Underwater gas self-transportation along femtosecond laser-written open superhydrophobic surface microchannels(<100μm)for bubble/gas manipulation

Underwater transportation of bubbles and gases has essential applications in manipulating and using gas,but achieving this function at the microscopic level remains a significant challenge.Here,we report a strategy to self-transport gas in water along a laser-induced open superhydrophobic microchannel with a width less than 100μm.The femtosecond laser can directly write superhydrophobic and underwater superaerophilic microgrooves on the polytetrafluoroethylene(PTFE)surfaces.In water,the single laser-induced microgroove and water medium generate a hollow microchannel.When the microchannel connects two superhydrophobic regions in water,the gas spontaneously travels from the small region to the large area along this hollow microchannel.Gas self-transportation can be extended to laser-drilled microholes through a thin PTFE sheet,which can even achieve anti-buoyancy unidirectional penetration.The gas can overcome the bubble’s buoyance and spontaneously travel downward.The Laplace pressure difference drives the processes of spontaneous gas transportation and unidirectional bubble passage.We believe the property of gas self-transportation in the femtosecond laser-structured open superhydrophobic and underwater superaerophilic microgrooves/microholes has significant potential applications related to manipulating underwater gas.

Options for Greenhouse Gas Mitigation Strategies for Road Transportation in Oman

Oman is a fast developing country where about 76% of registered vehicles as of 2014 were private cars with approximately one private car per household. The growth of automobile is faster than the growth of human population. From 2000-2009, Omani population has increased by 2% per annum while automobile usage in the country has increased by 4.3%. The leadership of Sultanate of Oman has pledged to cut down greenhouse (GHG) emissions by 2% as a commitment to United Nation Framework Convention on Climate Change (UNFCCC). Due to very limited public transportation system, traffic congestion and emission from vehicles are high during working days since majority of individuals uses private vehicles as only means of transport. This paper seeks to combine mitigation measures adopted in selected Middle East and North Africa (MENA) and UNFCCC to suggest cost-effective measures suitable in reducing GHG emissions from road transportation sector in Oman. These measures will specifically reduce vehicular emissions during working days where car occupancy rates are very low in an economically sustainable way.

The Research about Storage and Transportation of Natural Gas Based on LNG Technology

Nowadays, we are in great lack of the technology theory for the storage and transportation of gas hydrate. Under this condition, after checking out related theory of these, we established the technology roadmap of the storage and transportation of gas hydrate by LNG technology. Study has shown that the technology of LNG is more saving than that of pipeline. Then we came out with the new idea of storage and transportation of hydrate by LNG technology.

Large Potential Exists in China's Oil & Gas Transportation System

As China in the decades ahead is to go through significant reorganization in the power sector and the petrochemical industry will see considerable growth,the transportation infrastructure for petroleum and gas should have a new shape. Implementing the largest infrastructure projects and creating on this basis a modern transportation network will not only see a new reincarnation of traditional industrial centers, but also open wider opportunities for regional development.

The challenges facing the oil and gas storage and transportation technology and its developing direction

In recent years, our country is increasingly dependent on the use of the oil resources, and the degree of the oil mining is also continuously upgrading. After the completion of the tasks related to the oil mining in the lands, the technologies for the development of the offshore oil mining are particularly important. Among these problems, after the exploitation, the storage and transportation of the offshore oil and gas is worthy of the discussion of the technical personnel. From the experience of the oil and gas storage and transportation in the long years, in some environmentally degraded areas, there are problems in the efficiency and safety in the long pipeline transportation and the oil and gas mixed transportation, and in the transportation, there are also big shortcomings. In this paper, the author carries on the analysis of the existing questions encountering in our country＇s oil and gas storage and transportation~ and proposes the direction of the researches in the future oil and gas storage and transportation, and the purpose is to better improve the security of Cbina＇s oil and gas storage and transportation and to enhance the efficiency of the use of the oil and gas.

