Impacts of Water-Sediment Regulation Scheme on Chromophoric Dissolved Organic Matter in the Lower Yellow River

As a river with more than 3000 reservoirs in its watershed,the Yellow River has been affected by dams not only on the sediment load,but also on the water quality.Water-sediment regulation scheme(WSRS),which has been carried out annually in the Yellow River since 2002,is a typical human activity affecting river water quality.Chromophoric dissolved organic matter(CDOM)in river is susceptible to changes in ecological and environmental conditions as well as human activities.Here,we report variations in dissolved organic carbon concentrations,compositions and sources of CDOM in time series samples in the lower Yellow River during WSRS.In addition,a parallel factor fluorescence analysis(PARAFAC)method is applied to identify different fluorescent components in water samples during WRSR,showing four major components including tryptophan-like component(C1),microbial humic-like component(C2),terrestrial humic-like component(C3)and tyrosine-like component(C4).In general,C1 increased after water regulation,while C2 and C3 increased after sediment regulation,indicating that the water and sediment released by the dam have different effects on CDOM compositions.Under the impacts of the dam,source of CDOM in the lower Yellow River is mainly autochthonous related to microbial activities,and is regulated by the terrestrial input during WSRS period.Sediment resuspension inhibits microbial activities and reduces the production of autochthonous CDOM.Overall,human activities especially WSRS,as exemplified here,significantly alter the quality and quantity of CDOM in the lower Yellow River,affecting CDOM dynamics and biogeochemical processes in the estuarine environment.

Effect of water-sediment regulation and its impact on coastline and suspended sediment concentration in Yellow River Estuary

Implementation of the water-sediment regulation(WSR) scheme, mainly focused on solving the sedimentation problems of reservoirs and the lower reaches of the Yellow River, has inevitably influenced the sediment distribution and coastal morphology of the Yellow River Estuary.Using coastline delineation and suspended sediment concentration(SSC) retrieval methods, this study investigated water and sediment changes,identified detailed inter-annual and intra-annual variations of the coastline and SSC in the normal period(NP: 1986-2001, before and after the flood season) and WSR period(WSRP: 2002-2013, before and after WSR). The results indicate that(1) the sedimentation in the low reaches of the Yellow River turned into erosion from 2002 onward;(2) the inter-annual coastline changes could be divided into an accretion stage(1986-1996), a slow erosion stage(1996-2002), and a slow accretion stage(2002-2013);(3) an intra-annual coastline extension occurred in the river mouth in most years of the WSRP; and(4) the mean intra-annual accretion area was 0.789 km^2 in the NP and 4.73 km2 in the WSRP,and the mean SSC increased from 238 mg/L to 293 mg/L in the NP and from 192 mg/L to 264 mg/L in the WSRP.

The influence of water-sediment regulation on macrobenthic community structures in the Huanghe River(Yellow River)Estuary during 2012–2016

To determine if water-sediment regulation has affected macrobenthic community structure in the Huanghe River Estuary,China,macrobenthic samples were collected following regulation events from 2012 to 2016.We identify seven phyla and 138 macrobenthic species from within samples throughout the survey area,over time.Species richness and abundance in 2012 were significantly higher than in 2016.Biomass did not differ significantly during 2012–2016.Dominant species were mostly small polychaetes,with mollusks,arthropods,and echinoderms all being relatively rare.In 2016,dominant species were small polychaetes.MDS reveals macrobenthic communities at all surveyed distances from the estuary to have become the same community structure over time.Shannon-Wiener diversity and Margalef richness indexes trended down over time.CCA reveals the most dominant sediment-dwelling species to prefer lower dissolved oxygen,sulfides,and pH,and sediments with high D50 and low clay content.We speculate that water-sediment regulation has affected seabed communities,particularly Region A in our survey area.

Determination of optimal grid opening width for herringbone water-sediment separation structures based on sediment separation efficiency

The herringbone water-sediment separation structure(HWSSS) was developed to prevent debris flows. This paper mainly focuses on evaluating the sediment separation efficiency of HWSSS in debris flow prevention and determining the grid opening width D, a crucial structure parameter for HWSSS design. Theoretical analysis on the total sediment separation rate Pt reveals that the efficiency of sediment separation is much related with sediment grain size distribution(GSD) and grid opening width. The lower limit of Pt is deduced from the perspective of safety consideration by transforming debris flow into sediment-laden flow. Hydraulic model tests were carried out. Based on the regression analysis of the experimental data, the quantitative relationships between Pt and D and GSD characteristic values were finally established. A procedure for determining optimal grid opening width is proposed based on these analyses. These results are of significance in evaluating sediment separation effect by HWSSS in debris flow prevention and contribute to a more explicit methodology for design of HWSSS.

