation of membrane preparation technique is more urgent for the development of membrane separation technology,because it not only affects physicochemical properties and separation performance of the fabricated membranes,but also determines their potential in industrialized application.Among the various membrane preparation methods,spray technique has recently gained increasing attention because of its low cost,rapidity,scalability,minimum of environmental burden,and viability for nearly unlimited range of materials.In this Review article,we summarized and discussed the recent developments in separation membranes using the spray technique,including the fundamentals,important features and applications.The present challenges and future considerations have been touched to provide inspired insights for developing the sprayed separation membranes. 展开更多
关键词 Membrane separation technology Membrane preparation technique Spray technique SCALABILITY Industrialized application
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Pressure characteristics of a hydrocyclone for fine particle separation 被引量:1
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作者 赵立新 蒋明虎 +2 位作者 孙德智 BELAIDI A THEW M 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2006年第3期294-298,共5页
Solid-liquid hydrocyclones are mainly used to separate large particles, such as the particles of drilling fluid in petroleum industry, and large mineral particles. Till now the hydrocyclonic separation for fine partic... Solid-liquid hydrocyclones are mainly used to separate large particles, such as the particles of drilling fluid in petroleum industry, and large mineral particles. Till now the hydrocyclonic separation for fine particles is still a big problem. Basic separation principle of hydrocyclones and experimental research facility are simply introduced. The difficulty of separating fine particle is analyzed. Based on a solid-liquid hydrocyclone used for separating fine particles, relationships of dimensionless pressure characteristic parameters, i.e. Euler number and pressure drop ratio, with several main dimensionless parameters, such as split ratio, swirl number and gas-liquid ratio, were experimentally studied in detail. The research was carried out by using the hydrocyclonic separation experimental rig at the University of Bradford. It is shown that the less the size of particle, the less the value of radius of the balance orbit occupied by the particle, and then the more difficult for the particle to be separated. Experiments indicate that Euler number of the tested hydrocyclone increases with the rise of Reynolds number, split ratio, swirl number and gas-liquid ratio respectively, and the pressure drop ratio falls with the increase of Reynolds number, split ratio and swirl number respectively. It is concluded that the most effective way to decrease the unit energy dissipation of hydrocyclone is to reduce swirl number or gas-liquid ratio of the mixed media. 展开更多
关键词 water treatment separation technology HYDROCYCLONE PRESSURE
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The effects of science,technology,society,environment(STSE)interactions on teaching chemistry 被引量:2
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作者 Nuray Yoruk Inci Morgil Nilgun Secken 《Natural Science》 2010年第12期1417-1424,共8页
This study aimed to investigate the effects of making Science, Technology, Society and En-vironment relations on students’ comprehen-sion of chemistry topics through teaching che-mistry using STSE approach at seconda... This study aimed to investigate the effects of making Science, Technology, Society and En-vironment relations on students’ comprehen-sion of chemistry topics through teaching che-mistry using STSE approach at secondary level. The study made use of the research model where pre and post tests were administered to control and treatment groups. The Chemistry Achievement Test (CAT) was used in the study. The sampling consisted of Grade 9 students studying at Anatolian High School and Voca-tional High School. Since the sampling had not been equated, in order to determine students’ logical and spatial thinking skills, they were administered Logical Thinking Skill Test and Mental Rotation test as pretests. Students were chosen randomly to take part in two control and two treatment groups. This experimental study was applied to the treatment group in teaching of “Separation of Mixtures” topic in Grade 9 Chemistry course during a four-week period. Students in the control group were taught through the traditional teaching methods. The data obtained were analyzed through the SPSS Software. As a result of the study, statistically significant increases were observed in the achievement levels of treatment group which received instruction using STSE relations. The change observed in the achievement levels of the control group was not statistically signifi-cant. The difference between the achievement levels of control and treatment groups in the posttests were favoring the treatment groups. 展开更多
关键词 SCIENCE technology SOCIETY Environment(STSE) Chemistry Education separation of Mixtures
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Simulation and heat exchanger network designs for a novel single-column cryogenic air separation process
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作者 Quancong Zhang Zuqian Wu +2 位作者 Zhikai Cao Qingyin Jiang Hua Zhou 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2019年第7期1498-1509,共12页
