Effects of Temperature and Catalyst to Oil Weight Ratio on the Catalytic Conversion of Heavy Oil to Propylene Using ZSM-5 and USY Catalysts

It is useful for practical operation to study the rules of production of propylene by the catalytic conversion of heavy oil in FCC （fluid catalytic cracking）. The effects of temperature and C/O ratio （catalyst to oil weight ratio） on the distribution of the product and the yield of propylene were investigated on a micro reactor unit with two model catalysts, namely ZSM-5/Al2O3 and USY/Al2O3, and Fushun vacuum gas oil （VGO） was used as the feedstock. The conversion of heavy oil over ZSM-5 catalyst can be comparable to that of USY catalyst at high temperature and high C/O ratio. The rate of conversion of heavy oil using the ZSM-5 equilibrium catalyst is lower compared with the USY equilibrium catalyst under the general FCC conditions and this can be attributed to the poor steam ability of the ZSM-5 equilibrium catalyst. The difference in pore topologies of USY and ZSM-5 is the reason why the principal products for the above two catalysts is different, namely gasoline and liquid petroleum gas （LPG）, repspectively. So the LPG selectivity, especially the propylene selectivity, may decline if USY is added into the FCC catalyst for maximizing the production of propylene. Increasing the C/O ratio is the most economical method for the increase of LPG yield than the increase of the temperature of the two model catalysts, because the loss of light oil is less in the former case. There is an inverse correlation between HTC （hydrogen transfer coefficient） and the yield of propylene, and restricting the hydrogen transfer reaction is the more important measure in increasing the yield of propylene of the ZSM-5 catalyst. The ethylene yield of ZSM-5/A1203 is higher, but the gaseous side products with low value are not enhanced when ZSM-5 catalyst is used. Moreover, for LPG and the end products, dry gas and coke, their ranges of reaction conditions to which their yields are dependent are different, and that of end products is more severe than that of LPG. So it is clear that maximizing LPG and propylene and restricting dry gas and coke can be both achieved via increasing the severity of reaction conditions among the range of reaction conditions which LPG yield is sensitive to.

Graft-to-recipient weight ratio lower to 0.7% is safe without portal pressure modulation in right-lobe living donor liver transplantation with favorable conditions

BACKGROUND: The low graft-to-recipient weight ratio(GRWR) in adult-to-adult living donor liver transplantation(LDLT) is one of the major risk factors affecting graft survival. The goal of this study was to evaluate whether the lower limit of the GRWR can be safely reduced without portal pressure modulation in right-lobe LDLT. METHODS: From 2005 to 2011, 317 consecutive patients from a single institute underwent LDLT with right-lobe grafts without portal pressure modulation. Of these, 23 had a GRWR of less than 0.7%(group A), 27 had a GRWR of ≥0.7%, 【0.8%(group B), and 267 had a GRWR of more than and equal to 0.8%(group C). Medical records, including recipient, donor, operation factors, laboratory findings and complications were reviewed retrospectively. RESULTS: The baseline demographics showed low model for end-stage liver disease score(mean 16.3±8.9) and high percentage of hepatocellular carcinoma(231 patients, 72.9%). Three groups by GRWR demonstrated similar characteristics except recipient body mass index and donor gender. For smallforsize syndrome, there were 3(13.0%) in group A, 1(3.7%) in group B, and 2 patients(0.7%) in group C(P【0.001). Hepatic artery thrombosis was more frequently observed in group A than in groups B and C(8.7% vs 3.7% vs 1.9%, P=0.047). However, among the three groups, graft survival rates at 1 year(100% vs 96.3% vs 93.6%) and 3 years(91.7% vs 73.2% vs 88.1%) were not different(P=0.539). In laboratory measurements,there was no group difference in total bilirubin and albumin. However, prothrombin time was longer in group A within postoperative 1 week and platelet count was lower in groups A and B within postoperative 1 month. CONCLUSION: A GRWR lower to 0.7% is safe and does not need to modulate portal pressure in adult-to-adult LDLT using the right-lobe in favorable conditions including low model for end-stage liver disease score.

