The chemical weathering intensity and element migration features of the Xiashu loess profile in Zhenjiang are studied in this paper.（1）The Xiashu loess profile underwent moderate chemical weathering.It seems that th...The chemical weathering intensity and element migration features of the Xiashu loess profile in Zhenjiang are studied in this paper.（1）The Xiashu loess profile underwent moderate chemical weathering.It seems that the precipitation is a more important factor than the temperature in controlling the process of the chemical weathering.（2）The major elements such as Si,K,Na,Ca,Mg,Mn and P were migrated and leached,while the elements Fe and Ti were slightly enriched.The migration features of the major elements reveal that the Xiashu loess finished the primary process of chemical weathering characterized by leaching of Ca and Na,and almost reached the secondary process characterized by leaching of K.Except the elements Sr and Ga,other trace elements such as Th,Ba,Cu,Zn,Co,Ni,Cr and V were enriched.It might be caused by both the biogeochemical process and the adsorption of trace elements by clay mineral and organic materials.（3）The difference of element migration down the Xiashu loess profile reveals that the climate was warm and wet at the early-middle stage of the middle Pleistocene.At the end of the middle Pleistocene,it became dry and cool.At the early stage of the Late Pleistocene,the paleoclimate became warm and wet again.As a whole,the paleoclimate generally became drier and cooler in this region from the beginning of the middle Pleistocene.展开更多
A new type of rare earth elements （REEs） deposit was discovered from the gaolinite mudstone in the weathering crust of Permian basalt, Bijie region, western Guizhou, China. It contained ∑RE2O3 0.065%-1.086%. This t...A new type of rare earth elements （REEs） deposit was discovered from the gaolinite mudstone in the weathering crust of Permian basalt, Bijie region, western Guizhou, China. It contained ∑RE2O3 0.065%-1.086%. This type of REEs deposit was widely distributed with steady horizon and thickness of 3-4 m. The ore-bearing weathering crust （kaolinite） of the three discovered REEs deposits belonged to the third episode of the Emeishan basalt eruption. The new type of REEs deposit was suggested that basalt （tuff） weathering could lead to the enrichment of the rare earth elements. Therefore, it is of important economic significance to explore REEs deposits in the weathering crust of basalt （tuffs） in Yunnan, Guizhou, and Sichuan Provinces.展开更多
Although rare earth elements(REEs)in magmatic zircons have been widely used to identify the type and compositional evolution of host rocks,REE distribution patterns during the chemical alteration of zircons need clari...Although rare earth elements(REEs)in magmatic zircons have been widely used to identify the type and compositional evolution of host rocks,REE distribution patterns during the chemical alteration of zircons need clarification.We investigated REE characteristics in zircons with different degrees of chemical weathering through systematic observation of a granodiorite-weathering profile in southeast China.Despite the relatively stable provenance of the studied profile(zircon U–Pb ages are95.2±4.8 Ma),the zircon REEs exhibited systematic differences in abundance and fractionation patterns from the bedrock to upper layers,e.g.∑PREE,(LREE/HREE)_(CN),and Ce/Ce*.This evidence suggests chemical alteration of zircons during intensive chemical weathering and an expected influence on REE variability in the weathered products due to the presence of REE-bearing minerals.展开更多
