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Wootz: Cast Iron or Steel? 被引量:2
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作者 D. A. Sukhanov N. V. Plotnikova 《Materials Sciences and Applications》 2016年第11期792-802,共12页
It is shown that the excess carbide phase in Wootz is of an unusual nature origin that differs from the excess phase of secondary cementite, ledeburite and primary cementite in iron-carbon alloys. It is revealed that ... It is shown that the excess carbide phase in Wootz is of an unusual nature origin that differs from the excess phase of secondary cementite, ledeburite and primary cementite in iron-carbon alloys. It is revealed that the morphological features of excess cementite in Wootz lie in the abnormal size of excess carbides having the shape of irregular prisms. It is discovered that the faceted angular carbides are formed within the original of metastable ledeburite, so they are called “eutectic carbides”. It was found that angular eutectic carbides in the Wootz formed during long isothermal soaking at the annealing and subsequent deformation of ledeburite structures. It is revealed that carbon takes up 2.25% in Wootz (in the region of white cast iron), while none in its structure of crushed ledeburite. It is shown that the pattern of carbide heterogeneity consists entirely of angular eutectic carbides having an irregular trigonal-prismatic morphology. It is shown that Wootz (Damascus steel) is non-alloy tool steel of ledeburite class, similar with structural characteristics of die steel of ledeburite class and high-speed steel, differing from them only in the nature of excess carbide phase. 展开更多
关键词 wootz Damascus Steel Bulat Tool Steel
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“镔铁”新考 被引量:11
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作者 潜伟 《自然科学史研究》 CSCD 北大核心 2007年第2期165-191,共27页
“镔铁”作为一种高质量的钢铁制品在中西技术文化交流史中占有重要地位。“镔铁”最早文献记载于隋代的《不空羂索咒经》,见于史书最早为初唐的《周书》、《隋书》。唐代惠琳《一切经音义》有“镔铁”最早的词义解释。“镔”字除了外... “镔铁”作为一种高质量的钢铁制品在中西技术文化交流史中占有重要地位。“镔铁”最早文献记载于隋代的《不空羂索咒经》,见于史书最早为初唐的《周书》、《隋书》。唐代惠琳《一切经音义》有“镔铁”最早的词义解释。“镔”字除了外来语直接音译以外,也可解释为来自罽宾的铁。“镔铁”频繁出现在各种古代文献中,其中作为物产出现最多。史料记载的“辽以镔铁为号”应是金人杜撰;元代“镔铁局”只是借用“镔铁”这个名称,仅仅是对来自中亚、西亚的色人铁匠们进行管理的一个机构;哈密“喫铁石”的记载,经考证可能是陨石或者坩埚钢;太原府的镔铁坑(祠)应为一个冶铁遗址;镔铁制作的物品范围很广,不仅有兵器工具类,也有利用其精美外观特性制作的各种物品。南宋《云烟过眼录》中“金水总管造”镔铁小刀,是最早有关带花纹镔铁刀的记载。中国古代大量诗歌中,以镔铁为喻的篇章多谈及其锋利、表面花纹等特征。大马士革钢从某种程度上就是表面花纹钢的代名词,以自然花纹为特征,更像是由中亚的布拉特钢加工得来,而由南亚乌兹钢加工得到的大马士革钢却很少见。“镔铁”不是“大马士革钢”的同义词,更接近于坩埚钢系列。无论从文物考古还是文献资料来看,中国中原地区一直缺乏镔铁生产的可靠证据。新疆冶金考古的新进展,应该能够为探讨镔铁的起源与传播提供更多有价值的证据。 展开更多
关键词 技术史 镔铁 大马士革钢 布拉特钢 乌兹钢 冶金考古
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Formation of Eutectic Carbides in the Structure of High-Purity White Cast Iron in the Forging Process 被引量:1
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作者 D. A. Sukhanov L. B. Arkhangelsky 《Materials Sciences and Applications》 2017年第5期351-360,共10页
It is found that the deformation of white cast iron under forging production is only possible with a minimum number of permanent impurities. The developed modes of high-temperature intermediate annealing facilitate th... It is found that the deformation of white cast iron under forging production is only possible with a minimum number of permanent impurities. The developed modes of high-temperature intermediate annealing facilitate the deformation of the forging under normal production conditions. It is shown that in the process of isothermal annealing of white cast iron begins the process of disintegration of ledeburite in the more stable eutectic carbides, providing technological plasticity for subsequent forging. The installed influence of the purity of white cast iron on the morphology of the excess carbides and their ability to divide. Studies the morphology of the excess eutectic carbides after melting, pre-annealing and after deformation forging. Discovered that after severe plastic deformation the structure of white cast iron becomes more stable, due to the appearance of eutectic carbides. It was determined that the deformed structure of white iron, because of its lack ledeburite component, was more identical with the structure of the alloy ledeburite steels. The data obtained can be used for making Damascus bladed weapons products, experiencing shock-variables loads. 展开更多
关键词 WHITE CAST IRON Damascus STEEL wootz Ledeburitic STEEL
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Influence of the Distribution of Excess Carbide on the Properties of Genuine Damascus Steel 被引量:1
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作者 Dmitry Sukhanov Nataliya Plotnikova 《Materials Sciences and Applications》 2019年第2期118-136,共19页