Feasibility study on buoyancy-weight ratios of a submerged floating tunnel prototype subjected to hydrodynamic loads

The research progress of a novel traffic solution,a submerged floating tunnel（SFT）,is reviewed in terms of a study approach and loading scenario.Among existing publications,the buoyancy-weight ratio（BWR） is usually predefined.However,BWR is a critical structural parameter that tremendously affects the dynamic behaviour of not only the tunnel tube itself but also the cable system.In the context of a SFT prototype（SFTP） project in Qiandao Lake（Zhejiang Province,China）,the importance of BWR is illustrated by finite element analysis and subsequently,an optimized BWR is proposed within a reasonable range in the present study.In the numerical model,structural damping is identified to be of importance.Rayleigh damping and the corresponding Rayleigh coefficients are attained through a sensitivity study,which shows that the adopted damping ratios are fairly suitable for SFTP.Lastly,the human sense of security is considered by quantifying the comfort index,which helps further optimize BWR in the SFTP structural parameter design.

Successful living donor liver transplantation with a graft-to-recipient weight ratio of 0.41 without portal flow modulation:A case report

BACKGROUND There have been numerous efforts to lower the limit of minimum graft size to meet the metabolic demand of recipients in adult-to-adult living donor liver transplantation(LDLT).We experienced a successful case of LDLT using a verysmall-for-size graft without portal flow modulation such as splenectomy or portocaval shunt.CASE SUMMARY A 49-year-old man(weighing 91 kg)suffering hepatocellular carcinoma accompanied with hepatitis B virus related cirrhosis underwent LDLT.The one and only voluntary donor was his 17-year-old daughter whose body weight was 50 kg with a body mass index(BMI)of 18.3.The procured right liver graft was 411 g with a real graft-to-recipient weight ratio(GRWR)of 0.41%,the smallest to be reported in the literature.Both the recipient and donor had an uneventful recovery and were discharged on days 15 and 8,respectively,with normal liver function.The father and daughter have had no complication so far and are still in good health with normal liver function 81 mo after LDLT.CONCLUSION Satisfactory outcomes can be achieved in LDLT with a GRWR as low as 0.41%even without using portal flow modulation in highly selected patients.

Effect of Fiber Weight Ratio and Fiber Modification on Flexural Properties of Posidonia-Polyester Composites

The main objective of this research is to study the effect of fiber weight ratio and chemical fiber modification on flexural properties of composites reinforced with Posidonia fiber. An unsaturated polyester matrix reinforced with untreated and treated Posidonia fibers was fabricated under various fiber weight ratios. Results showed that the combined chemical treatment provided better mechanical properties of composites in comparison with untreated fiber. The fiber weight ratio influenced the flexural properties of composites. Indeed, a maximum value of flexural modulus was observed for 10% fiber weight ratio for composites reinforced with treated fibers. SEM photographs revealed a different fracture surface between Posidonia fibers reinforced polyester composites.

Effects of Fiber Weight Ratio, Structure and Fiber Modification onto Flexural Properties of Luffa-Polyester Composites

The effect of chemical modification, reinforcement structure and fiber weight ratio on the flexural proprieties of Luffa-polyester composites was studied. A unsaturated polyester matrix reinforced with a mat of Luffa external wall fibers (ComLEMat), a short Luffa external wall fibers(ComLEBC) and a short Luffa core fi-bers (ComLCBC) was fabricated under various conditions of fibers treatments (combined process, acetylat-ing and cyanoethylating) and fiber weight ratio. It resorts that acetylating and cyanoethylating enhance the flexural strength and the flexural modulus. The fiber weight ratio influenced the flexural properties of com-posites. Indeed, a maximum value of strength and strain is observed over a 10% fiber weight ratio. The uses of various reinforcement structures were investigated. The enhancement of elongation at break and the strain values of the composite reinforced by natural mat was proved.

