The adsorption properties of a novel gel-type weak acid resin (110-H) for Pb2+ were investigated using chemical methods and IR spectrometry.The optimal adsorption condition of 110-H for Pb2+ is at pH=6.49 in HAc-NaAc ...The adsorption properties of a novel gel-type weak acid resin (110-H) for Pb2+ were investigated using chemical methods and IR spectrometry.The optimal adsorption condition of 110-H for Pb2+ is at pH=6.49 in HAc-NaAc medium and the statically saturated adsorption capacity is 485 mg/g at 298 K.Pb2+ adsorbed on 110-H resin can be eluted with 0.025 mol/L HCl quantificationally.The adsorption rate constants determined under the temperatures of 288,298,308 and 318 K are 2.46×10-5,3.82×10-5,4.46×10-5 and 5.71×10-5 s-1,respectively.The apparent activation energy,Ea,is 18.1 kJ/mol and the thermodynamic parameters of adsorption,ΔH=20.9 kJ/mol,ΔS=161 J/(mol.K) and ΔG298 K =-48.0 kJ/mol,respectively.The adsorption behavior of 110-H resin for Pb2+ accords with the Langmuir isotherm.Infrared spectra show that the oxygen atoms of the functional group of resin coordinate with Pb2+ to form the coordination bands.展开更多
In this paper, the two-dimensional Marcinkewicz integral introduced by Stein μ(f)(x)=(∫_0~x|∫_(|x-y|≤1) _(|x-y|)^(Ω(x-y))f(y)dy|~2t^(-3)dt)~2 is shown to be of weak type (1,1) and weighted weak type (1,1) with r...In this paper, the two-dimensional Marcinkewicz integral introduced by Stein μ(f)(x)=(∫_0~x|∫_(|x-y|≤1) _(|x-y|)^(Ω(x-y))f(y)dy|~2t^(-3)dt)~2 is shown to be of weak type (1,1) and weighted weak type (1,1) with respect to power weight |x|~' if - 1< α< 0, where Ω is homogeneous of degree 0. has mean value 0 and belongs to Llog^+L(S^1).展开更多
基金Project (Y404279) supported by the Natural Science Foundation of Zhejiang Province, China
文摘The adsorption properties of a novel gel-type weak acid resin (110-H) for Pb2+ were investigated using chemical methods and IR spectrometry.The optimal adsorption condition of 110-H for Pb2+ is at pH=6.49 in HAc-NaAc medium and the statically saturated adsorption capacity is 485 mg/g at 298 K.Pb2+ adsorbed on 110-H resin can be eluted with 0.025 mol/L HCl quantificationally.The adsorption rate constants determined under the temperatures of 288,298,308 and 318 K are 2.46×10-5,3.82×10-5,4.46×10-5 and 5.71×10-5 s-1,respectively.The apparent activation energy,Ea,is 18.1 kJ/mol and the thermodynamic parameters of adsorption,ΔH=20.9 kJ/mol,ΔS=161 J/(mol.K) and ΔG298 K =-48.0 kJ/mol,respectively.The adsorption behavior of 110-H resin for Pb2+ accords with the Langmuir isotherm.Infrared spectra show that the oxygen atoms of the functional group of resin coordinate with Pb2+ to form the coordination bands.
文摘In this paper, the two-dimensional Marcinkewicz integral introduced by Stein μ(f)(x)=(∫_0~x|∫_(|x-y|≤1) _(|x-y|)^(Ω(x-y))f(y)dy|~2t^(-3)dt)~2 is shown to be of weak type (1,1) and weighted weak type (1,1) with respect to power weight |x|~' if - 1< α< 0, where Ω is homogeneous of degree 0. has mean value 0 and belongs to Llog^+L(S^1).
