The sticking coefficients of ozone on ice surface and solid solution of sulfate and sulfide were measured over a temperature range from 200K to 260K. Experiments were performed in a horizontal flow tube. Results indi...The sticking coefficients of ozone on ice surface and solid solution of sulfate and sulfide were measured over a temperature range from 200K to 260K. Experiments were performed in a horizontal flow tube. Results indicate that the sticking coefficients of ozone on ice are in the range from 1 3×10 -7 to 2 7×10 -6 , and it will become larger as temperature increases; the sticking coefficients of ozone on eight kinds of 0.1mol/L sulfate doped ice are in the range from 1 8×10 -7 to 6 9×10 -6 ; the sticking coefficients of ozone on four kinds of 0 1 mol/L sulfide doped ice are in the range from 3 2×10 -7 to 2 1×10 -5 . Ozone loss on these particles was evaluated.展开更多
The association of pollutants (nutrients, heavy metals and organic compounds) with colloidal and suspended particle matter(SPM) plays a dominant role in determining their transport, fate, biogeochemistry, bioavailabil...The association of pollutants (nutrients, heavy metals and organic compounds) with colloidal and suspended particle matter(SPM) plays a dominant role in determining their transport, fate, biogeochemistry, bioavailability and toxicity in natural waters. A scheme for the fractionation and composition of colloidal and suspended particulate matter from river waters has been tested. Sieving, continuous flow centrifugation and tangential flow filtration were used to collect gram amounts of colloidal and particulate matters. The separation scheme was able to process large samples(100L), within reasonable times(1 day) and the apparatus was portable. The aquatic colloid was also separated with high resolution, and sized using sedimentation field\|flow fractionation technique. The mass\|based particle size distribution for the river water sample showed a broad size distribution between 0\^05 and 0\^4 μm with the maximum around 0\^14 μm. There was a systematic increase in the content of organic carbon, Mg, Ca, Na, Cu and Zn with decreasing particle size, highlighting the importance of the colloidal(<1 μm) fraction.展开更多
文摘The sticking coefficients of ozone on ice surface and solid solution of sulfate and sulfide were measured over a temperature range from 200K to 260K. Experiments were performed in a horizontal flow tube. Results indicate that the sticking coefficients of ozone on ice are in the range from 1 3×10 -7 to 2 7×10 -6 , and it will become larger as temperature increases; the sticking coefficients of ozone on eight kinds of 0.1mol/L sulfate doped ice are in the range from 1 8×10 -7 to 6 9×10 -6 ; the sticking coefficients of ozone on four kinds of 0 1 mol/L sulfide doped ice are in the range from 3 2×10 -7 to 2 1×10 -5 . Ozone loss on these particles was evaluated.
文摘The association of pollutants (nutrients, heavy metals and organic compounds) with colloidal and suspended particle matter(SPM) plays a dominant role in determining their transport, fate, biogeochemistry, bioavailability and toxicity in natural waters. A scheme for the fractionation and composition of colloidal and suspended particulate matter from river waters has been tested. Sieving, continuous flow centrifugation and tangential flow filtration were used to collect gram amounts of colloidal and particulate matters. The separation scheme was able to process large samples(100L), within reasonable times(1 day) and the apparatus was portable. The aquatic colloid was also separated with high resolution, and sized using sedimentation field\|flow fractionation technique. The mass\|based particle size distribution for the river water sample showed a broad size distribution between 0\^05 and 0\^4 μm with the maximum around 0\^14 μm. There was a systematic increase in the content of organic carbon, Mg, Ca, Na, Cu and Zn with decreasing particle size, highlighting the importance of the colloidal(<1 μm) fraction.
