In order to precisely measure the ion parameters in a microwave electron cyclotron resonance plasma using an ion sensitive probe,the dependences of the current-voltage(I-V)characteristics on the shielding height(h...In order to precisely measure the ion parameters in a microwave electron cyclotron resonance plasma using an ion sensitive probe,the dependences of the current-voltage(I-V)characteristics on the shielding height(h)and the potential difference between inner and outer electrodes(V_B)have been investigated at different working pressures of 0.03 Pa and 0.8 Pa.Results show that the I-V curves at higher pressure are more sensitive to the variation of h than those at lower pressure.The influence of V_B on ion temperature(T_i)measurement becomes more prominent when the pressure is increased from 0.03 Pa to 0.8 Pa.Under both pressures,the optimized h is obtained at the condition where the current reaches zero in the positive voltage region with a suitable V_B of-1.5 V because of effective shielding of the electron E×B drift.展开更多
The effects of deforming temperatures on the tensile behaviors of quenching and partitioning treated steels were investigated. It was found that the ultimate tensile strength of the steel decreased with the increasing...The effects of deforming temperatures on the tensile behaviors of quenching and partitioning treated steels were investigated. It was found that the ultimate tensile strength of the steel decreased with the increasing temperature from 25 to 100 ℃, reached the maximum value at 300 ℃, and then declined by a significant extent when the temperature further reached 400 ℃. The total elongations at 100, 200 and 300 ℃are at about the same level. The steel achieved optimal mechanical properties at 300 ℃due to the proper transformation behavior of retained austenite since the stability of retained austenite is largely dependent on the deforming temperature. When tested at 100 and 200 ℃, the retained aus tenite was reluctant to transform, while at the other temperatures, about 10 vol. % of retained aus- tenite transformed during the tensile tests. The relationship between the stability of retained austenite and the work hardening behavior of quenching and partitioning treated steels at different deforming temperatures was also studied and discussed in detail. In order to obtain excellent mechanical properties, the stability of retained austenite should be carefully controlled so that the effect of transforma tion-induced plasticity could take place continuously during plastic deformation.展开更多
Lithium metal batteries(LMBs)have attracted considerable interest for use in electric vehicles and as next-generation energy storage devices because of their high energy density.However,a significant practical drawbac...Lithium metal batteries(LMBs)have attracted considerable interest for use in electric vehicles and as next-generation energy storage devices because of their high energy density.However,a significant practical drawback with LMBs is the instability of the Li metal/electrolyte interface,with concurrent parasitic reactions and dendrite growth,that leads to low Coulombic efficiency and poor cycle life.Owing to the significant role of electrolytes in batteries,rationally designed electrolytes can improve the electrochemical performance of LMBs and possibly achieve fast charge and a wide range of working temperatures to meet various requirements of the market in the future.Although there are some review papers about electrolytes for LMBs,the focus has been on a single parameter or single performance separately and,therefore,not sufficient for the design of electrolytes for advanced LMBs for a wide range of working environments.This review presents a systematic summary of recent progress made in terms of electrolytes,covering the fundamental understanding of the mechanism,scientific challenges,and strategies to address drawbacks of electrolytes for high-performance LMBs.The advantages and disadvantages of various electrolyte strategies are also analyzed,yielding suggestions for optimum properties of electrolytes for advanced LMBs applications.Finally,the most promising research directions for electrolytes are discussed briefly.展开更多
Solid electrolytes have gained attention recently for the development of next-generation Li-ion batteries since they can fun-damentally improve the battery stability and safety.Among various types of solid electrolyte...Solid electrolytes have gained attention recently for the development of next-generation Li-ion batteries since they can fun-damentally improve the battery stability and safety.Among various types of solid electrolytes,composite solid electrolytes(CSEs)exhibit both high ionic conductivity and excellent interfacial contact with the electrodes.Incorporating active nanofib-ers into the polymer matrix demonstrates an effective method to fabricate CSEs.However,current CSEs based on traditional poly(ethylene oxide)(PEO)polymer suffer from the poor ionic conductivity of PEO and agglomeration effect of inorganic fillers at high concentrations,which limit further improvements in Li+conductivity and electrochemical stability.Herein,we synthesize a novel PEO based cross-linked polymer(CLP)as the polymer matrix with naturally amorphous structure and high room-temperature ionic conductivity of 2.40×10^(−4)S cm^(−1).Li_(0.3)La_(0.557)TiO_(3)(LLTO)nanofibers are incorporated into the CLP matrix to form composite solid electrolytes,achieving enhanced ionic conductivity without showing filler agglomeration.The high content of Li-conductive nanofibers improves the mechanical strength,ensures the conductive network,and increases the total Li+conductivity to 3.31×10^(−4)S cm^(−1).The all-solid-state Li|LiFePO_(4)batteries with LLTO nanofiber-incorporated CSEs are able to deliver attractive specific capacity of 147 mAh g^(−1)at room temperature,and no evident dendrite is found at the anode/electrolyte interface after 100 cycles.展开更多