THE STUDY ON THREE-DIMENSIONAL MATHEMATICAL MODEL OF RIVER BED EROSION FOR WATER-SEDIMENT TWO-PHASE FLOW

Based on the tensor analysis of water-sediment two-phase how, the basic model equations for clear water flow and sediment-laden flow are deduced in the general curve coordinates for natural water variable-density turbulent how. Furthermore, corresponding boundary conditions are also presented in connection with the composition and movement of non-uniform bed material. The theoretical results are applied to the calculation of the float open caisson in the construction period and good results are obtained.

Impact of Water-Sediment Regulation on Variations of Amino Acids in the Middle-Lower Yellow River, China

In order to examine the impacts of water-sediment regulation on regional carbon cycling,we collected water,particulate and sediment samples from the middle-lower Yellow River in late June and early July,2015 and analyzed their specific amino acids(AA),DOC,POC,and bacteria abundance.Summarized by 14 specific AA,the total hydrolysable AA(THAA),particulate AA(PAA),and sediment AA(SAA)varied in ranges of 2.29-9.05μmol L^-1,5.22-22.96μmol L^-1,and 81.7-137.19μg g^-1 dry weight.After the regulation,dissolved free AA(DFAA)decreased by 29%while DCAA increased by 72%.These variations suggested that DFAA were further degraded,while DCAA molecules were further activated.Meanwhile,PAA increased almost 4 times as many as those before regulation,and SAA increased as well.After regulation,the amounts of bioactive amino acids(Asp,Glu and Gly)increased in THAA but decreased in PAA,with little changes in SAA.The ratios of Asp/Gly in different phases increased after regulation,indicating the AA contributions were promoted by calcareous organisms rather than by siliceous organisms.Multiple correlation analysis showed that PAA was primary representatives of AA and organic carbon,followed by DCAA and POC.Moreover,bacterial reproduction played a key role in shaping the AA compositions and properties,followed by the redox condition and acid-base balance.The results of this study provided a clear evidence for the effects of water-sediment regulation on regional biogeochemistry of organic carbon in the middle-lower Yellow River.

Nutrient exchange and release experiment and its simulation study in lake water-sediment interface

The sediment distributed and insolated under lake was collected for experiments. The nutrient layer distribution conditions of sampled sediment and its physical and chemical characteristics were analyzed to simulate and assess the influence degree to lake water quality. Based on the dynamic water exchanging experiments the nutrient release process in sediment and influence mechanism to substance exchanging on water-sediment interface was studied, and the correlation between the changing content of total phosphors and total nitrogen in sediment and covered water were analyzed for setting up a simulation model. At the same time the influence degree is explained in detail. The experimental results indicated that even if clean water without nutrient contents was used for water exchangement so as to decrease pollution or prevent eutrophication, however owing to the vertical nutrient distribution in lake sediment, it will lead to the increasing release amount greatly especially when the organic nutrient contained in sediment turns into inorganic status because of isolation. Besides the release process of total phosphate （TP） and total nitrogen （TN） were modeled and each nutrient＇s exchanging equation at interface caused by covered water nutrient concentration changing was set up. According to the simulating prediction, TP and TN content of cover water will also sustain a steady higher level in a long period. The nutrient release amount of sediment is not only affected by the covered water concentration but also connects with accumulative time. The experiments provide the fundamental theoretical and practical basis for taking ecological restoration project. And research is helpful to prevent or restore lake eutrophication.

REE distribution in water-sediment interface system at deep ocean floor

REE concentrations and distribution patterns in the different phases of water-sediment interface system at deep ocean floor were studied on the basis of samples of bottom water, sediments, interstitial water and polymetallic nodules collected from the East Pacific Basin by R/V Haiyang 4 during HY4-871 and HY4-881Cruises. It is suggested that REE concentrations in oxic interstitial water are lower than that in bottom weter,REE contents of polymetallic nodules, except Ce, are similar to that of sediments. Bottom water, sediments and interstitial water are almost the same in REE distribution patterns. MREE enrichment relative to LREE and HREE and negative Ce anomalies, MREE earichment has been found in polymetallic nodules,and Ce shows positive anomalies. REE contents in sediments increase with depth, and the vacations of distribution patterns with depth have not been found.

