Petrogenesis and Physicochemical Conditions of Fertile Porphyry in Non-arc Porphyry Mineralization:A Case from Habo Porphyry Cu-Mo Deposits,SW China

The Habo deposit is a typical porphyry Cu-Mo deposit in the Ailaoshan–Red River metallogenic belt.Ore minerals in the Habo deposit typically occur as veins in the monzonite porphyry.Zircon U-Pb dating suggests that the monzonite porphyry formed at 35.07±0.38 Ma.The monzonite porphyry is characterized by high SiO_(2),Al_(2)O_(3),K_(2)O and Na_(2)O contents,with A/CNK ratios ranging from 0.97 to 1.02.All samples exhibit fractionated REE patterns,characterized by high(La/Yb)N ratios(9.4–13.6,average of 11.2).They show adakite-like geochemical features,high Sr concentrations(627–751 ppm,average of 700 ppm),low Y concentrations(15.13–16.86 ppm,average of 15.81 ppm)and high Sr/Y values(39.5–47.4,average of 44.3).These samples have high initial^(87)Sr/^(86)Sr ratios(0.7074–0.7076)and negativeεNd(t)values(-5.1 to-3.7),whereas the zirconεHf(t)values range from-2.2 to+0.4,suggesting that the monzonite porphyry was derived from the partial melting of a thickened juvenile lower crust.The oxygen fugacity,calculated on the basis of the chemical composition of the amphiboles,shows?NNO values ranging from+1.65 to+2.16(average of 1.94)and lg(fO_(2))ranging from-12.72 to-11.99(average of-12.25),indicating that the monzonite porphyry has high oxygen fugacity.Zircons have high Ce^(4+)/Ce^(3+)ratios(29.29–164.24,average of 84.92),with high?FMQ values ranging from+0.50 to+1.51(average of 0.87)and high lg(fO_(2))values ranging from-14.72 to-12.85(average of-14.07),which also indicates that the oxygen fugacity of the magma was high.The dissolved water content of the Habo monzonite porphyry is 9.5–11.5 wt%,according to the geochemical characteristics,zircon-saturation thermometry(692–794°C)and the mineral phases(amphibole,no plagioclase)in the deep magma chamber.Combined with previous studies,we propose that the high oxygen fugacity and high water content of magma played key roles in controlling the formation of the Habo and other Cu-Mo-Au deposits in the Ailaoshan–Red River metallogenic belt.

Geochemical Characteristics and Significance of Major Elements, Trace Elements and REE in Mineralized Altered Rocks of Large-Scale Tsagaan Suvarga Cu-Mo Porphyry Deposit in Mongolia

The alteration types of the large-scale Tsagaan Suvarga Cu-Mo porphyry deposit mostly comprise stockwork silicification, argillization, quartz-sericite alteration, K-silicate alteration, and propylitization. The mineralized and altered zones from hydrothermal metallogenic center to the outside successively are Cu-bearing stockwork silicification zone, Cu-beating argillized zone, Cu-Mo-bearing quartz-sericite alteration zone, Cu-Mo-bearing K-silicate alteration zone, and pro- pylitization zone. The K-silicate alteration occurred in the early phase, quartz-sericite alteration in the medium phase, and argillization and carbonatization （calcite） in the later phase. Ore-bearing-altered rocks are significantly controlled by the structure and fissure zones of different scales, and NE- and NW-trending fissure zones could probably be the migration pathways of the porphyry hydrothermal system. Results in this study indicated that the less the concentrations of REE, LREE, and HREE and the more the extensive fractionation between LREE and HREE, the closer it is to the center circulatory hydrothermal ore-forming and the more extensive silicification. The exponential relationship between the fractionation of LREE and HREE and the intensity of silicification and K-silicate alteration was found in the Cu-Mo deposit studied. The negative Eu anomaly, normal Eu, positive Eu anomaly and obviously positive Eu anomaly are coincident with the enhancement of Na2O and K2O concentrations gradually, which indicated that Eu anomaly would be significantly controlled by the alkaline metasomatism of the circulatory hydrothermal ore-forming system. Therefore, such characteristics as the positive Eu anomaly, the obvious fractionation between LREE and HREE and their related special alteration lithofacies are suggested to be metallogenic prognostic and exploration indications for Tsagaan Suvarga-style porphyry Cu-Mo deposits in Mongolia and China.

