Seawater splitting into hydrogen,a promising technology,is seriously limited by the durability and tolerance of electrocatalysts for chlorine ions in seawater at large current densities due to chloride oxidation and c...Seawater splitting into hydrogen,a promising technology,is seriously limited by the durability and tolerance of electrocatalysts for chlorine ions in seawater at large current densities due to chloride oxidation and corrosion.Here,we present a robust and weak-nucleophilicity nickel-iron hydroxide electrocatalyst with excellent selectivity for oxygen evolution and an inert response for chlorine ion oxidation which are key and highly desired for efficient seawater electrolysis.Such a weak-nucleophilicity electrocatalyst can well match with strong-nucleophilicity OH-compared with the weak-nucleophilicity Cl^(-),resultantly,the oxidation of OH-in electrolyte can be more easily achieved relative to chlorine ion oxidation,confirmed by ethylenediaminetetraacetic acid disodium probing test.Further,no strongly corrosive hypochlorite is produced when the operating voltage reaches about 2.1 V vs.RHE,a potential that is far beyond the thermodynamic potential of chlorine ion oxidatio n.This concept and approach to reasonably designing weaknucleophilicity electrocatalysts that can greatly avoid chlorine ion oxidation under alkaline seawater environments can push forward the seawater electrolysis technology and also accelerate the development of green hydrogen technique.展开更多
Forward-backward pursuit (FBP) algorithm is a novel two-stage greedy approach. However once its forward and backward steps were determined during iteration, it would make computing time increased and affected the reco...Forward-backward pursuit (FBP) algorithm is a novel two-stage greedy approach. However once its forward and backward steps were determined during iteration, it would make computing time increased and affected the reconstruction efficiency. This paper presents a algorithm called forward-backward pursuit algorithm based on weak selection (SWFBP) by introducing threshold strategy into FBP algorithm, and in view of that in the first few iterations, most of the atoms which are selected are right, so this part of atoms are directly incorporated into support set instead of using backward strategy to reduce them. Flexible forward and backward steps accelerate the speed of atom selecting and improve the reconstruction accuracy. We compared SWFBP and FBP algorithm via one-dimensional signal and two-dimensional image reconstruction experiments. The simulation results demonstrate that compared with FBP, SWFBP algorithm has superior performance, including higher PSNR, faster computing speed and lower recovery time.展开更多
Traditionally, in weak interaction, I<sub>3</sub>, Y and four flavour quantum numbers are not conserved but several empirical selection rules work well. Recently, it was found that, in weak interaction, th...Traditionally, in weak interaction, I<sub>3</sub>, Y and four flavour quantum numbers are not conserved but several empirical selection rules work well. Recently, it was found that, in weak interaction, there are three levels of conservation of additive quantum numbers, and fermion quantum number F is conserved in all kinds of interactions. It is known that weak interaction has three types: fermionic, pure hadronic and pure leptonic, corresponding to the first and the second level of conservation of additive quantum numbers respectively. It is demonstrated in this paper that the selection rules in all types of weak interaction can be interpreted by conservation of F, and the formula of relation between Q/e, F and F<sub>0</sub> is more general than Gell-Mann-Nishijima formula. Description of weak interaction becomes simpler, If only we take Q, F<sub>0</sub> and F, based on the conserved physical quantities.展开更多
The key to improve the performance of heteroatom catalysts is to ensure the orderliness of catalysts and the good dispersion of heteroatoms.The alkalinity plays the indispensable role in synthetic process of V-MCM-41 ...The key to improve the performance of heteroatom catalysts is to ensure the orderliness of catalysts and the good dispersion of heteroatoms.The alkalinity plays the indispensable role in synthetic process of V-MCM-41 catalyst.The excessive alkalinity of synthetic system will make the MCM-41 difficult to crystallize,even to dissolve.It is easy to accumulate for heteroatomic species in the system of low alkalinity.Herein,the highly ordered VMCM-41 with high vanadic content in framework is synthesized in the condition of excessive NH3·H2 O in this paper.A series of characterization results prove the good dispersion of vanadium species,and most of vanadium gets into the framework of MCM-41 with the states of tetravalence and pentavalence.Furthermore,the modified MCM-41 by other transition metals is successful synthesized by the method of V-MCM-41 in this paper.The VMCM-41 shows well catalytic activity for the selective oxidation of benzyl alcohol,which up to 74.83%for the conversion of benzyl alcohol and 96.20%for selectivity of benzaldehyde when initial V/Si=0.10.The paper provides the possibility for industrial application of V-MCM-41 in the oxidation of benzyl alcohol for benzaldehyde.Besides,the work provides a significant idea for the synthesis of modified MCM-41 by well-dispersed transition metals.展开更多