Intoxication Induced by Urea Containing Diets in Broiler Chickens: Effect on Weight Gain, Feed Conversion Ratio, Hematological and Biochemical Profiles

Urea as a source of cheap non-protein nitrogen is used to adulterate fish and meat meals which are basic components of broiler diets. The present study was carried out to elucidate the effects of urea on weight gain, and hematological and biochemical profiles. A total of 48 broiler chicks were randomly allotted into 4 groups, designated Groups 1, 2, 3 and 4 of 12 birds each. Birds in Groups 2, 3 and 4 were fed on diets containing urea at the levels of 1%, 2.5% and 4%, respectively. Birds in Group 1 served as control and were not exposed to urea. Experimentation period was for 3 weeks and experiment was terminated when birds were 42 days of age. Body weight of all intoxicated birds at the various intervals was significantly decreased in comparison with that of the untreated control. Compared with control, all intoxicated broilers manifested significant (P ≤ 0.05) decrease in all hematological parameters involving erythrocytic and total leucocytic counts, Hemoglobin (Hb) and Packed Cell Volume (PCV) on a dose- and time-pattern. In comparison with the control levels, biochemical profile of the intoxicated birds disclosed significant decrease in blood glucose level and significant increase in serum uric acid, urea, Alkaline Phosphatase (ALP) and Lactate Dehydrogenase (LDH) levels. Based upon the present data, it was concluded that the addition of urea to broiler diets bears serious sequences concerning the general health condition, performance, weight gain, and hematological and biochemical profiles.

Dynamic genetic analysis for body weight and main length ratio in turbot Scophthalmus maximus

The objective of this study was to estimate genetic parameters of body width(BW)to body length(BL)ratio(BW/BL)and of body weight traits(BWT)in turbot,and to elucidate the genetic mechanism of the two traits during ontogeny by dynamic genetic analysis.From 3 to 27 months,BW,BL and BWT of each communally stocked fish were measured every 3 months.The BW/BL ratio was measured at different sampling ages.A twotrait animal model was used for genetic evaluation of traits.The results showed that the heritability values of BW/BL ratio ranged from 0.2168 to 0.3148,corresponding to moderate heritability.The BWT heritability values ranged from 0.2702 to 0.3479 corresponding to moderate heritability.The heritability of BW/BL ratio was lower than that of BWT,except at 3 months of age.Genetic correlation between BW/BL ratio and BWT decreased throughout the measurement period.Genetic correlations were higher than the phenotypic correlations.The current results for estimating genetic parameters demonstrate that the BW/BL ratio could be used as a phenotypic marker of fast-growing turbot,and the BW/BL ratio and BWT could be improved simultaneously through selective breeding.

加权断层泥比率法(WSGR)定量判别断层封闭性——以苏北盆地高邮凹陷永安地区为例

断层封闭性评价是断块圈闭成藏条件分析的重要内容,在改进断层泥比率法基础上,提出了一种新的断层封闭性评价方法——加权断层泥比率法(WSGR)。首先,通过不同的地质模型开展断层泥比率法计算参数及影响因素分析,明确了断层断距、泥质含量及泥岩分布特征是泥岩涂抹的重要影响因素;并认为断层断距范围内,滑过目标位置的对置盘所有泥质含量都具有涂抹贡献,但不同点的涂抹贡献不同,距离目标位置越近泥质含量越高的对置盘泥岩点,其涂抹贡献越大。为此引入了一个新的表征参数——距离系数,定义为断层断距与各泥岩点到目标位置距离的差与断层断距的比值,来表征泥岩分布对泥岩涂抹的影响作用;在此基础上,构建了加权断层泥比率计算方法,定义为各点的泥质含量与距离系数的乘积之和再与距离系数之和的比值。利用加权断层泥比率法对苏北盆地高邮凹陷上含油气系统已知的油水层进行封闭性验证,认为当加权断层泥比率值大于0.6时,断层具有较好的封闭性,从而确定了该方法的封闭性判别标准。在高邮凹陷永安等地区始新统戴南组断层封闭性评价中取得了较好应用效果。

Therapeutic effect of nerve growth factor on cerebral infarction in dogs using the hemisphere anomalous volume ratio of diffusion-weighted magnetic resonance imaging

