Frozen soils or those with permafrost cover large areas of the earth's surface and support unique vegetative ecosystems. Plants growing in such harsh conditions have adapted to small niches, which allow them to su...Frozen soils or those with permafrost cover large areas of the earth's surface and support unique vegetative ecosystems. Plants growing in such harsh conditions have adapted to small niches, which allow them to survive. In northern Alaska, USA, both moist acidic and non-acidic tundra occur, yet determination of frozen soil p Hs currently requires thawing of the soil so that electrometric pH methods can be utilized. Contrariwise, a portable X-ray fluorescence(PXRF) spectrometer was used in this study to assess elemental abundances and relate those characteristics to soil pH through predictive multiple linear regressions. Two operational modes, Soil Mode and Geochem Mode, were utilized to scan frozen soils in-situ and under laboratory conditions, respectively, after soil samples were dried and ground. Results showed that lab scanning produced optimal results with adjusted coefficient of determination(R^2) of 0.88 and 0.33 and root mean squared errors(RMSEs) of 0.87 and 0.34 between elemental data and lab-determined pH for Soil Mode and Geochem Mode, respectively. Even though the presence of ice attenuated fluoresced radiation under field conditions, adjusted R^2 and RMSEs between the datasets still provided reasonable model generalization(e.g., 0.73 and 0.49 for field Geochem Mode). Principal component analysis qualitatively separated multiple sampling sites based on elemental data provided by PXRF, reflecting differences in the chemical composition of the soils studied. Summarily, PXRF can be used for in-situ determination of soil pH in arctic environments without the need for sample modification and thawing. Furthermore, use of PXRF for determination of soil pH may provide higher sample throughput than traditional eletrometric-based methods, while generating elemental data useful for the prediction of multiple soil parameters.展开更多
X-ray pulsars offer stable, periodic X-ray pulse sequences that can be used in spacecraft positioning systems. A method using X-ray pulsars to determine the initial orbit of a satellite is presented in this paper. Thi...X-ray pulsars offer stable, periodic X-ray pulse sequences that can be used in spacecraft positioning systems. A method using X-ray pulsars to determine the initial orbit of a satellite is presented in this paper. This method suggests only one detector to be equipped on the satellite and assumes that the detector observes three pulsars in turn. To improve the performance, the use of incremental phase in one observation duration is proposed, and the incremental phase is combined with the time difference of arrival(TDOA). Then, a weighted least squares(WLS) algorithm is formulated to calculate the initial orbit. Numerical simulations are performed to assess the proposed orbit determination method.展开更多
文摘Frozen soils or those with permafrost cover large areas of the earth's surface and support unique vegetative ecosystems. Plants growing in such harsh conditions have adapted to small niches, which allow them to survive. In northern Alaska, USA, both moist acidic and non-acidic tundra occur, yet determination of frozen soil p Hs currently requires thawing of the soil so that electrometric pH methods can be utilized. Contrariwise, a portable X-ray fluorescence(PXRF) spectrometer was used in this study to assess elemental abundances and relate those characteristics to soil pH through predictive multiple linear regressions. Two operational modes, Soil Mode and Geochem Mode, were utilized to scan frozen soils in-situ and under laboratory conditions, respectively, after soil samples were dried and ground. Results showed that lab scanning produced optimal results with adjusted coefficient of determination(R^2) of 0.88 and 0.33 and root mean squared errors(RMSEs) of 0.87 and 0.34 between elemental data and lab-determined pH for Soil Mode and Geochem Mode, respectively. Even though the presence of ice attenuated fluoresced radiation under field conditions, adjusted R^2 and RMSEs between the datasets still provided reasonable model generalization(e.g., 0.73 and 0.49 for field Geochem Mode). Principal component analysis qualitatively separated multiple sampling sites based on elemental data provided by PXRF, reflecting differences in the chemical composition of the soils studied. Summarily, PXRF can be used for in-situ determination of soil pH in arctic environments without the need for sample modification and thawing. Furthermore, use of PXRF for determination of soil pH may provide higher sample throughput than traditional eletrometric-based methods, while generating elemental data useful for the prediction of multiple soil parameters.
基金supported by the National Natural Science Foundation of China(No.61401340)the Natural Science Basic Research Plan in Shaanxi Province of China(No.2016JM6035)+1 种基金the Fundamental Research Funds for the Central Universities,China(No.JB161303)and the Areospace T.T.&C.Innovation Program(No.201515A)
文摘X-ray pulsars offer stable, periodic X-ray pulse sequences that can be used in spacecraft positioning systems. A method using X-ray pulsars to determine the initial orbit of a satellite is presented in this paper. This method suggests only one detector to be equipped on the satellite and assumes that the detector observes three pulsars in turn. To improve the performance, the use of incremental phase in one observation duration is proposed, and the incremental phase is combined with the time difference of arrival(TDOA). Then, a weighted least squares(WLS) algorithm is formulated to calculate the initial orbit. Numerical simulations are performed to assess the proposed orbit determination method.