Environmental Flow Assessment Using Water-Sediment Approach at the Sekampung River, Indonesia

Environmental issue has been considered more significant in many aspects of engineering decision-making process particularly in river management. There is an increasing effort to conserve functioning of rivers for human use as well as nature, therefore environmental flow assessment has been widely developed. This paper discusses on environmental flow assessment of the Sekampung River, particularly on its middle reach. A new analytical approach based on water-sediment equations was introduced in order to determine a minimum environmental flow at the certain cross section of a river. The result of the new method was then compared with a minimum environmental flow provided by using two hydrological based methods, namely, Tennant and Flow Duration Curve Analysis (FDCA) method. The result shows that the concerned discharge provided by the water-sediment method (3.5 m3/s) is the smallest compare with a minimum environmental flow that is provided by both Tennant (5.7 m3/s) and FDCA method (4.5 m3/s). It is promising that the water-sediment method can be used as a simple approach on preliminary state of environmental flow assessment. The method involves not only water discharge but also its related sediment flow of the river in order to mitigate further ecological and morphological risks.

Equilibrium sediment transport in lower Yellow River during later sediment-retaining period of Xiaolangdi Reservoir

The Xiaolangdi Reservoir has entered the later sediment-retaining period, and new sediment transport phenomena and channel re-estab- lishing behaviors are appearing. A physical model test was used to forecast the scouring and silting trends of the lower Yellow River. Based on water and sediment data from the lower Yellow River during the period from 1960 to 2012, and using a statistical method, this paper analyzed the sediment transport in sediment-laden flows with different discharges and sediment concentrations in the lower Yellow River. The results show that rational water-sediment regulation is necessary to avoid silting in the later sediment-retaining period. The combination of 3 000 m^3/s 〈 Q 〈 4 000 m^3/s and 20 kg/m^3 〈 S 〈 60 kg/m^3 （where Q is the discharge and S is the sediment concentration） at the Huayuankou section is considered an optimal combination for equilibrium sediment transport in the lower Yellow River over a long period of time.

Flow Behavior of Clay-Silt to Sand-Silt Water-Rich Suspensions at Low to High Shear Rates: Implications for Slurries, Transitional Flows, and Submarine Debris-Flows

Water-rich clay to sand suspensions show a shear rate dependent flow behavior and knowledge of the appropriate rheological model is relevant for sedimentological, industrial and hydraulic studies. We present experimental rheological measurements of water-rich(40 to 60 wt%) clay to silt(population A) and silt to sand(population B) suspensions mixed in different proportions. The data evidence a shear rate dependent shear thinning-shear thickening transition. At lower shear rates, the suspensions organize in chains of particles, whereas at higher shear rates, these chains disrupt so increasing the viscosity. The viscosity, consistency and yield stress decrease as the A+B fraction decreases as the content of B particles increases. This behavior reflects the competing effects of the lubrication and frictional processes as a function of particle size and water content. Transitional flows form by the incorporation of small amounts of the finer fraction while ‘oceanic floods’ form at the estuary of rivers and the submarine debris-flows increase their velocity by incorporating water. The critical Reynolds number of the studied suspensions is ～2000±100 suggesting that the grainsize plays a major role in the laminar to turbulent transition. Our results have implications for the modeling of sediment flows and the hazard related to floods.

Spatiotemporal Evolution of Runoff and Sediment of the Taohe River and Its Driving Analysis

In order to explore the spatial and temporal changes of runoff and sediment in the Taohe River and its driving mechanism,Spearman correlation coefficient method,Mann-Kendell mutation test method and ordered clustering method were used to analyze the changes of runoff and sediment discharge and their driving factors in four hydrological stations along the Taohe River from 1957 to 2016.The results showed that the correlation between runoff and sediment of the four hydrological stations along the Taohe River was significant,and the correlation coefficient was 0.728-0.984.The runoff and sediment transport in the interval showed an increasing and decreasing trend.The decrease rate of runoff was 133.82%-216.17%higher than that of Xiabagou station,and the decrease rate of sediment transport was 250.49%-4766.33%higher than that of Xiabagou station.The mutation year of the Taohe River runoff occurred in 1986,and the maximum decrease was 35%.The water-sediment relationship curves of different periods showed that the sediment discharge of the four stations changed abruptly around 1990,and the maximum reduction before and after the mutation was up to 73%,and the sediment discharge in the river channel decreased significantly.The research showed that human activities were the main driving factors for the change of water-sediment relationship in the Taohe River.