Polymer-based dielectric capacitors are widely-used energy storage devices.However,although the functions of dielectrics in applications like high-voltage direct current transmission projects,distributed energy system...Polymer-based dielectric capacitors are widely-used energy storage devices.However,although the functions of dielectrics in applications like high-voltage direct current transmission projects,distributed energy systems,high-power pulse systems and new energy electric vehicles are similar,their requirements can be quite different.Low electric loss is a critical prerequisite for capacitors for electric grids,while high-temperature stability is an essential pre-requirement for those in electric vehicles.This paper reviews recent advances in this area,and categorizes dielectrics in terms of their foremost properties related to their target applications.Requirements for polymer-based dielectrics in various power electronic equipment are emphasized,including high energy storage density,low dissipation,high working temperature and fast-response time.This paper considers innovations including chemical structure modification,composite fabrication and structure re-design,and the enhancements to material performances achieved.The advantages and limitations of these methods are also discussed.展开更多
Considering the effect of work roll shifting on roll temperature field,a finite difference method of PR format for roll temperature field was presented,which can meet the requirements of accuracy and speed of online c...Considering the effect of work roll shifting on roll temperature field,a finite difference method of PR format for roll temperature field was presented,which can meet the requirements of accuracy and speed of online calculation.The step-by-step accumulation method was used to simulate the roll temperature field and thermal crown,and the evolution of roll thermal crown in a rolling campaign was studied.And then,the effects of strip width,rolling rhythm and work roll shifting on roll thermal crown were analyzed.It is found that work roll shifting can disperse the thermal expansion of the roll body especially the edge to make roll thermal contour uniform.The effect of work roll shifting on roll thermal crown is mainly concentrated in regions around twice of roll shifting stroke,and the change range of roll thermal crown is±30μm or so in the same roll body location.展开更多
基金supported by National Natural Science Foundation of China(No.10875093)
文摘In order to precisely measure the ion parameters in a microwave electron cyclotron resonance plasma using an ion sensitive probe,the dependences of the current-voltage(I-V)characteristics on the shielding height(h)and the potential difference between inner and outer electrodes(V_B)have been investigated at different working pressures of 0.03 Pa and 0.8 Pa.Results show that the I-V curves at higher pressure are more sensitive to the variation of h than those at lower pressure.The influence of V_B on ion temperature(T_i)measurement becomes more prominent when the pressure is increased from 0.03 Pa to 0.8 Pa.Under both pressures,the optimized h is obtained at the condition where the current reaches zero in the positive voltage region with a suitable V_B of-1.5 V because of effective shielding of the electron E×B drift.
基金financial support of the National Key Research and Development Program of China(No.2017YFB0304401)National Natural Science Foundation of China(Nos.U1564203,51571141 and 51201105)the support provided by Shanghai Key Laboratory of Materials Laser Processing and Modification,Shanghai Jiao Tong University
文摘The effects of deforming temperatures on the tensile behaviors of quenching and partitioning treated steels were investigated. It was found that the ultimate tensile strength of the steel decreased with the increasing temperature from 25 to 100 ℃, reached the maximum value at 300 ℃, and then declined by a significant extent when the temperature further reached 400 ℃. The total elongations at 100, 200 and 300 ℃are at about the same level. The steel achieved optimal mechanical properties at 300 ℃due to the proper transformation behavior of retained austenite since the stability of retained austenite is largely dependent on the deforming temperature. When tested at 100 and 200 ℃, the retained aus tenite was reluctant to transform, while at the other temperatures, about 10 vol. % of retained aus- tenite transformed during the tensile tests. The relationship between the stability of retained austenite and the work hardening behavior of quenching and partitioning treated steels at different deforming temperatures was also studied and discussed in detail. In order to obtain excellent mechanical properties, the stability of retained austenite should be carefully controlled so that the effect of transforma tion-induced plasticity could take place continuously during plastic deformation.
基金Financial support provided by the Australian Research Council(ARC)(Nos.FL210100050,LP160101629,and DP210101486)is gratefully acknowledgedMingnan Li acknowledges the Chinese Sponsorship Council for scholarship support(No.202106130006).
