Solidification/stabilization (S/S) is one of the most effective methods of dealing with heavy metal contaminated soils. The effects of cyclic wetting and drying on solidified/stabilized contaminated soils were inves...Solidification/stabilization (S/S) is one of the most effective methods of dealing with heavy metal contaminated soils. The effects of cyclic wetting and drying on solidified/stabilized contaminated soils were investigated. A series of test program, unconfined compressive strength (UCS) test, TCLP leaching test and scanning electron microscopy (SEM) test, were performed on lead and zinc contaminated soils solidified/stabilized by fly ash. Test results show that UCS and the leaching characteristics of heavy metal ions of S/S contaminated soils are significantly improved with the increase of fly ash content. UCS of S/S soils firstly increases with the increase of the times of drying and wetting cycles, after reaching the peak, it decreases with it. When the pollutant content is lower (1 000 mg/kg), the TCLP concentration first slightly decreases under cyclic drying and wetting, then increases, but the change is minor. The TCLP concentration is higher under a high pollutant content of 5 000 mg/kg, and increases with the increase of the times of drying and wetting cycles. The results of scanning electron microscopy (SEM) test are consistent with UCS tests and TCLP leaching tests, which reveals the micro-mechanism of the variations of engineering properties of stabilized contaminated soils after drying and wetting cycles.展开更多
The presence of stress is shown to have a significant impact on chloride ions in concrete. Reinforced concrete is usually durable and cost-effective which has resulted in its widespread use for construction, however, ...The presence of stress is shown to have a significant impact on chloride ions in concrete. Reinforced concrete is usually durable and cost-effective which has resulted in its widespread use for construction, however, the concrete subjected to environment and load has become increasingly apparently that attacked by aggressive agents such as chloride ion. In this study, the coupling influences are stress effects and environmental problems on the coastline concrete durability have been investigated. A series of cyclic of a wet-dry cycle and submersion tests were performed onto the stressed concrete to obtain an understanding of the physical mechanisms causing the accumulation of chlorides in the interior pores of concrete under different stress types and exposure environments, based on the same duration. Specimens were prepared and subjected to NaCl solution in a wet-dry cycle and submersion, the chloride in the tension zone is gradual with increasing the stress level, as well as the chloride ion in the wet-dry cycle, is increasing the number of cycles. The apparent diffusion coefficient of each specimen was calculated respectively, the profile of concentration at a different section of tension and compression zones were presented in influence factors of the number of cycles, the length of drying phase, and periodic wetting cycles with sodium solution was discussed. After employed Fick’s second law, the results suggested D<sub>a</sub> in a wet-dry cycle is much higher than the D<sub>a</sub> in submersion zones.展开更多
基金Foundation item: Projects(41172273, 40802079, 51108288) supported by the National Natural Science Foundation of China Project(KLE-TJGE-B1106) supported by the Opening Fund of Key Laboratory of Geotechnical and Underground Engineering of Ministry of Education (Tongji University), China
文摘Solidification/stabilization (S/S) is one of the most effective methods of dealing with heavy metal contaminated soils. The effects of cyclic wetting and drying on solidified/stabilized contaminated soils were investigated. A series of test program, unconfined compressive strength (UCS) test, TCLP leaching test and scanning electron microscopy (SEM) test, were performed on lead and zinc contaminated soils solidified/stabilized by fly ash. Test results show that UCS and the leaching characteristics of heavy metal ions of S/S contaminated soils are significantly improved with the increase of fly ash content. UCS of S/S soils firstly increases with the increase of the times of drying and wetting cycles, after reaching the peak, it decreases with it. When the pollutant content is lower (1 000 mg/kg), the TCLP concentration first slightly decreases under cyclic drying and wetting, then increases, but the change is minor. The TCLP concentration is higher under a high pollutant content of 5 000 mg/kg, and increases with the increase of the times of drying and wetting cycles. The results of scanning electron microscopy (SEM) test are consistent with UCS tests and TCLP leaching tests, which reveals the micro-mechanism of the variations of engineering properties of stabilized contaminated soils after drying and wetting cycles.
文摘The presence of stress is shown to have a significant impact on chloride ions in concrete. Reinforced concrete is usually durable and cost-effective which has resulted in its widespread use for construction, however, the concrete subjected to environment and load has become increasingly apparently that attacked by aggressive agents such as chloride ion. In this study, the coupling influences are stress effects and environmental problems on the coastline concrete durability have been investigated. A series of cyclic of a wet-dry cycle and submersion tests were performed onto the stressed concrete to obtain an understanding of the physical mechanisms causing the accumulation of chlorides in the interior pores of concrete under different stress types and exposure environments, based on the same duration. Specimens were prepared and subjected to NaCl solution in a wet-dry cycle and submersion, the chloride in the tension zone is gradual with increasing the stress level, as well as the chloride ion in the wet-dry cycle, is increasing the number of cycles. The apparent diffusion coefficient of each specimen was calculated respectively, the profile of concentration at a different section of tension and compression zones were presented in influence factors of the number of cycles, the length of drying phase, and periodic wetting cycles with sodium solution was discussed. After employed Fick’s second law, the results suggested D<sub>a</sub> in a wet-dry cycle is much higher than the D<sub>a</sub> in submersion zones.