A model of focal cerebral ischemic infarction was established in dogs through middle cerebral artery occlusion of the right side.Thirty minutes after occlusion,models were injected with nerve growth factor adjacent to the infarct locus.The therapeutic effect of nerve growth factor against cerebral infarction was assessed using the hemisphere anomalous volume ratio,a quantitative index of diffusion-weighted MRI.At 6 hours,24 hours,7 days and 3 months after modeling,the hemisphere anomalous volume ratio was significantly reduced after treatment with nerve growth factor. Hematoxylin-eosin staining,immunohistochemistry,electron microscopy and neurological function scores showed that infarct defects were slightly reduced and neurological function significantly improved after nerve growth factor treatment.This result was consistent with diffusion-weighted MRI measurements.Experimental findings indicate that nerve growth factor can protect against cerebral infarction,and that the hemisphere anomalous volume ratio of diffusion-weighted MRI can be used to evaluate the therapeutic effect.

Minimum MSE Weighted Estimator to Make Inferences for a Common Risk Ratio across Sparse Meta-Analysis Data

The paper aims to discuss three interesting issues of statistical inferences for a common risk ratio (RR) in sparse meta-analysis data. Firstly, the conventional log-risk ratio estimator encounters a number of problems when the number of events in the experimental or control group is zero in sparse data of a 2 × 2 table. The adjusted log-risk ratio estimator with the continuity correction points based upon the minimum Bayes risk with respect to the uniform prior density over (0, 1) and the Euclidean loss function is proposed. Secondly, the interest is to find the optimal weights of the pooled estimate that minimize the mean square error (MSE) of subject to the constraint on where , , . Finally, the performance of this minimum MSE weighted estimator adjusted with various values of points is investigated to compare with other popular estimators, such as the Mantel-Haenszel (MH) estimator and the weighted least squares (WLS) estimator (also equivalently known as the inverse-variance weighted estimator) in senses of point estimation and hypothesis testing via simulation studies. The results of estimation illustrate that regardless of the true values of RR, the MH estimator achieves the best performance with the smallest MSE when the study size is rather large and the sample sizes within each study are small. The MSE of WLS estimator and the proposed-weight estimator adjusted by , or , or are close together and they are the best when the sample sizes are moderate to large (and) while the study size is rather small.

基于视觉信息加工的草原公路行车安全性分析

为探究草原公路各典型行车环境驾驶人视觉信息加工模式的差异性,从视觉层面解析草原公路行车安全,基于眼动仪开展草原公路实车实验,提取驾驶人在自由行驶、跟驰、对向来车、后车切入、路侧风险、交叉口6种真实行车环境下的眼动数据。首先,从视觉分配和视觉搜索两个维度构建评价指标体系,采用动态聚类法将驾驶人的视觉兴趣区域划分为5类,将信息熵与马尔可夫链平稳分布理论结合,构建视点分布信息熵量化驾驶人视觉注意分配的复杂度,并引入扫视幅度、扫视速度分析驾驶人对视觉信息的搜索过程。最后,构建基于CRITIC法的加权秩和比评价模型,对不同行车环境下驾驶人的视觉信息加工强度进行了综合评价。结果显示:驾驶人的视点分布在不同行车环境中存在差异,但当前车道始终是驾驶人获取视觉信息的主视区;各视觉评价指标随行车环境的变化呈显著的统计学差异;驾驶人遇到路侧风险时的视觉信息加工强度最大,行车安全性相对更低。

中国城市经济韧性的水平、耦合协调度与空间分布特征

中国经济的强韧性是防范风险的最有力支撑。以全国282个城市为研究样本,采用熵权法与加权秩和比法测算中国城市经济韧性水平,在此基础上利用耦合协调模型、空间自相关模型研究中国城市经济韧性三大子系统的耦合协调度,分析其空间分布的整体特征。研究发现:2011—2019年,中国城市经济韧性整体处在中等水平且呈现缓慢上升趋势,同时区域差异较大;中国城市经济韧性总体处于中级协调阶段,但各地区三大子系统耦合协调度及其增长情况有所不同;中国城市经济韧性的耦合协调度在空间分布上具有正相关性,且呈现显著的空间集聚特征和方向性。由此建议采取措施扎实推进城市经济韧性及城市经济韧性耦合协调度的全方位提升,提高区域经济的整体发展水平。