To realize the industrialization of the novel single-column air separation process proposed in previous work,steady-state simulation for four different configurations of the single-column process with ternary(nitrogen... To realize the industrialization of the novel single-column air separation process proposed in previous work,steady-state simulation for four different configurations of the single-column process with ternary(nitrogen,oxygen and argon)is developed.Then,exergy analysis of the single-column processes is also carried out and compared with the conventional double-column air separation process at the same capacity.Furthermore,based on the steady-state simulation of single-column processes,the different heat exchanger networks(HENs)for the main heat exchanger and subcooler in each process are designed.To obtain better performance for this novel process,optimization of process configuration and operation is investigated.The optimal condition and configuration for this process is consisted as:feedstock is divided into two streams and the reflux nitrogen is compressed at the approximate temperature of 301 K.In addition,HEN is optimized to minimize the utilities.HENs without utilities are obtained for the four different configurations of single-column process.Furthermore,capital costs of the HEN for different cases are estimated and compared. 展开更多
关键词 CRYOGENIC air separation Single-column Exergy PINCH technology Heat exchange network
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Processing, Recovery and Analysis of Precious Metals Using Molecular Recogntion Technology
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作者 IZATT Steven R. BRUENING Ronald L. IZATT Nell E. 《贵金属》 CAS CSCD 北大核心 2012年第A01期88-95,共8页
IBC Advanced Technologies' Molecular Recognition Technology(MRT) products,trade named SuperLig,selectively and rapidly bind with target metal ions to remove them from solution.The MRT process can produce a high pu... IBC Advanced Technologies' Molecular Recognition Technology(MRT) products,trade named SuperLig,selectively and rapidly bind with target metal ions to remove them from solution.The MRT process can produce a high purity separation product of maximum added value at low cost.In this paper,applications of MRT in the precious metals industry,including selective commercial separations involving Au,Pd,Pt,Rh,and Ru,are described and discussed.Application of MRT to the analytical determination of precious metals is presented.Potential use of MRT in recovering precious metals from end-of-life(EOL) products is discussed. 展开更多
关键词 selective metal separations molecular recognition technology metal recovery from waste electronics PALLADIUM PLATINUM RHODIUM RUTHENIUM gold analytical determinations
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Development of Combined Biological Technology for Treatment of High-strength Organic Wastewater and Results of Case Studies
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作者 REN Nanqi WANG Aijie HAN Hongjun MA Fang DING Jie SHI Yue ZHAO Dan 《Journal of Ocean University of China》 SCIE CAS 2006年第4期311-316,共6页
Our study group has developed a unique combined ters from the industries of dyestuff, pharmaceutical, chemical biological technology to treat high-strength organic wastewaengineering and zymolysis by using the princip... Our study group has developed a unique combined ters from the industries of dyestuff, pharmaceutical, chemical biological technology to treat high-strength organic wastewaengineering and zymolysis by using the principles of anaerobic ecological niche and bio-phase separation. The study obtained five national invention patents and eight patent equipments. This technology contains four kernel processes - two-phase anaerobic-aerobic process, hydrolysis-acidification-oxidation process, UASBAF-oxidation process, and internal cycling-hydrolysis-oxidation process. Fifteen pilot projects were accomplished in the basins of Tai Lake, Huai River, Liao River and Songhua River, and their total capital investment reached 185.214 million Yuan (RMB). Compared to conventional wastewater treatment technology, the innovative technology is more costeffective for high-strength organic wastewater treatment, can save capital investment by 15% - 30%, lessen land usage by 20% to 40% and decrease the operating cost by 10% to 25%. The operating cost of treatment per cubic meter industrial wastewater could be below 0.6 to 1.4 Yuan (RMB). 展开更多
关键词 bio-phase separation combined biological technology high-strength organic wastewater pilot plant
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钽铌清洁冶金与纯化技术研究进展与探讨
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作者 韩桂洪 孙虎 +1 位作者 车玉思 何季麟 《有色金属(冶炼部分)》 CAS 北大核心 2024年第11期5-18,共14页
钽铌是至关重要的战略性金属。随着高端制造业对先进材料的需求不断增加,以及绿色发展理念的深刻践行,产品纯化精制和过程清洁循环已成为钽铌湿法冶金的重要转型目标。本文概述了我国钽铌原生资源及二次资源的特点与利用现状,系统介绍... 钽铌是至关重要的战略性金属。随着高端制造业对先进材料的需求不断增加,以及绿色发展理念的深刻践行,产品纯化精制和过程清洁循环已成为钽铌湿法冶金的重要转型目标。本文概述了我国钽铌原生资源及二次资源的特点与利用现状,系统介绍了钽铌原料绿色分解技术、钽铌溶液分离与纯化技术、钽铌冶金废水增值利用技术的新进展,结合工业实际对比分析了各技术优缺点,并从资源保障、技术发展方向及污染物全面治理等方面提出了展望和建议,以期为钽铌冶金工业的可持续高质量发展提供支持。 展开更多
关键词 湿法冶金 分离纯化 清洁技术 研究进展
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印迹壳聚糖吸附剂对镍离子的选择性吸附行为研究
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作者 郭娜 赵莹 +1 位作者 李浩然 廖兵 《安全与环境学报》 CAS CSCD 北大核心 2024年第8期3235-3242,共8页
为了有效分离软锰矿浸出液的镍离子,研究采用离子印迹技术,以壳聚糖为基体,制备了镍印迹壳聚糖珠体(Ni2+-imprinted Chitosan Beads, Ni-CTS)。采用傅里叶变换红外光谱(Fourier Transform Infrared Spectroscopy, FT-IR)对Ni-CTS进行了... 为了有效分离软锰矿浸出液的镍离子,研究采用离子印迹技术,以壳聚糖为基体,制备了镍印迹壳聚糖珠体(Ni2+-imprinted Chitosan Beads, Ni-CTS)。采用傅里叶变换红外光谱(Fourier Transform Infrared Spectroscopy, FT-IR)对Ni-CTS进行了表征,考察了不同锰离子质量浓度背景及实际软锰矿浸出液中Ni-CTS对镍离子的选择性分离效果,以乙二胺四乙酸二钠(Ethylene Diamine Tetra-acetic Acid, EDTA)为解吸液对吸附剂的再生性能进行了研究。试验结果显示:在高质量浓度锰离子背景下,Ni-CTS对镍离子显示了较高的选择性,且先被吸附的锰离子会被后面吸附的镍离子取代,在Ni-CTS上存在对镍离子特异性吸附的活性位点。经过5次再生试验后,Ni-CTS对镍离子吸附质量比约为12.1 mg/g,仍表现出良好的吸附性能。在实际软锰矿浸出液中,吸附反应后浸出液中的锰镍质量浓度的比值由3 020提高到了8 635。 展开更多
关键词 环境工程学 离子印迹技术 壳聚糖 选择性分离 软锰矿浸出液
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