Element geochemistry of lake sediments has been widely used to detect climate change because element composition and ratios can reflect the weathering degree in the source area. Given the element composition of lake s...Element geochemistry of lake sediments has been widely used to detect climate change because element composition and ratios can reflect the weathering degree in the source area. Given the element composition of lake sediments from Gulug Co Lake, Hoh Xil, Qinghai-Xizang Plateau, chemical index of alteration (CIA), index of composition variability (ICV) and other element ratios have been used to establish the weathering sequence of this area since 1820 AD. The weathering is so weak that the element composition change is more sensitive to climate change and autochthonous processes. From 1820 to 1984 AD, there were two drier periods with a wetter interval from 1870 to 1945 AD. After 1984 the weather showed a tendency of becoming wet.展开更多
Clearing up sediment and regolith on the foundation of the dam in the Three Gorges of the Yangtze River in 1999, riverbed were exposed. On the basis of weathering granite regolith sampled from different portions of th...Clearing up sediment and regolith on the foundation of the dam in the Three Gorges of the Yangtze River in 1999, riverbed were exposed. On the basis of weathering granite regolith sampled from different portions of the valley landforms, by analysing total chemical contents with X rays fluorescent slice and calculating proper value of chemical element transferring ratio and intensity, the transferring law of chemical elements in different portions of the landforms were concluded: 1) In various landforms of the river valley, the process of desilication is not distinct; 2) in weathering granite regolith of riverbed, easy soluble CaO and MgO are relatively enriched whereas Al2O3 tends to decrease. The enriching rate of Fe2O3 is the greatest in various landforms of the river valley; 3) in weathering granite regolith of flood-plain, K2O and MgO contents are relatively enriched; 4) the weathering granite regolith of valley slope is a typical north subtropical weathering regolith, and its chemical weathering degree is in the transition phase from early to middle period; and 5) there is an opposite layer where K2O is relatively leaching and Na2O relatively enriching in 6.5 m depth of all weathering granite regolith.展开更多
Thirteen weathering profiles of sedimentary rocks such as limestone, dolomitic limestone, dolomite, sillicalite, black shale and purple sandrock from Wujiang catchments were selected for study on enrichment and releas...Thirteen weathering profiles of sedimentary rocks such as limestone, dolomitic limestone, dolomite, sillicalite, black shale and purple sandrock from Wujiang catchments were selected for study on enrichment and release behavior of rare earth elements （REE） during weathering, and its impact on plant growth and riverine REE distribution in the catchments with methods of hierachical cluster analysis and mass balance calculation in order to set a basis for riverine material source research and agricultural production. The results show that the enrichment degree of REE in calcareous soils from the Wujiang catchments is much higher than that of limestone, yellow soil, upper continental crust （UCC）, China soil （CS） and world soil （WS）. The ability of enrichment and release of REE is partly controlled by distribution of REE in bedrocks, contents and adsorption ability of organic matters, clay minerals and Fe-oxides/hydroxides in weathering profiles. The REE released from weathering of carbonate rocks and clastic rocks can be absorbed and utilized by local plants. The results also reveal that release of REE and Fe mainly from weathering of carbonate rocks and partly from clastic rocks exerts an important control on riverine REE distribution.展开更多