Geochronological Constraints on the Haftcheshmeh Porphyry Cu-Mo-Au Ore Deposit, Central Qaradagh Batholith, Arasbaran Metallogenic Belt, Northwest Iran

The Haftcheshmeh porphyry Cu-Mo-Au deposit in the Arasbaran metallogenic belt （AMB） of NW Iran contains more than 185 Mt of ore, with a grade ranging from 0.3% to 0.4%. It is hosted within a porphyritic diorite to granodiorite intruded into an older gabbro - diorite intrusion. 40Ar/39Ar analyses of primary magmatic hornblende from the granodiorite porphyry and gabbro - diorite show plateau ages of 26.41 ± 0.59 Ma, with an inverse isochron age of 25.9 ± 1.0 Ma and a plateau age of 27.47 ± 0.17 Ma, with an inverse isochron age of 27.48 ± 0.35 Ma for these two rock types, respectively. Comparing these new age data with those from the nearby Sungun （20.69 ± 0.35 Ma） and Kighal porphyry deposits defines a northwest-southeast Cu-Mo-Au mineralization zone extending for 20 km over the time span of-27 to 20 Ma. Geochemically, Haftcheshmeh rocks are calc-alkaline with high potassium affinities with tectonic setting in relation to volcanic arc setting. Large ion lithophile elements （LILE） such as Th, U and K show enrichment on a primitive mantle normalized diagram （specially Pb）, and are depleted in high field strength elements （HFSE） such as Ti and Nb, pointing to a mantle magma source contamination with crustal materials by subducted oceanic crust.

Re-Os isotopic dating and geological significance of molybdenite from Xintian Cu-Mo polymetallic deposit in Yanbian,Jilin

Xintian polymetallie deposit is a hydrothermal vein type Cu-Mo deposit. Analysis on Re-Os isotopic dating for the molybdenite from this deposit is undertaken to determine metallogenic epoch and dynamics setting of the deposit. Re-Os isotopic dating for the molybdenite yields model ages ranging from 123.9 ± 1.9 Ma to 124.7 ± 1.8 Ma, with a weighted mean age of 123.4 ±0.81 Ma, and an isochron age of 127 ± 16 Ma, MSWD = 0.25, indicating that the metallization was at late Yanshanian. The content of Re in molybdenite is （330.1 ±4.0-367.9 ± 3.1 ） xl0^-6, which demonstrates mantle derived metallogenic sources. Integrating the region-al tectonic evolution and the metallogenic characteristics of other contemporaneous Cu-Mo deposits in the re-gion, it is suggested that the Cu-Mo mineralization of this deposit occurred in an active epieontinental environ-ment under lithospheric extension resulted from the subduction of the Izanagi plate to the Paleo-Asia continental margin at late Yanshanian. The Mantle wedge was partially melted with large amount of metallogenic elements dissolved in it. Under the favorable conditions of crust-mantle interaction, large-scale magmatic activity turns out to be the important mechanism of the mineralization of many Cu-Mo deposits in the Xiaoxingan Range-Zhangguangcai Mountain metallogenic belt, including the Xintian Cu-Mo polymetallic deposit.

Re-Os geochronology of Cu and W-Mo deposits in the Balkhash metallogenic belt,Kazakhstan and its geological significance

The Central Asian metallogenic domain （CAMD） is a multi-core metallogenic system controlled by boundary strike-slip fault systems. The Balkhash metallogenic belt in Kazakhstan, in which occur many large and super-large porphyritic Cu--Mo deposits and some quartz vein- and greisen-type W-Mo deposits, is a well-known porphyritic Cu--Mo metallogenic belt in the CAMD. In this paper 11 molybdenite samples from the western segment of the Balkhash metallogenic belt are selected for Re--Os compositional analyses and Re--Os isotopic dating. Molybdenites from the Borly porphyry Cu deposit and the three quartz vein-greisen W--Mo deposits--East Kounrad, Akshatau and Zhanet--all have relatively high Re contents （2712--2772 μg/g for Borly and 2.267--31.50 μg/g for the other three W-Mo deposits）, and lower common Os contents （0.670-2.696 ng/g for Borly and 0.0051--0.056 ng/g for the other three）. The molybdenites from the Borly porphyry Cu--Mo deposit and the East Kounrad, Zhanet, and Akshatau quartz vein- and greisen-type W-Mo deposits give average model Re--Os ages of 315.9 Ma, 298.0 Ma, 295.0 Ma, and 289.3 Ma respectively. Meanwhile, molybde- nites from the East Kounrad, Zhanet, and Akshatan W-Mo deposits give a Re--Os isochron age of 297.9 Ma, with an MSWD value of 0.97. Re--Os dating of the molybdenites indicates that Cu-W-Mo metallogenesis in the western Balkhash metallogeuic belt occurred during Late Carboniferous to Early Permian （315.9--289.3 Ma）, while the porphyry Cu--Mo deposits formed at ~316 Ma, and the quartz vein-greisen W--Mo deposits formed at ~298 Ma. The Re--Os model and isochron ages thus suggest that Late Carboniferous porphyry granitoid and pegmatite magmatism took place during the late Hercy- nian movement. Compared to the Junggar-East Tianshan porphyry Cu metallogenic belt in northwestern China, the formation of the Cu-Mo metallogenesis in the Balkhash rnetallogenic belt occurred between that of the Tuwu-Yandong in East Tianshan and the Baogutu porphyry Cu deposits in West Junggar. Collectively, the large-scale Late Carboniferous porphyry Cu-Mo metallogenesis in the Central Asian metallogenic domain is related to Hercynian tectono-magmatic activities.

