The removal of hydrogen sulfide from gas plays an important role in rational utilization of resources and environ- mental protection. In this paper, the process of hydrogen sulfide removal by wet oxidation method in a...The removal of hydrogen sulfide from gas plays an important role in rational utilization of resources and environ- mental protection. In this paper, the process of hydrogen sulfide removal by wet oxidation method in a rotating packed bed was investigated in a scale for treating 10 000 Nm3/h of gas. On the basis of studying the influence of the species and con- centration of alkali source, the liquid/gas volume ratio, the high gravity factor, and the hydrogen sulfide content in feed gas on the desulfurization effect, the suitable technological conditions were obtained. The hydrogen sulfide removal efficiency could reach 98.0% under these conditions. The results of continuous operation of process facilities showed that the high gravity method has many merits including higher desulfurization rate, good stability in operation, lower liquid/gas volume ratio, greater operation elasticity, and apparent energy saving effects.展开更多
Bismuth-doped tin dioxide （BTO） nanometer powders were prepared by the wet chemical method using tin tetrachloride （SnCl4）, bismuth nitrate [Bi（NO3） 3 ] and ammonia as raw materials. Non-bridge hydroxides and ca...Bismuth-doped tin dioxide （BTO） nanometer powders were prepared by the wet chemical method using tin tetrachloride （SnCl4）, bismuth nitrate [Bi（NO3） 3 ] and ammonia as raw materials. Non-bridge hydroxides and capillary force between particles were found to be key factors causing hard aggregation of BTO through analyzing the formation mechanism of hard aggregation. The hard aggregation of BTO was eliminated effectively when the Bi-Sn precursor （BSP） was treated with post processing including dispersing with ultrasonic wave, refluxing and distilling with addition of n-butanol and benzene （DRD） and drying by microwave. Characterized with X-ray diffraction （XRD） and transmission electron microscopy （TEM）, BTO spherical particles with tetragonal phase structure are well crystallized, dispersed easily and the average size was less than 10 nm.展开更多
The large-scale ZnO rods of submicrometer were prepared on the bare glass using a wet chemical method under different experimental parameters,such as the reactant concentration and the growth time.The microstructure o...The large-scale ZnO rods of submicrometer were prepared on the bare glass using a wet chemical method under different experimental parameters,such as the reactant concentration and the growth time.The microstructure of the ZnO rods was characterized by X-ray diffractometry(XRD) and field emission scanning electron microscopy (FESEM) with the energy dispersive X-ray spectroscopy(EDX),and the optical property was investigated by the room-temperature photoluminescence (PL) spectra.XRD and FESEM results show that the wurtzite structure and rod-like ZnO is obtained.The length (3-8 μm) and the diameter (400 nm-3 μm) vary with the experimental parameters.A strong UV emission at 384 nm and a weak visible yellow-green emission around 570 nm are observed in the PL spectrum.After annealing at 600 ℃ in air,the UV peak intensity increases obviously and the yellow-green peak intensity decreases greatly.The near-band-edge UV emission is attributed to the exciton recombination; the yellow-green emission can be associated with the defect recombination; and some defect complexes may be responsible for the latter emission.展开更多
A modified wet chemical route for low-temperature synthesis of the calcium stannate CaSnO3, a potentialmaterial for dielectric applications is reported. Firstly, a precursor CaSn(OH)6 was prepared using tin tetrachlor...A modified wet chemical route for low-temperature synthesis of the calcium stannate CaSnO3, a potentialmaterial for dielectric applications is reported. Firstly, a precursor CaSn(OH)6 was prepared using tin tetrachloride,calcium chloride and sodium hydroxide at room temperature. Then the precursor was annealed at relatively low tem-perature of 600 ℃ to obtain CaSnO3. The phase identification, thermal behavior and surface morphology of the sam-ples were characterized by element analysis, X-ray diffraction (XRD), thermo-gravimetric (TG) analysis and deriva-tive thermo-gravimetric (DTG) analysis, Fourier transform infrared spectroscopy (FTIR) and scanning electron mi-croscopy (SEM) in detail. The results show that CaSnO3 obtained by this method possesses a cubic perovskitestructure with average grain size of 5 μm.展开更多
A wet-chemical method was presented for preparation of spherical, flowerlike, hexagonal, and triangular microsized silver crystals. Well-defined particles were prepared by mixing of iron（II） sulfate heptahydrate sol...A wet-chemical method was presented for preparation of spherical, flowerlike, hexagonal, and triangular microsized silver crystals. Well-defined particles were prepared by mixing of iron（II） sulfate heptahydrate solution with silver nitrate solution at the presence of different modifiers with high-speed stirring at 8-20℃. It is found that the diameters of resulting products are 0.6-6.0 um and the morphologies of the silver microcrystals are greatly affected by the introduced modifiers. It is concluded that the microsized silver crystals with different morphologies can be synthesized by introducing appropriate modifiers at appropriate experimental parameters. Scanning electron microscopy and X-ray diffraction were used to characterize the resulting products.展开更多