This study was conducted to evaluate the weathering intensity of the major soils developed on igneous rocks in semiarid region of northwestern Iran.Eight parent materials were selected including monzodiorite,alkali gr...This study was conducted to evaluate the weathering intensity of the major soils developed on igneous rocks in semiarid region of northwestern Iran.Eight parent materials were selected including monzodiorite,alkali granite,granodiorite,syenite,pyroxene diorite,hornblende andesite,pyroxene andesite,and dacite.Representative soil profiles were described and soil samples were collected and analyzed for selected chemical and physical properties and total concentrations of major elements and Zr,V,Ti and Y.Bulk densities as well as Ti,Zr and V concentrations were used to estimate the strain factors and mass balance equations were used to quantify the net result of pedogenic weathering,i.e.elemental loss and gain.The results of clay content and pedogenic iron variability as well as index of compositional variability(ICV),chemical index of alteration(CIA) and,A-CN-K and MFW ternary plots showed that the soils developed on volcanic rocks(hornblende andesite> pyroxene andesite> dacite) were more weathered than those on the plutonic parent rocks(alkali granite,granodiorite,monzodiorite,syenite,pyroxene diorite).The results of mass balance calculations based on the strain factors revealed that the Ca and Na depleted during weathering progress mostly from plagioclase grains.In the semiarid regions Ca is precipitated as pedogenic calcite in the soil horizons.K and Mg depletion is less than Ca and Na especially in the profiles on the hornblende andesite with the highest clay and LOI content.The results of this study clearly suggest that the behavior of K and Mg during the weathering cannot only be explained by the disintegration of the primary minerals,since they are fixed on the secondary clay minerals.Iron did not change in the soils compared to the parent material and was precipitated as the pedogenic iron and conserved in the soil horizons.Overall,the results on the weathering indicators and major elements mass balance enrichment/depletion in the study area confirmed that the soil profiles developed on volcanic rocks are more weathered than those on the plutonic igneous rocks.展开更多
硅是植物生长的有益元素,也是人和其他动物生长发育、骨骼形成不可或缺的微量元素。在地球表层系统中,大多数的硅以硅酸盐矿物和石英的形式赋存于岩石之中。伴随着地表硅酸盐矿物的风化,硅可以水为载体不断向周边环境释放并参与到生物...硅是植物生长的有益元素,也是人和其他动物生长发育、骨骼形成不可或缺的微量元素。在地球表层系统中,大多数的硅以硅酸盐矿物和石英的形式赋存于岩石之中。伴随着地表硅酸盐矿物的风化,硅可以水为载体不断向周边环境释放并参与到生物地球化学循环中,为陆地和海洋生物提供所需的硅元素,维持生态系统健康,在全球物质循环中起着重要作用(Yang Jinling et al.,2018)。展开更多
【目的】探讨全新世以来华南地区陆地化学风化强度的变化及其控制因素。【方法】利用琼东海域沉积柱GH7的XRF扫描元素数据,从主量和微量元素中提取代表陆源输入的主成分PC1,分析华南沿海地区化学风化强度。【结果与结论】风化强度在13.2...【目的】探讨全新世以来华南地区陆地化学风化强度的变化及其控制因素。【方法】利用琼东海域沉积柱GH7的XRF扫描元素数据,从主量和微量元素中提取代表陆源输入的主成分PC1,分析华南沿海地区化学风化强度。【结果与结论】风化强度在13.2 ka BP以来经历了“强(13.2—7.5 ka BP)—弱(7.5—3.0 ka BP)—强(3.0—0 ka BP)”的变化,并在全球冷事件新仙女木、9.2 ka和8.2 ka时期均有明显减弱。PC1变化显示华南沿海地区风化强度大约在3 ka BP处于最强期,反映此时降雨量处于最大期,可能与热带辐合带(ITCZ)在此时期南移至低纬度有关。PC1频谱分析揭示风化强度存在一个约2 ka的周期,与厄尔尼诺(ENSO)周期一致,说明华南地区风化强度演变在千年尺度上很可能受ITCZ南移和ENSO的共同调控。展开更多
用于航天器轨道预报的热层密度模型普遍存在30%左右的误差,影响LEO卫星的精密轨道确定和载荷控制。基于低轨航天器平运动变化与大气密度的关系,使用GRACE(gravity recovery and climate experiment)卫星TLE数据反演2003、2007年沿轨大...用于航天器轨道预报的热层密度模型普遍存在30%左右的误差,影响LEO卫星的精密轨道确定和载荷控制。基于低轨航天器平运动变化与大气密度的关系,使用GRACE(gravity recovery and climate experiment)卫星TLE数据反演2003、2007年沿轨大气密度,通过比较反演值、模型值和实测值的关系分析误差产生原因,使用对数正态分布拟合密度比值。通过分析太阳辐射、地磁指数对大气密度变化的影响,提出一种基于空间环境指数的热层大气密度模型校正与预报方式。使用该方法对2003、2004、2007、2008年的MSIS86模型计算密度进行修正,将模型平均相对误差从33.33%~59.62%降低到11.55%~15.13%,太阳活动低年改进量是高年的1.5~2倍。对2009年经验模型结果进行预报校正,将预报误差降低36.49%,提高了模型精度。展开更多
Vertisol developed on argillaceous rocks has its special pedogenic processes and properties, and formed some secondary nodules. In study area, contents of rare earth elements (REE) are significantly different in diffe...Vertisol developed on argillaceous rocks has its special pedogenic processes and properties, and formed some secondary nodules. In study area, contents of rare earth elements (REE) are significantly different in different sedimentary rocks due to varied contents of clay fraction and clay mineral composition, etc. Under the dry and hot climate, REEs were less differentiated than their parent sedimentary rocks. However, REEs in secondary nodules formed in pedogenic process display their specific behaviors. They are more concentrated in iron concretions, the content of heavy REEs increases relatively, and positive Ce-anomaly appears. But, negative Ce-anomaly was found in calcium concretions, while normal Ce content in parent rocks and vertisol.展开更多