Strontium isotopic geochemistry of the Changjiang estua-rine waters: Implications for water-sediment interaction

The Sr concentrations and 87Sr/86Sr ratios have been measured for the Changjiang es-tuarine waters with a main purpose to understand physical and chemical processes at the estuary. The result shows that the Changjiang River water has higher Sr concentration (150 ng/g) and lower 87Sr86Sr ratio (0.7105) when compared with the average values (0.7119 for 87Sr/86Sr and 78ppb for Sr, respectively) of large world rivers. In the mixing process, no simple mixing of two end-members has been found according to the variations of Sr concentration and isotope ratios. There is an abrupt rise of Sr isotope ratios at the salinity about 1 mg/g during river-sea water mixing at the estuary. This abrupt rise of Sr isotope ratios is mostly ascribed to the strong water-sediment interaction, because there exists the same rise of suspended particulate materials due to energetic resuspension of bottom sediments.

Nutrient fluxes induced by disturbance in Meiliang Bay of Lake Taihu

A wave flume experiment was conducted to study nutrient fluxes at water-sediment interface of Meiliang Bay under different hydrodynamic conditions. The results reveal that hydrodynamics has remarkable effects on nutrient fluxes in this area. With a bottom wave stress of 0.019 N m-2 (equivalent to disturbance caused by wind SE 5-7 m s-1 at the sediment sample site of Meiliang Bay), the fluxes of TN, TDN and NH4+-N were separately 1.92× 10-3, -1.81 × 10-4 and 5.28× 10-4 mg m-2 s-1(positive for upward and negative for downward), but for TP, TDP and SRP, the fluxes were 5.69 × 10-4, 1.68 × 10-4 and -1.29 × 10-4 mgm-2 s-1. In order to calculate the released amount of nutrients based on these results, statistic analysis on the long-term meteorological data was conducted.The result shows that the maximum lasting time for wind SE 5-7 m s-1 in this area is about 15 h in summer. Further calculation shows that 111 t TN, 32 t NH4+-N, 34 t TP and 10 t TDP can be released into water (the sediment area was 47.45% of the whole surface area), resulting in concentration increase of 0.025, 0.007, 0.007 and 0.002 mg L-1 separately. With stronger disturbance (bottom wave stress is 0.217 N m-2 which is equivalent to disturbance caused by wind SE 10-11 m s-1 at the same site), there has been significant increase of nutrient fluxes (1.16× 10-2, 6.76×10-3, 1.14× 10-2 and 2.14× 10-3 mgm-2 s-1 for TN, DTN and NH4+-N and TP). The exceptions were TDP with flux having a decrease (measured to be 9.54× 10-5 mgm-2 s-1 ) and SRP with flux having a small increase (measured to be 5.42 × 10-5 mgm-2 s-1). The same statistic analysis on meteorological data reveal that the maximum lasting time for wind SE 10-11 m s-1 is no more than 5 h. Based on the nutrient fluxes and the wind lasting-time, similar calculations were also made suggesting that 232 t TN, 134.9 t TDN, 228 t NH4+-N, 42.7 t TP, 2.0 t TDP and 1.1 t SRP will be released from sediment at this hydrodynamic condition resulting in the concentration increases of 0.050, 0.029, 0.049, 0.009, 0.0004 and 0.0002 mg L-1. Therefore in shallow lakes, surface disturbance can lead to significant increase of nutrient concentrations although some components in water column had negative flux with weak disturbance (e.g. TDN and SRP in this experiment). In this case, sediment looks to be a source of nutrients. These nutrients deposited in sediment can be carried or released into water with sediment resuspension or changes of environmental conditions at water-sediment interface, which can have great effects on aquatic ecosystem and is also the characteristics of shallow lakes.

Dual state-parameter optimal estimation of one-dimensional open channel model using ensemble Kalman filter

In this paper, both state variables and parameters of one-dimensional open channel model are estimated using a framework of the Ensemble Kalman Filter （EnKF）. Compared with observation, the predicted accuracy of water level and discharge are impro- ved while the parameters of the model are identified simultaneously. With the principles of the EnKF, a state-space description of the Saint-Venant equation is constructed by perturbing the measurements with Gaussian error distribution. At the same time, the rough- ness, one of the key parameters in one-dimensional open channel, is also considered as a state variable to identify its value dynamica- lly. The updated state variables and the parameters are then used as the initial values of the next time step to continue the assimilation process. The usefulness and the capability of the dual EnKF are demonstrated in the lower Yellow River during the water-sediment regulation in 2009. In the optimization process, the errors between the prediction and the observation are analyzed, and the rationale of inverse roughness is discussed. It is believed that （1） the flexible approach of the dual EnKF can improve the accuracy of predi- cting water level and discharge, （2） it provides a probabilistic way to identify the model error which is feasible to implement but hard to handle in other filter systems, and （3） it is practicable for river engineering and management.