辽宁省农村三产融合综合评价研究

农村一二三产融合是实现乡村振兴和农业农村现代化的重要手段,有利于农村经济的高质量发展.辽宁省农村一二三产融合在空间上分布不均衡,运用熵权法和秩和比综合评价法研究农村三产融合综合水平,对于辽宁省三产融合高质量发展具有理论与现实意义.首先分析了辽宁省2012—2021年农村三产融合水平的时序变化,然后以2021年为例对辽宁省14地市农村三产融合水平的空间差异进行研究.结果表明:从时间特征来看,辽宁省2012—2021年农村一二三产融合综合水平总体呈上升趋势,受2016年中国经济呈现的放缓态势的影响,2016年融合水平出现明显下降;从空间特征来看,2021年辽宁省农村一二三产融合综合水平各地存在空间差异,其中大连排名第一,沈阳次之,抚顺、营口、辽阳排名靠后,前后存在较大差距.采用障碍度模型计算障碍因子,各地应立足自身优势,弥补不足,关注生产效率和产业链延伸的同时更要注重社会效益和绿色可持续发展,推进辽宁农村三产业融合整体发展.

低烈度区某超高层塔楼优化分析

超高层建筑由于单塔体量较大,结构经济指标备受关注,寻找最合理结构体系是超高层建筑不断自我迭代更新的主题。高烈度区和低烈度区塔楼控制方向完全不同,着重介绍优化过程以寻找低烈度区超高层塔楼的最优结构。以某位于低烈度6度区的建筑高度250m超高层塔楼为例,根据塔楼初步方案确定控制指标为刚重比和剪重比,以控制指标为目标进行附加质量和自重的迭代优化。其次是提高结构刚度,核心筒尺寸根据竖向交通及设备管井已确定,在建筑允许条件下通过柱的不同排布实现了更好的框架刚度贡献;纯混凝土柱重量贡献大于刚度贡献,通过对比叠合柱和型钢柱,选取了更合理的叠合柱截面形式;在低烈度区结构竖向承载满足基本需求而水平刚度不满足规范要求的情况下,通过增加伸臂桁架提高整体刚度;通过分析不同伸臂桁架形式,选取了最有效的伸臂形式。通过降低结构冗余重量和有效提高结构刚度选出最高效结构,且建筑品质优、造价合理。

基于特征判定系数的电力变压器振动信号故障诊断

变压器带电故障诊断对于保证电力变压器安全平稳运行具有重要的意义。针对变压器工作环境复杂且单一参数表征变压器故障类型不全面的问题,文中提出一种基于自适应噪声完备集合经验模态分解(complete ensemble empirical mode decomposition with adaptive noise,CEEMDAN)和特征熵权法(entropy weight method,EWM)进行故障诊断的方法。通过相关系数与峭度加权(correlation coefficient and weighted kurtosis,CCWK)原则筛选CEEMDAN分量并重构信号,在实现剔除冗余分量的同时,提升变压器振动信号特征的表征能力;利用EWM构建特征判定系数实现单一数据诊断变压器故障类型;通过主成分分析法减小混合域特征尺度,采用鸡群优化算法优化支持向量机(support vector machine,SVM)模型进行故障诊断。对某变电站110 kV三相油浸式变压器进行分析,结果表明与概率神经网络和SVM等变压器故障诊断方法相比,文中方法能在提前定性故障类型的同时,进一步提高变压器故障诊断的准确率与效率。