The development status and the prospect of the pipeline robots in the oil and gas storage and transportation industry

In the process of the constant development of the oil and gas storage and transportation technology, the maintenance of the large pipelines is an important task. At present, China vigorously promotes the use of the pipeline robots, for the maintenance of the oil and gas pipelines by the unique characteristics of the robots. In this paper, the author carries out the detailed analysis on the current situation of the development of the pipeline robots in the oil and gas storage and transportation industry, and compares the different applications of the pipeline robots at home and abroad. Starting from the principles of the operation of the robots, the author analyzes the characteristics of the different types of the robots, and combined with the existing conditions of the oil and gas storage and transportation in our country, the author tries to find the most favorable way of the working of the pipeline robots, to continuously improve the development of the oil and gas storage and transportation industry using the robot technologies.

2013 Production of China's Shale Gas Reaches 200 Million Cubic Meters and the First Transportation Pipeline Constructed

Results of the global shale gas resources show that minable resources of global shale gas are 187 trillion cubic meters （tern）, of which China accounts for 36 tcm （about 20% of the total amount）, which is mainly distributed in the Sichuan Basin, Yangtze Terrace, and Ordos Basin. From 2009 to 2012, China completed an accumulative number of 129 drilling wells related to shale gas, including 46 investigated vertical wells, 55 exploration wells and 28 evaluation wells, with 2012 production ranging from 25 million cubic meters （mcm） to 30 mcm.

Current State and Prospects of CNPC's Oil and Gas Storage and Transportation

Oil and gas transportation facilities are important for a country to secure an energy supply and maintain social stability and economic development.Social capitals in China are now encouraged by the government to invest in the construction of oil and gas infrastructures in the country.With China's growing economy and new reforms in the oil and gas sector,more opportunities are available for private companies seeking to get involved in energy infrastructure.It is estimated that the future market of energy infrastructure projects in China is valued at nearly RMB 2 trillion.This paper is trying to offer some clues regarding investment in energy infrastructure in China by giving a brief introduction to the current situation of CNPC's oil and gas infrastructure construction.

Main Indexes of Pipeline Transportation of Crude Oil and Gas

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Reform Exploration for Safety Course System of Oil and Gas Storage and Transportation Facilities

In recent years,the safety of oil and gas storage and transportation facilities has been paid more attention by the state and enterprises due to frequent accidents.The oil and gas storage and transportation facilities safety courses in China University of Petroleum(Beijing)includes“Engineering mechanics”,“Strength design of pipelines and tanks”and“Safety and integrity management of oil and gas storage and transportation facilities”.The three courses lack relevance and the teaching mode is too rigid,resulting in students losing their initiative in learning.If students can’t use the knowledge flexibly,it will affect the achievement of the objectives of the training program.Therefore,oil and gas storage and transportation facilities safety courses are reformed,training plans are adjusted and teaching methods are improved.The practice shows that the reform enriches the teaching content,improves the teaching quality,stimulates classroom activity and gets a good evaluation of students.The reform of safety courses has a certain significance for cultivating compound talents who have the ability to solve practical problems in engineering.

Influence of Al Composition on Transport Properties of Two-Dimensional Electron Gas in Al_xGa_(1-x)N/GaN Heterostructures

Magnetotransport properties of two-dimensional electron gases （2DEG） in AlxGa1-x N/GaN heterostructures with different Al compositions are investigated by magnetotransport measurements at low temperatures and in high magnetic fields. It is found that heterostructures with a lower Al composition in the barrier have lower 2DEG concentration and higher 2DEG mobility.

Numerical simulation of gas transport mechanisms in tight shale gas reservoirs

Due to the nanometer scale pore size and extremely low permeability of a shale matrix,traditional Darcy＇s law can not exactly describe the combined gas transport mechanisms of viscous flow and Knudsen diffusion.Three transport models modified by the Darcy equation with apparent permeability are used to describe the combined gas transport mechanisms in ultra-tight porous media,the result shows that Knudsen diffusion has a great impact on the gas transport and Darcy＇s law cannot be used in a shale matrix with a pore diameter less than 1 μm.A single porosity model and a double porosity model with consideration of the combined gas transport mechanisms are developed to evaluate the influence of gas transport mechanisms and fracture parameters respectively on shale gas production.The numerical results show that the gas production predicted by Darcy＇s law is lower than that predicted with consideration of Knudsen diffusion and the tighter the shale matrix,the greater difference of the gas production estimates.In addition,the numerical simulation results indicate that shale fractures have a great impact on shale gas production.Shale gas cannot be produced economically without fractures.