RESERVOIR SEDIMENTATION AND TRANSFORMATION OF MORPHO-LOGY IN THE LOWER YELLOW RIVER DURING 10 YEAR'S INITIAL OPERATION OF THE XIAOLANGDI RESERVOIR

The Xiaolangdi Hydro-Project is one of the large projects on the main stem of the Middle Yellow River. It has been operated for more than 10 years, since its impoundment in October, 1999. The reservoir has trapped 2.833 × 10^9 m3 of sediment, and caused the total erosion of 1.891 × 10^9t in the Lower Yellow River from October, 1999 through October, 2010. Not only the serious atrophied situation of the Lower Yellow River （LYR） has been resuscitating, but also many new phenomena of sediment transport and behaviors of channel re-establishing are coming into being. They are illustrated and discussed in detail in this paper.

Characteristics of the Lower Yellow River channel shrinkage and its discriminant parameters

This paper analyzes the changing trends of the Lower Yellow River(LYR) transverse profile parameters and their aberrance points by the time series analysis method.Research results show that there has been a trend of changes in the LYR channel transverse profile parameters since the 1950s.The main river channel has a tendency of shrinkage year by year and the trend will be continued in the future.The main features of the LYR channel shrinkage are remarkable reductions of bankfull dis-charges and bankfull areas,corresponding decreases of bankfull widths,average bankfull water depths and maximal bankfull water depths,as well as increases of bankfull water levels and width-depth ratios accompanied.The discriminant parameters for threshold of the LYR main channel shrinkage were put forward.It indicates that the LYR main channel began to shrink in the 1970s and has entered into a serious phase of channel shrinkage since the 1990s.The incompatible index of discharged water-sediment processes of the Sanmenxia Reservoir was introduced,which revealed that there was a trend of increasing in the incompatibility between water flow and sediment load.Response relations between the LYR main channel shrinkage parameters and discharged water-sediment processes of the Sanmenxia Reservoir were founded,which indicate that the LYR main channel shrinkage can be mitigated and improved through the regulation of discharged water-sediment processes of the reservoir,especially through the regulation of water-sediment incompatible index.The LYR channel for water and sediment transportation can be restored and maintained.

Seasonal dynamics of iron and phosphorus in reservoir sediments in Eucalyptus plantation region

Background:Iron(Fe)and phosphorus(P)dynamics in sediments have direct and indirect impacts on water quality.However,the mobility of P and Fe in reservoir sediments in Eucalyptus plantation region remains unclear.This study examined P and Fe pollution in sediments in a Eucalyptus plantation region using the novel planar optode,the ZrO-Chelex DGT,and the DIFS model.Results:Direct in situ investigations showed that the levels of labile P and Fe were smaller in the Eucalyptus species-dominated sediments(X2)compared to sediments without Eucalyptus species(X1).The mean concentration of labile P and Fe decreased by 25%and 42%from X1 to X2.The decrement was insignificant(p=0.20)in the surface sediment concentration for labile P.The significant disparity for DGT-Fe(Fe^(2+))(p=0.03)observed in the surface sediments could be attributed to the Eucalyptus species’elevated organic matter(tannins)concentration at X2,which reacted and consumed labile Fe.For both regions,the maximum concentration of labile P and Fe occurred in November(autumn).The reductive decomposition of Fe/Mn oxides was recognized as the main driver for their high P efflux in July and November.Low concentration of labile P and Fe was observed in December(winter)due to the adsorption of Fe/Mn oxides.The concentration of labile Fe synchronizes uniformly with that of labile P in both sediments indicating the existence of a coupling relationship(r>0.8,p<0.01)in both regions.The positive diffusion fluxes in both regions suggested that the sediments release labile P and Fe.The fluxes of labile P and Fe in both regions were substantially higher(p<0.05)in the summer(anoxic period)than winter(aerobic period),indicating that hypoxia and redox conditions influenced the seasonal efflux of labile P and Fe.From the DIFS model,the replenishment ability of reactive P was higher during the anoxic period(R=0.7,k_(1)=79.4 day^(-1),k_(-1)=0.2 day^(-1))than the aerobic period(R=0.4,k_(1)=14.2 day^(-1),k_(-1)=0.1 day^(-1)),suggesting that oxygen inhibited the efflux of P in the sediments.Conclusion:Our results indicated that hypoxia,Eucalyptus species(organic matter(tannins)),and redox conditions influenced the seasonal mobility of sediment labile P and Fe.Our findings provided an insight into the mobility of labile P and Fe in Eucalyptus-dominated sediments and,moreover,serves as a reference for developing future studies on Eucalyptus-dominated sediments.