A particular porosity method named ＂slot method＂ is implemented in a depth-integrated shallow water flow model （DIVAST） to simulate wetting and drying processes. Discussed is the relationship between the shape fac...A particular porosity method named ＂slot method＂ is implemented in a depth-integrated shallow water flow model （DIVAST） to simulate wetting and drying processes. Discussed is the relationship between the shape factors of the ＂slot＂ and the preset depth used in ＂wetting-drying＂ algorithm. Two typical tests are conducted to examine the performance of the method with the effect of the shape factors of the ＂slot＂ being checked in detail in the first test. Numerical results demonstrate that： 1 ） no additional effort to improve the finite difference scheme is needed to implement ＂slot method＂ in DIVAST, and 2） ＂slot method＂ will simulate wetting and diying processes correctly if the shape factors of the ＂slot＂ being selected properly.展开更多
To prepare PZT powder at lower temperature, lead zirconate titanate (PZT) powder (x(Zr)/x(Ti)=56?44) was prepared by wet-dry method. Glycol was used as the solvent, and zirconium oxychloride was used as zirconium sour...To prepare PZT powder at lower temperature, lead zirconate titanate (PZT) powder (x(Zr)/x(Ti)=56?44) was prepared by wet-dry method. Glycol was used as the solvent, and zirconium oxychloride was used as zirconium source. The properties and structure of the powder were analyzed by XRD, SEM and Sedimentograph. The effects of sintering parameter such as sintering temperature, keeping time and heating-up velocity on structure of PZT power were investigated. The results show that homogeneous PZT with single-phase perovskite structure can be obtained after sintering at 730 ℃ for 2 h, and the average size of PZT powder is about 113 nm.展开更多
Soil surface wetness is indispensable land surface parameter in agriculture, hydrology and environmental engineering. This paper explores the relationship between surface radiant temperature and fractional vegetation ...Soil surface wetness is indispensable land surface parameter in agriculture, hydrology and environmental engineering. This paper explores the relationship between surface radiant temperature and fractional vegetation cover derived from satellite imagery to estimate soil surface wetness (triangle method) in Allahabad district. The pixel distributions create triangular shapes because the range of surface radiant temperature decreases as the amount of vegetation cover increases and sufficient number of pixels exists. A very weak correlation is found between the simulated soil surface wetness and ground measured soil moisture at deeper soil layers (R<sup>2</sup> < 0.15) on all the dates under investigation. This is because the drying rates at the surface discontinue to be linearly correlated to that at lower levels (depths). The standing water pixels distort the shape of the triangle especially at lower left edge of the triangle. This distortion is removable. The spatial and temporal inhomogeneity of soil surface wetness is examined.展开更多
基金the Shanxi Provin-cial Youth Science and Technology Research Fund (No.2008021009-2) for the financial support to this project
文摘The removal of hydrogen sulfide from gas plays an important role in rational utilization of resources and environ- mental protection. In this paper, the process of hydrogen sulfide removal by wet oxidation method in a rotating packed bed was investigated in a scale for treating 10 000 Nm3/h of gas. On the basis of studying the influence of the species and con- centration of alkali source, the liquid/gas volume ratio, the high gravity factor, and the hydrogen sulfide content in feed gas on the desulfurization effect, the suitable technological conditions were obtained. The hydrogen sulfide removal efficiency could reach 98.0% under these conditions. The results of continuous operation of process facilities showed that the high gravity method has many merits including higher desulfurization rate, good stability in operation, lower liquid/gas volume ratio, greater operation elasticity, and apparent energy saving effects.
文摘Bismuth-doped tin dioxide （BTO） nanometer powders were prepared by the wet chemical method using tin tetrachloride （SnCl4）, bismuth nitrate [Bi（NO3） 3 ] and ammonia as raw materials. Non-bridge hydroxides and capillary force between particles were found to be key factors causing hard aggregation of BTO through analyzing the formation mechanism of hard aggregation. The hard aggregation of BTO was eliminated effectively when the Bi-Sn precursor （BSP） was treated with post processing including dispersing with ultrasonic wave, refluxing and distilling with addition of n-butanol and benzene （DRD） and drying by microwave. Characterized with X-ray diffraction （XRD） and transmission electron microscopy （TEM）, BTO spherical particles with tetragonal phase structure are well crystallized, dispersed easily and the average size was less than 10 nm.