In weak measurement thought experiment, an ensemble consists of M quantum particles and N states. We observe that separability of the particles is lost, and hence we have fuzzy occupation numbers for the particles in ...In weak measurement thought experiment, an ensemble consists of M quantum particles and N states. We observe that separability of the particles is lost, and hence we have fuzzy occupation numbers for the particles in the ensemble. Without sharply measuring each particle state, quantum interferences add extra possible configurations of the ensemble, this explains the Quantum Pigeonhole Principle. This principle adds more entropy to the system;hence the particles seem to have a new kind of correlations emergent from particles not having a single, well-defined state. We formulated the Quantum Pigeonhole Principle in the language of abstract Hilbert spaces, then generalized it to systems consisting of mixed states. This insight into the fundamentals of quantum statistical mechanics could help us understand the interpretation of quantum mechanics more deeply, and possibly have implication on quantum computing and information theory.展开更多
In this paper,the weak pre-orthogonal adaptive Fourier decomposition(W-POAFD)method is applied to solve fractional boundary value problems(FBVPs)in the reproducing kernel Hilbert spaces(RKHSs)W_(0)^(4)[0,1] and W^(1)[...In this paper,the weak pre-orthogonal adaptive Fourier decomposition(W-POAFD)method is applied to solve fractional boundary value problems(FBVPs)in the reproducing kernel Hilbert spaces(RKHSs)W_(0)^(4)[0,1] and W^(1)[0,1].The process of the W-POAFD is as follows:(i)choose a dictionary and implement the pre-orthogonalization to all the dictionary elements;(ii)select points in[0,1]by the weak maximal selection principle to determine the corresponding orthonormalized dictionary elements iteratively;(iii)express the analytical solution as a linear combination of these determined dictionary elements.Convergence properties of numerical solutions are also discussed.The numerical experiments are carried out to illustrate the accuracy and efficiency of W-POAFD for solving FBVPs.展开更多
基金supported by the National Natural Science Foundation of China(NSFC,No.22078052)the Fundamental Research Funds for the Central Universities(DUT22ZD207,DUT22LAB612)。
文摘Seawater splitting into hydrogen,a promising technology,is seriously limited by the durability and tolerance of electrocatalysts for chlorine ions in seawater at large current densities due to chloride oxidation and corrosion.Here,we present a robust and weak-nucleophilicity nickel-iron hydroxide electrocatalyst with excellent selectivity for oxygen evolution and an inert response for chlorine ion oxidation which are key and highly desired for efficient seawater electrolysis.Such a weak-nucleophilicity electrocatalyst can well match with strong-nucleophilicity OH-compared with the weak-nucleophilicity Cl^(-),resultantly,the oxidation of OH-in electrolyte can be more easily achieved relative to chlorine ion oxidation,confirmed by ethylenediaminetetraacetic acid disodium probing test.Further,no strongly corrosive hypochlorite is produced when the operating voltage reaches about 2.1 V vs.RHE,a potential that is far beyond the thermodynamic potential of chlorine ion oxidatio n.This concept and approach to reasonably designing weaknucleophilicity electrocatalysts that can greatly avoid chlorine ion oxidation under alkaline seawater environments can push forward the seawater electrolysis technology and also accelerate the development of green hydrogen technique.
文摘Forward-backward pursuit (FBP) algorithm is a novel two-stage greedy approach. However once its forward and backward steps were determined during iteration, it would make computing time increased and affected the reconstruction efficiency. This paper presents a algorithm called forward-backward pursuit algorithm based on weak selection (SWFBP) by introducing threshold strategy into FBP algorithm, and in view of that in the first few iterations, most of the atoms which are selected are right, so this part of atoms are directly incorporated into support set instead of using backward strategy to reduce them. Flexible forward and backward steps accelerate the speed of atom selecting and improve the reconstruction accuracy. We compared SWFBP and FBP algorithm via one-dimensional signal and two-dimensional image reconstruction experiments. The simulation results demonstrate that compared with FBP, SWFBP algorithm has superior performance, including higher PSNR, faster computing speed and lower recovery time.