Geology,Geochemistry and Zircon U-Pb Geochronology of Porphyries in the Dabate Mo-Cu Deposit,Western Tianshan,China:Petrogenesis and Tectonic Implications

The Dabate Mo-Cu deposit is a medium-sized porphyry-type deposit in the Sailimu Lake region, western Tianshan, China. We present the geology, geochemistry and zircon U-Pb geochronology of granite porphyries from the Dabate district with the intent to constrain their tectonic setting and petrogenesis. Porphyries in the Dabate district include granite porphyry I（gray white color with large phenocrysts）, granite porphyry II（pink color with small phenocrysts） and quartz porphyry. Granite porphyry II is the Cu and Mo ore-bearing granitoid in the Dabate deposit. LA-ICPMS zircon U-Pb analyses indicate that granite porphyry II was emplaced at 284.2±1.8 Ma. Granite porphyry I and II have similar geochemical features and are both highly fractionated granites：（1） They have high SiO2 content（70.93–80.18 wt% and 72.14–72.64 wt%, respectively）, total alkali（7.58–8.95 wt% and 9.35–9.68 wt%, respectively）, mafic index（0.95–0.98 and 0.93–0.94, respectively） and felsic index（0.79–0.94 and 0.89–0.91, respectively）;（2） They are characterized by pronounced negative Eu anomaly, ＂seagullstyle＂ chondrite-normalized REE patterns and ＂tetrad effect＂ of REE;（3） They are rich in Rb, K, Th, Ta, Zr, Hf, Y and REE, but depleted in Sr, P, Ti and Nb. The magma of granite porphyries in Dabate can be interpreted to have been generated by partial melting of the upper crust due to mantle-derived magma underplating in a post-collisional extensional setting.

Rare Earth Element Behaviour in theWunugetushan Copper - Molybdenum Deposit,Inner Mongolia, and Its Implications

Considering porphyry and wall rocks as a whole system, the behaviour of rare earth elements (REE) in hydrothermal alteration and mineralization of the exceedingly large Wunugetushan porphyry Cu-Mo deposit of Inner Mongolia has been studied. It has been found for the first time that there exists complementary REE variation in hydrothermal alteration between porphyry and wall rocks, and Eu depletion has certain significance in indicating mineralization. Based on an analysis of the variation in REE contents of relevant minerals during the hydrothermal alteration, the ore-forming fluids are inferred to be depleted in ∑REE, comparatively enriched in ∑Y and strongly depleted in Eu. In the intermediate-strong alteration zones, porphyry and wall rock took part in hydrothermal metasomatism and alteration almost in equal ratio mass. Furthermore, studies of REE and hydrogen and oxygen isotopes and fluid inclusions confirm the existence of hydrothermal convection and the possibility of supplying part of ore materials by the wall rock and indicate that the application of REE geochemistry in mineral prospecting is promising.

Late Jurassic Cu-Mo Mineralization at the Zhashui-Shanyang District,South Qinling,China:Constraints from Re-Os Molybdenite and Laser Ablation-Inductively Coupled Plasma Mass Spectrometry U-Pb Zircon Dating

The Zhashui-Shanyang district is one of the most important sulfide deposits in the Qinling Orogen where the formation of porphyry-skarn Cu-Mo deposits has a close genetic link with the Yanshannian magmatism.Laser Ablation-Inductively Coupled Plasma Mass Spectrometry（LA-ICP-MS） U-Pb zircon dating of two granodiorite intrusions（Xiaohekou and Lengshuigou deposits）was investigated in the Zhashui-Shanyang district and the rock-forming ages obtained from 148.3±2.8 to 152.6±1.2 Ma,averaging 150.5 Ma,accompanied by a younger disturbance age of 144.3±1.7 Ma in the Lengshuigou intrusion,which is in excellent agreement with published sensitive high resolution ion micro-probe（SHRIMP）zircon date on the later monzodiorite porphyry phase in the Lenshuigou deposit.Two samples were selected for molybdenite ICP-MS Re-Os isotopic analyses from the Lengshuigou granodiorite porphyry,yielding Re-Os model ages from 149.2±2.7 Ma to 150.6±3.4 Ma, with a weighted mean age of 149.7±2.1 Ma.These mineralization ages overlap rock-forming ages of the host intrusions within the error range.This implies that the mineralization occurred in the Late Jurassic,which belongs to the tectonic phase B event of the Yanshan Movement,not Cretaceous as previously thought.Therefore,the Late Jurassic mineralization of the Zhashui-Shanyang district could be connected to the large-scale Yanshan molybdenum metallogenic period,the geodynamic regime of which is attributable to the far field response of convergence of surrounding plates,perhaps the approximately westward subduction of the Izanagi plate beneath the Eurasian continent.