基金National Natural Science Foundation of China, No.40401006 Open Foundation of State Key Laboratory of Loess and Quaternary Geology, No.SKLLQG0304 Experimental Foundation of Nanjing University
文摘The chemical weathering intensity and element migration features of the Xiashu loess profile in Zhenjiang are studied in this paper.（1）The Xiashu loess profile underwent moderate chemical weathering.It seems that the precipitation is a more important factor than the temperature in controlling the process of the chemical weathering.（2）The major elements such as Si,K,Na,Ca,Mg,Mn and P were migrated and leached,while the elements Fe and Ti were slightly enriched.The migration features of the major elements reveal that the Xiashu loess finished the primary process of chemical weathering characterized by leaching of Ca and Na,and almost reached the secondary process characterized by leaching of K.Except the elements Sr and Ga,other trace elements such as Th,Ba,Cu,Zn,Co,Ni,Cr and V were enriched.It might be caused by both the biogeochemical process and the adsorption of trace elements by clay mineral and organic materials.（3）The difference of element migration down the Xiashu loess profile reveals that the climate was warm and wet at the early-middle stage of the middle Pleistocene.At the end of the middle Pleistocene,it became dry and cool.At the early stage of the Late Pleistocene,the paleoclimate became warm and wet again.As a whole,the paleoclimate generally became drier and cooler in this region from the beginning of the middle Pleistocene.
基金the Major State Basic Research Development Program of China (2006CB403202)the Doctoral Discipline Foundation of Guizhou University
文摘A new type of rare earth elements （REEs） deposit was discovered from the gaolinite mudstone in the weathering crust of Permian basalt, Bijie region, western Guizhou, China. It contained ∑RE2O3 0.065%-1.086%. This type of REEs deposit was widely distributed with steady horizon and thickness of 3-4 m. The ore-bearing weathering crust （kaolinite） of the three discovered REEs deposits belonged to the third episode of the Emeishan basalt eruption. The new type of REEs deposit was suggested that basalt （tuff） weathering could lead to the enrichment of the rare earth elements. Therefore, it is of important economic significance to explore REEs deposits in the weathering crust of basalt （tuffs） in Yunnan, Guizhou, and Sichuan Provinces.
基金supported by National Natural Science Foundation of China(No.41506058)Open Financial Grant from Qingdao National Laboratory for Marine Science and Technology(No.QNLM2016ORP0211)State Key Laboratory of Marine Geology,Tongji University(No.MG20170402)
文摘Although rare earth elements(REEs)in magmatic zircons have been widely used to identify the type and compositional evolution of host rocks,REE distribution patterns during the chemical alteration of zircons need clarification.We investigated REE characteristics in zircons with different degrees of chemical weathering through systematic observation of a granodiorite-weathering profile in southeast China.Despite the relatively stable provenance of the studied profile(zircon U–Pb ages are95.2±4.8 Ma),the zircon REEs exhibited systematic differences in abundance and fractionation patterns from the bedrock to upper layers,e.g.∑PREE,(LREE/HREE)_(CN),and Ce/Ce*.This evidence suggests chemical alteration of zircons during intensive chemical weathering and an expected influence on REE variability in the weathered products due to the presence of REE-bearing minerals.