Mechanism model for shale gas transport considering diffusion, adsorption/desorption and Darcy flow

To improve the understanding of the transport mechanism in shale gas reservoirs and build a theoretical basic for further researches on productivity evaluation and efficient exploitation, various gas transport mechanisms within a shale gas reservoir exploited by a horizontal well were thoroughly investigated, which took diffusion, adsorption/desorption and Darcy flow into account. The characteristics of diffusion in nano-scale pores in matrix and desorption on the matrix surface were both considered in the improved differential equations for seepage flow. By integrating the Langmuir isotherm desorption items into the new total dimensionless compression coefficient in matrix, the transport function and seepage flow could be formalized, simplified and consistent with the conventional form of diffusion equation. Furthermore, by utilizing the Laplace change and Sethfest inversion changes, the calculated results were obtained and further discussions indicated that transfer mechanisms were influenced by diffusion, adsorption/desorption. The research shows that when the matrix permeability is closed to magnitude of 10^-9D, the matrix flow only occurs near the surfacial matrix; as to the actual production, the central matrix blocks are barely involved in the production; the closer to the surface of matrix, the lower the pressure is and the more obvious the diffusion effect is; the behavior of adsorption/desorption can increase the matrix flow rate significantly and slow down the pressure of horizontal well obviously.

Transport model for shale gas well leakage through the surrounding fractured zones of a longwall mine

The environmental risks associated with casing deformation in unconventional(shale)gas wells positioned in abutment pillars of longwall mines is a concern to many in the mining and gas well industry.With the recent interest in shale exploration and the proximity to longwall mining in Southwestern Pennsylvania,the risk to mine workers could be catastrophic as fractures in surrounding strata create pathways for transport of leaked gases.Hence,this research by the National Institute for Occupational Safety and Health(NIOSH)presents an analytical model of the gas transport through fractures in a low permeable stratum.The derived equations are used to conduct parametric studies of specific transport conditions to understand the influence of stratum geology,fracture lengths,and the leaked gas properties on subsurface transport.The results indicated that the prediction that the subsurface gas flux decreases with an increase in fracture length is specifically for a non-gassy stratum.The sub-transport trend could be significantly impacted by the stratum gas generation rate within specific fracture lengths,which emphasized the importance of the stratum geology.These findings provide new insights for improved understanding of subsurface gas transport to ensure mine safety.

Three-phase flow of submarine gas hydrate pipe transport

In the hydraulic transporting process of cutter-suction mining natural gas hydrate, when the temperature-pressure equilibrium of gas hydrate is broken, gas hydrates dissociate into gas. As a result, solid-liquid two-phase flow(hydrate and water) transforms into gas-solid-liquid three-phase flow(methane, hydrate and water) inside the pipeline. The Euler model and CFD-PBM model were used to simulate gas-solid-liquid three-phase flow. Numerical simulation results show that the gas and solid phase gradually accumulate to the center of the pipe. Flow velocity decreases from center to boundary of the pipe along the radial direction. Comparison of numerical simulation results of two models reveals that the flow state simulated by CFD-PBM model is more uniform than that simulated by Euler model, and the main behavior of the bubble is small bubbles coalescence to large one. Comparison of numerical simulation and experimental investigation shows that the values of flow velocity and gas fraction in CFD-PBM model agree with experimental data better than those in Euler model. The proposed PBM model provides a more accurate and effective way to estimate three-phase flow state of transporting gas hydrate within the submarine pipeline.