In situ U-Pb dating and trace elements of magmatic rutile from Mujicun Cu-Mo deposit,North China Craton:Insights into porphyry mineralization

Porphyry Cu(Mo-Au)deposit is one of the most important types of copper deposit and usually formed under magmatic arc-related settings,whilst the Mujicun porphyry Cu-Mo deposit in North China Craton uncommonly generated within intra-continental settings.Although previous studies have focused on the age,origin and ore genesis of the Mujicun deposit,the ore-forming age,magma source and tectonic evolution remain controversial.Here,this study targeted rutile(TiO_(2))in the ore-hosting diorite porphyry from the Mujicun Cu-Mo deposit to conduct in situ U-Pb dating and trace element composition studies,with major views to determine the timing and magma evolution and to provide new insights into porphyry Cu-Mo metallogeny.Rutile trace element data show flat-like REE patterns characterized by relatively enrichment LREEs and depleted HREEs,which could be identified as magmatic rutile.Rutile U-Pb dating yields lower intercept ages of 139.3–138.4 Ma,interpreted as post magmatic cooling timing below about 500℃,which are consistent or slightly postdate with the published zircon U-Pb ages of diorite porphyry(144.1–141.7 Ma)and skarn(146.2 Ma;139.9 Ma)as well as the molybdenite Re-Os ages of molybdenum ores(144.8–140.0 Ma).Given that the overlap between the closure temperature of rutile U-Pb system and ore-forming temperature of the Mujicun deposit,this study suggests that the ore-forming ages of the Mujicun deposit can be constrained at 139.3–138.4 Ma,with temporal links to the late large-scale granitic magmatism at 138–126 Ma in the Taihang Orogen.Based on the Mg and Al contents in rutile,the magma of ore-hosting diorite porphyry was suggested to be derived from crust-mantle mixing components.In conjunction with previous studies in Taihang Orogen,this study proposes that the far-field effect and the rollback of the subducting Paleo-Pacific slab triggered lithospheric extension,asthenosphere upwelling,crust-mantle interaction and thermo-mechanical erosion,which jointly facilitated the formation of dioritic magmas during the Early Cretaceous.Subsequently,the dioritic magmas carrying crust-mantle mixing metallic materials were emplaced and precipitated at shallow positions along NNE-trending ore-controlling faults,eventually resulting in the formation of the Mujicun Cu-Mo deposit within an intracontinental extensional setting.

内蒙古乌努格吐山铜钼矿床Cu、Mo同位素组成及绢云母Ar-Ar测年对区域成矿作用的启示

内蒙古乌努(奴)格吐山铜铅锌矿整装勘查区位于得尔布干成矿带西南段,是我国北方重要的Cu-Mo-Fe-Au-AgPb-Zn成矿带。近年来随着多接收电感耦合等离子体质谱(MC-ICP-MS)的广泛应用,使Mo、Cu、Fe、Zn等同位素的研究应用于矿床学研究中。本文通过对乌努格吐山斑岩型矿床黄铜矿Cu同位素、辉钼矿Mo同位素组成,绢云母Ar-Ar年龄进行研究,借此探讨该矿床的形成时代、矿床成因。结果显示,矿床成矿早阶段的绢云母坪年龄为181.9±1.1Ma,等时线年龄为181.0±2.3Ma,与辉钼矿Re-Os等时线年龄相一致。而石英+钾长石+辉钼矿+黄铜矿+黄铁矿脉中和石英+黄铜矿+黄铁矿脉中黄铜矿的δ65 Cu平均值分别为0.31y‰和0.40‰,显示黄铜矿的δ65 Cu值从早到晚逐渐增高,这可能为流体出溶过程中63 Cu优先进入富气相流体,残余岩浆流体逐渐富集65 Cu的结果。辉钼矿的δ98 Mo/δ95 Mo介于-0.16‰~0.35‰之间,说明在成矿作用的过程中Mo进入不同的矿物组合中并发生了同位素分馏,可能受到了氧化还原条件、温度等物理化学条件的变化,或者是辉钼矿的多型特征的影响。得尔布干成矿带矿床的形成与蒙古鄂霍次克洋的演化密切相关,结合前人研究成果,将成矿带斑岩型矿床分为240~230Ma、180~200Ma、150~160Ma三期。