文摘Element geochemistry of lake sediments has been widely used to detect climate change because element composition and ratios can reflect the weathering degree in the source area. Given the element composition of lake sediments from Gulug Co Lake, Hoh Xil, Qinghai-Xizang Plateau, chemical index of alteration (CIA), index of composition variability (ICV) and other element ratios have been used to establish the weathering sequence of this area since 1820 AD. The weathering is so weak that the element composition change is more sensitive to climate change and autochthonous processes. From 1820 to 1984 AD, there were two drier periods with a wetter interval from 1870 to 1945 AD. After 1984 the weather showed a tendency of becoming wet.
基金The Project of Study on Deep Trough FormationRiver Valley Development in the Three Gorges Dam Region of Yangtze River+1 种基金from Exploitation Corporation of The Three Gorges Project of Yangtze River in China Foundation Attracting TalentsZhejiang Uni
文摘Clearing up sediment and regolith on the foundation of the dam in the Three Gorges of the Yangtze River in 1999, riverbed were exposed. On the basis of weathering granite regolith sampled from different portions of the valley landforms, by analysing total chemical contents with X rays fluorescent slice and calculating proper value of chemical element transferring ratio and intensity, the transferring law of chemical elements in different portions of the landforms were concluded: 1) In various landforms of the river valley, the process of desilication is not distinct; 2) in weathering granite regolith of riverbed, easy soluble CaO and MgO are relatively enriched whereas Al2O3 tends to decrease. The enriching rate of Fe2O3 is the greatest in various landforms of the river valley; 3) in weathering granite regolith of flood-plain, K2O and MgO contents are relatively enriched; 4) the weathering granite regolith of valley slope is a typical north subtropical weathering regolith, and its chemical weathering degree is in the transition phase from early to middle period; and 5) there is an opposite layer where K2O is relatively leaching and Na2O relatively enriching in 6.5 m depth of all weathering granite regolith.
基金Key Direction Projects of the Innovation Programof Chinese Academy of Sciences (KZCX3-SW-140 , KZCX2-105)
文摘Thirteen weathering profiles of sedimentary rocks such as limestone, dolomitic limestone, dolomite, sillicalite, black shale and purple sandrock from Wujiang catchments were selected for study on enrichment and release behavior of rare earth elements （REE） during weathering, and its impact on plant growth and riverine REE distribution in the catchments with methods of hierachical cluster analysis and mass balance calculation in order to set a basis for riverine material source research and agricultural production. The results show that the enrichment degree of REE in calcareous soils from the Wujiang catchments is much higher than that of limestone, yellow soil, upper continental crust （UCC）, China soil （CS） and world soil （WS）. The ability of enrichment and release of REE is partly controlled by distribution of REE in bedrocks, contents and adsorption ability of organic matters, clay minerals and Fe-oxides/hydroxides in weathering profiles. The REE released from weathering of carbonate rocks and clastic rocks can be absorbed and utilized by local plants. The results also reveal that release of REE and Fe mainly from weathering of carbonate rocks and partly from clastic rocks exerts an important control on riverine REE distribution.