咸淡水组合灌溉对土壤盐分和棉花生长的影响

为揭示不同微咸水(农田排水)与淡水在“先咸后淡”的组合灌溉模式下对土壤容重、盐分迁移和棉花生长的影响。以淡水灌溉为对照(CK),设置7种不同微咸水、淡水组合灌溉(微咸水∶淡水=1∶14(T1)、2∶13(T2)、3∶12(T3)、6∶9(T4)、9∶6(T5)、12∶3(T6)),T7处理采用全额微咸水灌溉,于2022年4-9月进行了棉花田间试验。结果表明,采用微咸水灌溉造成土壤表层盐分积累,0~40 cm土层出现积盐现象,棉花生育期结束后,各处理与淡水对照(CK)比较,T1~T6在0~40 cm土层的电导率分别增加1.16%~26.61%,T7处理电导率增加86.40%;与淡水对照相比,组合灌溉后各处理土层0~40 cm土壤容重明显增加,土壤孔隙度降低,以全额微咸水灌溉T7处理最为显著(容重增加10.24%);微咸水组合灌溉有效提高棉花株高、叶面积指数、茎粗。合理利用微咸水组合灌溉能够为棉花生长提供良好的水盐环境,提高棉花产量,能够为极端干旱区合理利用微咸水提供一种新的灌水模式,为灌区发展节水灌溉及农业可持续发展提供理论支撑。

车齿面齿轮残余应力加工参数优化

为了实现对车齿加工参数的合理控制,以20CrMnTi面齿轮为研究对象,以转速、进给速度、切削深度为主要加工参数设计正交试验。通过信噪比基本特性计算加工参数的变异系数,分析加工参数对面齿轮齿廓间残余应力的影响程度;利用熵权理论对面齿轮性能的客观需求进行修正,得到齿廓间残余应力的综合熵权;通过灰色理论与综合熵权计算齿廓残余应力的综合灰色关联度,建立2阶响应预测模型并进行方差分析,最终得到最优加工参数组合。结果表明,加工参数对面齿轮齿廓间残余应力的影响程度为:转速>切削深度>进给速度。齿廓间残余应力的综合熵权为:齿根残余应力权重W_(1)=0.3005,分度圆残余应力权重W_(2)=0.5002,齿顶残余应力权重W_(3)=0.1993。最优加工参数组合为:转速=340r/min,进给速度=17mm/min,切削深度=0.25mm。

基于加权密切值法的山东省健康管理服务评价研究

目的:以山东省三级综合医院为切入点,研究目前健康管理服务实施现状,探索其中存在的问题,为出台有关政策措施、提升健康管理服务能力提供依据。方法:在山东各地市随机抽取25家设有健康管理中心或体检中心的三级综合医院,对其健康管理服务现状进行问卷调查;采用加权密切值法和秩和比法两种方法对三级综合医院健康管理服务能力进行评价分档,并根据不同分档医院的健康管理服务能力绘制雷达图,探索薄弱环节。结果:(1)综合评价分档排序中2家医院处于优档,13家医院为中档,3家医院为差档;分别约占11.11%、72.22%、16.67%。(2)同一地市不同三级综合医院健康管理服务能力差异较大。(3)通过“雷达图”直观反映,三档中差档在投入、过程、产出、效果指标方面均与其他两档具有明显差异。结论:政府应加强顶层设计,提升区域内健康管理服务标准化建设;激励三级综合医院发挥骨干带头作用,与医联体各成员单位多项联动,合理构建全域健康管理服务新体系。

混凝土结构设计中常见的稳定问题

混凝土结构的稳定问题受重视程度不及钢结构,本文对比中国、欧洲、美国和新西兰的混凝土设计规范中关于结构整体稳定、构件稳定的条文,并结合示例和公式推导,给出相关设计建议。对于整体稳定,刚重比数值受侧向合力位置、建筑重力大小及位置的影响,不应简单地以刚重比的数值来评判不同建筑的整体稳定性。对于构件稳定,分析了几个常见而易被忽视的问题。穿层柱及支撑连桥的框架柱宜考虑二阶效应;对于大跨度梁和长悬臂梁可借鉴外国规范,控制梁的高宽比和侧向无支撑长度;通过数值屈曲分析来反算柱子计算长度时,应正确施加荷载;国内对墙肢的稳定限制较严,对比墙肢的稳定等效荷载与轴压比限值荷载,给出了楼梯间外墙和L形剪力墙的截面由稳定控制的临界高度。