The methods of spectral, x-ray phase and microprobe analysis show that genuine Damascus steel is a high-purity unalloyed high-carbon steel with a high phosphorus content. It is shown that phosphorus in an amount of fr... The methods of spectral, x-ray phase and microprobe analysis show that genuine Damascus steel is a high-purity unalloyed high-carbon steel with a high phosphorus content. It is shown that phosphorus in an amount of from 0.1% to 0.2%, having a high liquation coefficient, contributes to the process of segregation of carbon in interdendritic zone in the process of crystallization. Interdendritic zone formed carbon clusters, in the process of forging transform into oblong carbides cementite. The main physical and chemical factors affecting the formation of oblong carbides are revealed. The hardness of carbide layers was determined, which was about 920 HV. The hardness of the troostite matrix was amounted about 475 HV. It is established that the cutting edge of the blade knife of Damascus steel is nothing more than a “micro-saw” consisting of parallel carbide and troostite layers. Tests are conducted on the preservation of the cutting edge sharpness of the blades knife of homogeneous structure of steel У15А (Russian) and the layered structure of genuine Damascus steel Ds15P (Indo-Persian). Found that with little effort cut (to 4 kg) ancient Damascus steel (Ds15P) shows a greater number of cuts than the modern instrument steel У15А. With an increase, force on the cutting edge from 6 kg to 12 kg carbon Tool steel is showed a more number of cutting on the 25% than in genuine Damascus steel. The fatigue crack propagation in the true Layered structure of Damascus steel Ds15P occurs for a greater number of cycles than in a homogeneous structure of the steel У15А. The blade knife of genuine Damascus steel, in terms of fatigue reliability (survivability), has almost 2 times longer service life than the blade knife of the modern carbon tool steel type У15А. It is proved that loss in cutting ability of a genuine Damascus steel compensates increased the reliability (“survivability”) of the blade knife with fatigue loads. 展开更多
关键词 Carbon Tool Steels GENUINE Damascus STEEL wootz STEEL Bulat STEEL Indo-Persian STEEL
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Influence of Morphology Pattern of Genuine Damascus Steel on the Nature of Relief of Fracture Surfaces
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作者 Dmitry A. Sukhanov 《Materials Sciences and Applications》 CAS 2022年第7期453-468,共16页
It has been revealed that the structure of the transverse and longitudinal parts of the genuine Damascus knife of the XVIII century consists of troostite-carbide of the banding. The microhardness of the troostite laye... It has been revealed that the structure of the transverse and longitudinal parts of the genuine Damascus knife of the XVIII century consists of troostite-carbide of the banding. The microhardness of the troostite layers is 450 HV;the carbide layers reach 950 HV. It is shown that such a banding structure in hardness will have a huge impact on the formation of a naturally patterned genuine Damascus structure. It is established that the form of the main drawings of the genuine Damascus pattern consists of separate elements of the topographic contour: hollows, hills, saddles, crosses and wavy dunes. It is shown that the damask pattern is a set of individual elements of the macrostructure alternating in a disordered form on different local areas of the surface. It is established that the destruction of genuine Damascus steels occurs under the action of two or more mechanisms, during the implementation of which traces remain on the surface of the fractures in the form of relief details of a mixed type. The mechanisms of mixed destruction are a combination of intragrain cleavage, micropore fusion and intergrain cracking. It is established that in order to implement the mechanism of separation of the main crack in the direction of the chopping blow, an optimum is required in the dispersion of troostite (61.8%) and carbide (38.2%) layers in genuine Damascus steel, the ratio of their volumes obeys the golden section rule. It is established that the damask pattern, consisting of elements of sinuous lines of a topographic contour, does not significantly affect the level of mechanical properties. This factor is a category of the quality of banding structures in genuine Damascus steel. 展开更多
关键词 Genuine Damascus Steel wootz Steel Bulat Steel Indo-Persian Steel
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Formation of Faceted Excess Carbides in Damascus Steels Ledeburite Class 被引量:1
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作者 Dmitry Sukhanov Natalia Plotnikova 《材料科学与工程(中英文B版)》 2018年第1期36-44,共9页
关键词 大马士革 碳化物 碳钢 W6MO5CR4V2 持续时间 CR12 六角形 类型
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古代大马士革钢刀锻打花纹形成机制的理论分析 被引量:4
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作者 罗海文 潜伟 董瀚 《科学通报》 EI CAS CSCD 北大核心 2014年第9期833-842,共10页
古代大马士革刀锻打花纹的形成机制是历史上持续数个世纪的热门研究课题.本文简要回顾了乌兹钢、大马士革刀和大马士革花纹的历史背景,着重介绍并分析了当代冶金研究者关于大马士革花纹形成机制的主要观点和争论,并通过现代冶金学热力... 古代大马士革刀锻打花纹的形成机制是历史上持续数个世纪的热门研究课题.本文简要回顾了乌兹钢、大马士革刀和大马士革花纹的历史背景,着重介绍并分析了当代冶金研究者关于大马士革花纹形成机制的主要观点和争论,并通过现代冶金学热力学和动力学理论模型分析了这些主要观点,包括定量计算钢中S,P,V等元素对Fe-C平衡相图的影响、慢速凝固时S,P等元素的偏析程度、以及V(CN)粒子在奥氏体相区的析出温度以及V在高温退火时扩散动力学等.据此,作者提出了关于古代大马士革刀中花纹形成的新机制,即由于乌兹钢锭中凝固时S,P的枝晶偏析,导致凝固后偏析区形成硫化物或磷化物,尤其是磷的枝晶偏析导致冷却时形成磷化物与渗碳体的共晶体,在后续的加热过程中不能完全固溶,并作为热锻时析出的渗碳体析出核心,从而决定了渗碳体在大马士革刀中的空间分布和最终的大马士革花纹的形成. 展开更多
关键词 大马士革刀 大马士革花纹 乌兹钢 渗碳体 凝固 枝晶偏析
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