文摘This study was conducted to evaluate the weathering intensity of the major soils developed on igneous rocks in semiarid region of northwestern Iran.Eight parent materials were selected including monzodiorite,alkali granite,granodiorite,syenite,pyroxene diorite,hornblende andesite,pyroxene andesite,and dacite.Representative soil profiles were described and soil samples were collected and analyzed for selected chemical and physical properties and total concentrations of major elements and Zr,V,Ti and Y.Bulk densities as well as Ti,Zr and V concentrations were used to estimate the strain factors and mass balance equations were used to quantify the net result of pedogenic weathering,i.e.elemental loss and gain.The results of clay content and pedogenic iron variability as well as index of compositional variability(ICV),chemical index of alteration(CIA) and,A-CN-K and MFW ternary plots showed that the soils developed on volcanic rocks(hornblende andesite> pyroxene andesite> dacite) were more weathered than those on the plutonic parent rocks(alkali granite,granodiorite,monzodiorite,syenite,pyroxene diorite).The results of mass balance calculations based on the strain factors revealed that the Ca and Na depleted during weathering progress mostly from plagioclase grains.In the semiarid regions Ca is precipitated as pedogenic calcite in the soil horizons.K and Mg depletion is less than Ca and Na especially in the profiles on the hornblende andesite with the highest clay and LOI content.The results of this study clearly suggest that the behavior of K and Mg during the weathering cannot only be explained by the disintegration of the primary minerals,since they are fixed on the secondary clay minerals.Iron did not change in the soils compared to the parent material and was precipitated as the pedogenic iron and conserved in the soil horizons.Overall,the results on the weathering indicators and major elements mass balance enrichment/depletion in the study area confirmed that the soil profiles developed on volcanic rocks are more weathered than those on the plutonic igneous rocks.
文摘硅是植物生长的有益元素,也是人和其他动物生长发育、骨骼形成不可或缺的微量元素。在地球表层系统中,大多数的硅以硅酸盐矿物和石英的形式赋存于岩石之中。伴随着地表硅酸盐矿物的风化,硅可以水为载体不断向周边环境释放并参与到生物地球化学循环中,为陆地和海洋生物提供所需的硅元素,维持生态系统健康,在全球物质循环中起着重要作用(Yang Jinling et al.,2018)。
文摘【目的】探讨全新世以来华南地区陆地化学风化强度的变化及其控制因素。【方法】利用琼东海域沉积柱GH7的XRF扫描元素数据,从主量和微量元素中提取代表陆源输入的主成分PC1,分析华南沿海地区化学风化强度。【结果与结论】风化强度在13.2 ka BP以来经历了“强(13.2—7.5 ka BP)—弱(7.5—3.0 ka BP)—强(3.0—0 ka BP)”的变化,并在全球冷事件新仙女木、9.2 ka和8.2 ka时期均有明显减弱。PC1变化显示华南沿海地区风化强度大约在3 ka BP处于最强期,反映此时降雨量处于最大期,可能与热带辐合带(ITCZ)在此时期南移至低纬度有关。PC1频谱分析揭示风化强度存在一个约2 ka的周期,与厄尔尼诺(ENSO)周期一致,说明华南地区风化强度演变在千年尺度上很可能受ITCZ南移和ENSO的共同调控。
文摘用于航天器轨道预报的热层密度模型普遍存在30%左右的误差,影响LEO卫星的精密轨道确定和载荷控制。基于低轨航天器平运动变化与大气密度的关系,使用GRACE(gravity recovery and climate experiment)卫星TLE数据反演2003、2007年沿轨大气密度,通过比较反演值、模型值和实测值的关系分析误差产生原因,使用对数正态分布拟合密度比值。通过分析太阳辐射、地磁指数对大气密度变化的影响,提出一种基于空间环境指数的热层大气密度模型校正与预报方式。使用该方法对2003、2004、2007、2008年的MSIS86模型计算密度进行修正,将模型平均相对误差从33.33%~59.62%降低到11.55%~15.13%,太阳活动低年改进量是高年的1.5~2倍。对2009年经验模型结果进行预报校正,将预报误差降低36.49%,提高了模型精度。
文摘Vertisol developed on argillaceous rocks has its special pedogenic processes and properties, and formed some secondary nodules. In study area, contents of rare earth elements (REE) are significantly different in different sedimentary rocks due to varied contents of clay fraction and clay mineral composition, etc. Under the dry and hot climate, REEs were less differentiated than their parent sedimentary rocks. However, REEs in secondary nodules formed in pedogenic process display their specific behaviors. They are more concentrated in iron concretions, the content of heavy REEs increases relatively, and positive Ce-anomaly appears. But, negative Ce-anomaly was found in calcium concretions, while normal Ce content in parent rocks and vertisol.