文摘Lithium metal batteries(LMBs)have attracted considerable interest for use in electric vehicles and as next-generation energy storage devices because of their high energy density.However,a significant practical drawback with LMBs is the instability of the Li metal/electrolyte interface,with concurrent parasitic reactions and dendrite growth,that leads to low Coulombic efficiency and poor cycle life.Owing to the significant role of electrolytes in batteries,rationally designed electrolytes can improve the electrochemical performance of LMBs and possibly achieve fast charge and a wide range of working temperatures to meet various requirements of the market in the future.Although there are some review papers about electrolytes for LMBs,the focus has been on a single parameter or single performance separately and,therefore,not sufficient for the design of electrolytes for advanced LMBs for a wide range of working environments.This review presents a systematic summary of recent progress made in terms of electrolytes,covering the fundamental understanding of the mechanism,scientific challenges,and strategies to address drawbacks of electrolytes for high-performance LMBs.The advantages and disadvantages of various electrolyte strategies are also analyzed,yielding suggestions for optimum properties of electrolytes for advanced LMBs applications.Finally,the most promising research directions for electrolytes are discussed briefly.
基金the Department of Energy,Office of Energy Efficiency and Renewable Energy(EERE),under Award Number DE-EE0007806.
文摘Solid electrolytes have gained attention recently for the development of next-generation Li-ion batteries since they can fun-damentally improve the battery stability and safety.Among various types of solid electrolytes,composite solid electrolytes(CSEs)exhibit both high ionic conductivity and excellent interfacial contact with the electrodes.Incorporating active nanofib-ers into the polymer matrix demonstrates an effective method to fabricate CSEs.However,current CSEs based on traditional poly(ethylene oxide)(PEO)polymer suffer from the poor ionic conductivity of PEO and agglomeration effect of inorganic fillers at high concentrations,which limit further improvements in Li+conductivity and electrochemical stability.Herein,we synthesize a novel PEO based cross-linked polymer(CLP)as the polymer matrix with naturally amorphous structure and high room-temperature ionic conductivity of 2.40×10^(−4)S cm^(−1).Li_(0.3)La_(0.557)TiO_(3)(LLTO)nanofibers are incorporated into the CLP matrix to form composite solid electrolytes,achieving enhanced ionic conductivity without showing filler agglomeration.The high content of Li-conductive nanofibers improves the mechanical strength,ensures the conductive network,and increases the total Li+conductivity to 3.31×10^(−4)S cm^(−1).The all-solid-state Li|LiFePO_(4)batteries with LLTO nanofiber-incorporated CSEs are able to deliver attractive specific capacity of 147 mAh g^(−1)at room temperature,and no evident dendrite is found at the anode/electrolyte interface after 100 cycles.
基金This research was supported by Zhejiang Provincial Natural Science Foundation of China(Grant No.LQ18E030004)State Key Laboratory of Electrical Insulation and Power Equipment(Grant No.EIPE19204)Zhejiang Top Priority Discipline of Textile Science and Engineering/Material Science and Engineering(Grant No.2019YBZX03).
文摘Polymer-based dielectric capacitors are widely-used energy storage devices.However,although the functions of dielectrics in applications like high-voltage direct current transmission projects,distributed energy systems,high-power pulse systems and new energy electric vehicles are similar,their requirements can be quite different.Low electric loss is a critical prerequisite for capacitors for electric grids,while high-temperature stability is an essential pre-requirement for those in electric vehicles.This paper reviews recent advances in this area,and categorizes dielectrics in terms of their foremost properties related to their target applications.Requirements for polymer-based dielectrics in various power electronic equipment are emphasized,including high energy storage density,low dissipation,high working temperature and fast-response time.This paper considers innovations including chemical structure modification,composite fabrication and structure re-design,and the enhancements to material performances achieved.The advantages and limitations of these methods are also discussed.
基金Sponsored by National Natural Science Foundation of China(51205336)Fujian Natural Science Foundation of China(2013J05086)
文摘Considering the effect of work roll shifting on roll temperature field,a finite difference method of PR format for roll temperature field was presented,which can meet the requirements of accuracy and speed of online calculation.The step-by-step accumulation method was used to simulate the roll temperature field and thermal crown,and the evolution of roll thermal crown in a rolling campaign was studied.And then,the effects of strip width,rolling rhythm and work roll shifting on roll thermal crown were analyzed.It is found that work roll shifting can disperse the thermal expansion of the roll body especially the edge to make roll thermal contour uniform.The effect of work roll shifting on roll thermal crown is mainly concentrated in regions around twice of roll shifting stroke,and the change range of roll thermal crown is±30μm or so in the same roll body location.