基金Project(2004CB619301) supported by the National Basic Research Program of ChinaProject supported by 985-Automotive Engineering of Jilin University, China
文摘The large-scale ZnO rods of submicrometer were prepared on the bare glass using a wet chemical method under different experimental parameters,such as the reactant concentration and the growth time.The microstructure of the ZnO rods was characterized by X-ray diffractometry(XRD) and field emission scanning electron microscopy (FESEM) with the energy dispersive X-ray spectroscopy(EDX),and the optical property was investigated by the room-temperature photoluminescence (PL) spectra.XRD and FESEM results show that the wurtzite structure and rod-like ZnO is obtained.The length (3-8 μm) and the diameter (400 nm-3 μm) vary with the experimental parameters.A strong UV emission at 384 nm and a weak visible yellow-green emission around 570 nm are observed in the PL spectrum.After annealing at 600 ℃ in air,the UV peak intensity increases obviously and the yellow-green peak intensity decreases greatly.The near-band-edge UV emission is attributed to the exciton recombination; the yellow-green emission can be associated with the defect recombination; and some defect complexes may be responsible for the latter emission.
文摘A modified wet chemical route for low-temperature synthesis of the calcium stannate CaSnO3, a potentialmaterial for dielectric applications is reported. Firstly, a precursor CaSn(OH)6 was prepared using tin tetrachloride,calcium chloride and sodium hydroxide at room temperature. Then the precursor was annealed at relatively low tem-perature of 600 ℃ to obtain CaSnO3. The phase identification, thermal behavior and surface morphology of the sam-ples were characterized by element analysis, X-ray diffraction (XRD), thermo-gravimetric (TG) analysis and deriva-tive thermo-gravimetric (DTG) analysis, Fourier transform infrared spectroscopy (FTIR) and scanning electron mi-croscopy (SEM) in detail. The results show that CaSnO3 obtained by this method possesses a cubic perovskitestructure with average grain size of 5 μm.
文摘A wet-chemical method was presented for preparation of spherical, flowerlike, hexagonal, and triangular microsized silver crystals. Well-defined particles were prepared by mixing of iron（II） sulfate heptahydrate solution with silver nitrate solution at the presence of different modifiers with high-speed stirring at 8-20℃. It is found that the diameters of resulting products are 0.6-6.0 um and the morphologies of the silver microcrystals are greatly affected by the introduced modifiers. It is concluded that the microsized silver crystals with different morphologies can be synthesized by introducing appropriate modifiers at appropriate experimental parameters. Scanning electron microscopy and X-ray diffraction were used to characterize the resulting products.
基金the National Natural Science Foundation of China (Grant No.10702050)the Natural Science Foundation of Tianjin (Grant No.07JCYBJC07500)the Support Plan of Science and Technology of Tianjin (Grant No.07ZCGYSH01700)
文摘A particular porosity method named ＂slot method＂ is implemented in a depth-integrated shallow water flow model （DIVAST） to simulate wetting and drying processes. Discussed is the relationship between the shape factors of the ＂slot＂ and the preset depth used in ＂wetting-drying＂ algorithm. Two typical tests are conducted to examine the performance of the method with the effect of the shape factors of the ＂slot＂ being checked in detail in the first test. Numerical results demonstrate that： 1 ） no additional effort to improve the finite difference scheme is needed to implement ＂slot method＂ in DIVAST, and 2） ＂slot method＂ will simulate wetting and diying processes correctly if the shape factors of the ＂slot＂ being selected properly.
文摘To prepare PZT powder at lower temperature, lead zirconate titanate (PZT) powder (x(Zr)/x(Ti)=56?44) was prepared by wet-dry method. Glycol was used as the solvent, and zirconium oxychloride was used as zirconium source. The properties and structure of the powder were analyzed by XRD, SEM and Sedimentograph. The effects of sintering parameter such as sintering temperature, keeping time and heating-up velocity on structure of PZT power were investigated. The results show that homogeneous PZT with single-phase perovskite structure can be obtained after sintering at 730 ℃ for 2 h, and the average size of PZT powder is about 113 nm.
文摘Soil surface wetness is indispensable land surface parameter in agriculture, hydrology and environmental engineering. This paper explores the relationship between surface radiant temperature and fractional vegetation cover derived from satellite imagery to estimate soil surface wetness (triangle method) in Allahabad district. The pixel distributions create triangular shapes because the range of surface radiant temperature decreases as the amount of vegetation cover increases and sufficient number of pixels exists. A very weak correlation is found between the simulated soil surface wetness and ground measured soil moisture at deeper soil layers (R<sup>2</sup> < 0.15) on all the dates under investigation. This is because the drying rates at the surface discontinue to be linearly correlated to that at lower levels (depths). The standing water pixels distort the shape of the triangle especially at lower left edge of the triangle. This distortion is removable. The spatial and temporal inhomogeneity of soil surface wetness is examined.