GAS BUBBLE-FACILITATED TRANSPORT OF METALS IN LITHOSPHERE

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COMPETITIVE FACILITATED TRANSPORT OF ACID GASES IN MODIFIED CARRIER MEMBRANES

1 INTRODUCTIONMany attempts to develop semipermeable membranes for gas separation have beendone over the past twenty years [1,2].However,it is still difficult to prepare apolymer film which makes certain gas separation processed within range of being econ-omically and technically feasible,since most polymeric materials are relativelyimpermeable to gases.Facilitated transport concept which was first proposed

Analysis of gas transport behavior in organic and inorganic nanopores based on a unified apparent gas permeability model

Different from the conventional gas reservoirs,gas transport in nanoporous shales is complicated due to multiple transport mechanisms and reservoir characteristics.In this work,we presented a unified apparent gas permeability model for real gas transport in organic and inorganic nanopores,considering real gas effect,organic matter(OM)porosity,Knudsen diffusion,surface diffusion,and stress dependence.Meanwhile,the effects of monolayer and multilayer adsorption on gas transport are included.Then,we validated the model by experimental results.The influences of pore radius,pore pressure,OM porosity,temperature,and stress dependence on gas transport behavior and their contributions to the total apparent gas permeability(AGP)were analyzed.The results show that the adsorption effect causes Kn(OM)>Kn(IM)when the pore pressure is larger than 1 MPa and the pore radius is less than 100 nm.The ratio of the AGP over the intrinsic permeability decreases with an increase in pore radius or pore pressure.For nanopores with a radius of less than 10 nm,the effects of the OM porosity,surface diffusion coefficient,and temperature on gas transport cannot be negligible.Moreover,the surface diffusion almost dominates in nanopores with a radius less than 2 nm under high OM porosity conditions.For the small-radius and low-pressure conditions,gas transport is governed by the Knudsen diffusion in nanopores.This study focuses on revealing gas transport behavior in nanoporous shales.

Investigation of the performance of CF3I/c-C4F8/N2 and CF3I/c-C4F8/CO2 gas mixtures from electron transport parameters

CF3I gas mixtures have attracted considerable attention as potential environmentally-friendly alternatives to SF6 gas,owing to their excellent insulating performance.This paper attempts to study the CF3I ternary gas mixtures with c-C4F8 and buffer gases N2 and CO2 by considering dielectric strength from electron transport parameters based on the Boltzmann method and synergistic effect analysis,compared with SF6 gas mixtures.The results confirm that the critical electric field strength of CF3I/c-C4F8/70%CO2 is greater than that of 30%SF6/70%CO2 when the CF3I content is greater than 17%.Moreover,a higher content of c-C4F8 decreases the sensitivity of gas mixtures to an electric field,and this phenomenon is more obvious in CF3I/c-C4F8/CO2 gas mixtures.The synergistic effects for CF3I/c-C4F8/70%N2 were most obvious when the c-C4F8 content was approximately 20%,and for CF3I/c-C4F8/70%CO2 when the c-C4F8 content was approximately 10%.On the basis of this research,CF3I/c-C4F8/70%N2 shows better insulation performance when the c-C4F8 content is in the15%–20%range.For CF3I/c-C4F8/70%CO2,when the c-C4F8 content is in the 10%–15%range,the gas mixtures have excellent performance.Hence,these gas systems might be used as alternative gas mixtures to SF6 in high-voltage equipment.

CFD simulation of effect of anode configuration on gas–liquid flow and alumina transport process in an aluminum reduction cell

Numerical simulations of gas–liquid two-phase flow and alumina transport process in an aluminum reduction cell were conducted to investigate the effects of anode configurations on the bath flow, gas volume fraction and alumina content distributions. An Euler–Euler two-fluid model was employed coupled with a species transport equation for alumina content. Three different anode configurations such as anode without a slot, anode with a longitudinal slot and anode with a transversal slot were studied in the simulation. The simulation results clearly show that the slots can reduce the bath velocity and promote the releasing of the anode gas, but can not contribute to the uniformity of the alumina content. Comparisons of the effects between the longitudinal and transversal slots indicate that the longitudinal slot is better in terms of gas–liquid flow but is disadvantageous for alumina mixing and transport process due to a decrease of anode gas under the anode bottom surface. It is demonstrated from the simulations that the mixing and transfer characteristics of alumina are controlled to great extent by the anode gas forces while the electromagnetic forces(EMFs) play the second role.