文摘Traditionally, in weak interaction, I<sub>3</sub>, Y and four flavour quantum numbers are not conserved but several empirical selection rules work well. Recently, it was found that, in weak interaction, there are three levels of conservation of additive quantum numbers, and fermion quantum number F is conserved in all kinds of interactions. It is known that weak interaction has three types: fermionic, pure hadronic and pure leptonic, corresponding to the first and the second level of conservation of additive quantum numbers respectively. It is demonstrated in this paper that the selection rules in all types of weak interaction can be interpreted by conservation of F, and the formula of relation between Q/e, F and F<sub>0</sub> is more general than Gell-Mann-Nishijima formula. Description of weak interaction becomes simpler, If only we take Q, F<sub>0</sub> and F, based on the conserved physical quantities.
基金partially supported by the National Natural Science Foundation of China(Grant Nos.21601026,21771030)Fundamental Research Funds for the Central Universities(DUT16RC(4)10,DUT18RC(6)008)。
文摘The key to improve the performance of heteroatom catalysts is to ensure the orderliness of catalysts and the good dispersion of heteroatoms.The alkalinity plays the indispensable role in synthetic process of V-MCM-41 catalyst.The excessive alkalinity of synthetic system will make the MCM-41 difficult to crystallize,even to dissolve.It is easy to accumulate for heteroatomic species in the system of low alkalinity.Herein,the highly ordered VMCM-41 with high vanadic content in framework is synthesized in the condition of excessive NH3·H2 O in this paper.A series of characterization results prove the good dispersion of vanadium species,and most of vanadium gets into the framework of MCM-41 with the states of tetravalence and pentavalence.Furthermore,the modified MCM-41 by other transition metals is successful synthesized by the method of V-MCM-41 in this paper.The VMCM-41 shows well catalytic activity for the selective oxidation of benzyl alcohol,which up to 74.83%for the conversion of benzyl alcohol and 96.20%for selectivity of benzaldehyde when initial V/Si=0.10.The paper provides the possibility for industrial application of V-MCM-41 in the oxidation of benzyl alcohol for benzaldehyde.Besides,the work provides a significant idea for the synthesis of modified MCM-41 by well-dispersed transition metals.
文摘In weak measurement thought experiment, an ensemble consists of M quantum particles and N states. We observe that separability of the particles is lost, and hence we have fuzzy occupation numbers for the particles in the ensemble. Without sharply measuring each particle state, quantum interferences add extra possible configurations of the ensemble, this explains the Quantum Pigeonhole Principle. This principle adds more entropy to the system;hence the particles seem to have a new kind of correlations emergent from particles not having a single, well-defined state. We formulated the Quantum Pigeonhole Principle in the language of abstract Hilbert spaces, then generalized it to systems consisting of mixed states. This insight into the fundamentals of quantum statistical mechanics could help us understand the interpretation of quantum mechanics more deeply, and possibly have implication on quantum computing and information theory.
基金University of Macao Multi-Year Research Grant Ref.No MYRG2016-00053-FST and MYRG2018-00168-FSTthe Science and Technology Development Fund,Macao SAR FDCT/0123/2018/A3.
文摘In this paper,the weak pre-orthogonal adaptive Fourier decomposition(W-POAFD)method is applied to solve fractional boundary value problems(FBVPs)in the reproducing kernel Hilbert spaces(RKHSs)W_(0)^(4)[0,1] and W^(1)[0,1].The process of the W-POAFD is as follows:(i)choose a dictionary and implement the pre-orthogonalization to all the dictionary elements;(ii)select points in[0,1]by the weak maximal selection principle to determine the corresponding orthonormalized dictionary elements iteratively;(iii)express the analytical solution as a linear combination of these determined dictionary elements.Convergence properties of numerical solutions are also discussed.The numerical experiments are carried out to illustrate the accuracy and efficiency of W-POAFD for solving FBVPs.
