In this paper water-soluble C 60 derivative was iodolabelled radioactively with Iodogen method. The labelled yield was measured by Silica GF254 TLC. The effects of pH value, time, temperature and the amount of Iodogen...In this paper water-soluble C 60 derivative was iodolabelled radioactively with Iodogen method. The labelled yield was measured by Silica GF254 TLC. The effects of pH value, time, temperature and the amount of Iodogen on the labelled yield were studied. 125 I-C 60 (OH) x O y was purified by Sephadex G-25 column chromatography and then the stability of 125 I-C 60 (OH) x O y was examined. The results showed that the radiochemical purity of 125 I-C 60 (OH) xO y solution with 2% benzylalcohol remained 82.7% after 43h.展开更多
Ultrathin InSb films on SiO2/Si substrates are prepared by radio frequency（RF） magnetron sputtering and rapid thermal annealing（RTA） at 300,400,and 500℃,respectively.X-ray diffraction（XRD） indicates that InSb f...Ultrathin InSb films on SiO2/Si substrates are prepared by radio frequency（RF） magnetron sputtering and rapid thermal annealing（RTA） at 300,400,and 500℃,respectively.X-ray diffraction（XRD） indicates that InSb film treated by RTA at 500℃,which is higher than its melting temperature（about 485℃）,shows a monocrystalline-like feature.A high-resolution transmission electron microscopy（HRTEM） micrograph shows that melt recrystallization of InSb film on SiO2/Si（111） substrate is along the（111） planes.The transmittances of InSb films decrease and the optical band gaps redshift from 0.24 eV to 0.19 eV with annealing temperature increasing from 300℃ to 500℃,which is indicated by Fourier transform infrared spectroscopy（FTIR） measurement.The observed changes demonstrate that RTA is a viable technique for improving characteristics of InSb films,especially the melt-recrystallized film treated by RTA at 500℃.展开更多
A mechanochemical redox reaction between KMnO4 and CoCl2 was developed to obtain a CoxMn1-xOy catalyst with a specific surface area of 479 m^2 g^-1,which was higher than that obtained using a co-precipitation(CP)metho...A mechanochemical redox reaction between KMnO4 and CoCl2 was developed to obtain a CoxMn1-xOy catalyst with a specific surface area of 479 m^2 g^-1,which was higher than that obtained using a co-precipitation(CP)method(34 m2 g^-1),sol-gel(SG)method(72 m^2 g^-1),or solution redox process(131 m^2 g^-1).During catalytic combustion,this CoxMn1-xOy catalyst exhibited better activity(T100 for propylene=~200℃)than the control catalysts obtained using the SG(325℃)or CP(450℃)methods.The mechanical action,mainly in the form of kinetic energy and frictional heating,may generate a high degree of interstitial porosity,while the redox reaction could contribute to good dispersion of cobalt and manganese species.Moreover,the as-prepared CoxMn1-xOy catalyst worked well in the presence of water vapor(H2O 4.2%,>60 h)or SO2(100 ppm)and at high temperature(400℃,>60 h).The structure MnO2·(CoOOH)2.93 was suggested for the current CoxMn1-xOy catalyst.This catalyst could be extended to the total oxidation of other typical hydrocarbons(T90=150°C for ethanol,T90=225°C for acetone,T90=250℃for toluene,T90=120℃for CO,and T90=540℃for CH4).Scale-up of the synthesis of CoxMn1-xOy catalyst(1 kg)can be achieved via ball milling,which may provide a potential strategy for real world catalysis.展开更多
文摘In this paper water-soluble C 60 derivative was iodolabelled radioactively with Iodogen method. The labelled yield was measured by Silica GF254 TLC. The effects of pH value, time, temperature and the amount of Iodogen on the labelled yield were studied. 125 I-C 60 (OH) x O y was purified by Sephadex G-25 column chromatography and then the stability of 125 I-C 60 (OH) x O y was examined. The results showed that the radiochemical purity of 125 I-C 60 (OH) xO y solution with 2% benzylalcohol remained 82.7% after 43h.
基金Project supported by the Special Funds for State 11th Five-Year Basic Research Project of China (Grant No. 51318060207)
文摘Ultrathin InSb films on SiO2/Si substrates are prepared by radio frequency（RF） magnetron sputtering and rapid thermal annealing（RTA） at 300,400,and 500℃,respectively.X-ray diffraction（XRD） indicates that InSb film treated by RTA at 500℃,which is higher than its melting temperature（about 485℃）,shows a monocrystalline-like feature.A high-resolution transmission electron microscopy（HRTEM） micrograph shows that melt recrystallization of InSb film on SiO2/Si（111） substrate is along the（111） planes.The transmittances of InSb films decrease and the optical band gaps redshift from 0.24 eV to 0.19 eV with annealing temperature increasing from 300℃ to 500℃,which is indicated by Fourier transform infrared spectroscopy（FTIR） measurement.The observed changes demonstrate that RTA is a viable technique for improving characteristics of InSb films,especially the melt-recrystallized film treated by RTA at 500℃.
文摘A mechanochemical redox reaction between KMnO4 and CoCl2 was developed to obtain a CoxMn1-xOy catalyst with a specific surface area of 479 m^2 g^-1,which was higher than that obtained using a co-precipitation(CP)method(34 m2 g^-1),sol-gel(SG)method(72 m^2 g^-1),or solution redox process(131 m^2 g^-1).During catalytic combustion,this CoxMn1-xOy catalyst exhibited better activity(T100 for propylene=~200℃)than the control catalysts obtained using the SG(325℃)or CP(450℃)methods.The mechanical action,mainly in the form of kinetic energy and frictional heating,may generate a high degree of interstitial porosity,while the redox reaction could contribute to good dispersion of cobalt and manganese species.Moreover,the as-prepared CoxMn1-xOy catalyst worked well in the presence of water vapor(H2O 4.2%,>60 h)or SO2(100 ppm)and at high temperature(400℃,>60 h).The structure MnO2·(CoOOH)2.93 was suggested for the current CoxMn1-xOy catalyst.This catalyst could be extended to the total oxidation of other typical hydrocarbons(T90=150°C for ethanol,T90=225°C for acetone,T90=250℃for toluene,T90=120℃for CO,and T90=540℃for CH4).Scale-up of the synthesis of CoxMn1-xOy catalyst(1 kg)can be achieved via ball milling,which may provide a potential strategy for real world catalysis.
