The analysis of early stage rodingite from the ultramafic rocks of the Xialu Massif in the Xigaze Ophiolite,Tibet,in China shows that the rodingitization involved continuous changes in fluid composition during differe...The analysis of early stage rodingite from the ultramafic rocks of the Xialu Massif in the Xigaze Ophiolite,Tibet,in China shows that the rodingitization involved continuous changes in fluid composition during different stages of subduction.The early stage prehnite-bearing rodingite was produced at low pressures and temperatures along extensional fractures.Samples of rodingite were collected along a profile from the center to the margin of a rodingitized intrusive igneous rock(^10 m×30 m),and they record wide variations in bulk composition,mineralogy,and texture.The mineral assemblages,from center to margin,vary from(1)relics of primary clinopyroxene(Cpx_(r))and primary amphibole(Amp_(r))+newly formed late amphibole(Act)+primary plagioclase(Pl_(r))+clinozoisite+prehnite+albite+chlorite+titanite+ilmenite(R1 rodingite),through(2)relics of primary clinopyroxene(Cpx_(r))+newly formed late clinopyroxene(Cpx_(n))+primary and late amphiboles(Amp_(r)+Act)+clinozoisite+prehnite+albite+chlorite+titanite(R2 rodingite),to(3)newly formed late clinopyroxene(Cpx_(n))and amphibole(Act)+clinozoisite+prehnite+albite+chlorite+titanite(R3 rodingite).As a result of the metasomatic process of rodingitization,the content of CaO in the whole rock chemical composition from R1 to R3 increases,SiO_(2) decreases,and Na_(2)O+K_(2)O is almost completely removed.Massbalance diagrams show enrichments in large ion lithophile elements such as Rb,Cs,Ba,and Pb as well as Ni during rodingitization.The central part of the rodingitized intrusion(R1 rodingite)was only slightly affected by metasomatism.On the other hand,the contents of the rare earth elements(REEs),high field strength elements(HFSEs;e.g.Zr,Nb,Ta,Hf,and Y),and some highly compatible elements such as Cr and Sc decreased slightly during rodingitization.Thermodynamic modeling based on equilibrium mineral assemblages indicates that the rodingite of the Xialu Massif formed in an H_(2)O-saturated,CO_(2)-rich environment.The estimated conditions of metamorphism were-281-323℃and 0.4-3.9 kbar,representing the subgreenschist facies.In this environment,REEs and HFSEs were soluble in the fluids and partly removed.Moreover,these prehnite rodingites formed in a progressively reducing and less alkaline environment,as indicated by decreases in f(O_(2))and bulk-rock Fe^(3+)/Fe^(2+) ratios,and the records of fluidΔpH from the center to the margin of the studied rodingitized intrusion.展开更多
Meso\| and microstructural characteristics of cataclastic fault rocks developed in the Xialu chert are described. The Xialu chert represents pelagic and deep marine sediments (Middle Jurassic—Lower Cretaceous), and o...Meso\| and microstructural characteristics of cataclastic fault rocks developed in the Xialu chert are described. The Xialu chert represents pelagic and deep marine sediments (Middle Jurassic—Lower Cretaceous), and occupies the southern marginal part of the E—W trending Yarlung Zangbo suture zone. The apparent total thickness of siliceous deposits exceeds 1km. The current study is concentrated along the two measured sections, Xialu\|E and Xialu\|W. The Xialu\|E section is composed mainly of red chert associated with reddish purple siliceous mudstone and greenish gray mudstone. The beds steeply dip north or south. The 45m section studied is divided into three units (chert unit, chert\|siliceous mudstone unit, and melange unit from north to south). They are in fault contact with each other. In the southern half of the chert unit and the northernmost of the chert\|siliceous mudstone unit, a 15m thick cohesive cataclasite zone can be defined. The cataclasites are composed of chert fragments in a fine grained matrix, and deformed with jigsaw puzzle structures. The chert\|siliceous mudstone unit is made up of four slabs of chert\|siliceous mudstone sequence. Mesoscopic duplex zones in thickness from 1 to 3m are recognized at slab boundaries. Flat and ramp structure and associated P foliations, R1 shears, Y surfaces are developed. Shear spacing range from 1 to 10cm. The slip senses are dextral strike\|slip movement along these duplex zones. The cataclasite zone is cut by the duplex zone along the southern boundary.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.41572044)the SGSTSP of the Chinese Academy of Sciences(Grant No.XDB03010201)+1 种基金SDUST Research Fund(Grant No.2015TDJH101)financial support from Chinese Scholarship Council(Grant No.201808370192)。
文摘The analysis of early stage rodingite from the ultramafic rocks of the Xialu Massif in the Xigaze Ophiolite,Tibet,in China shows that the rodingitization involved continuous changes in fluid composition during different stages of subduction.The early stage prehnite-bearing rodingite was produced at low pressures and temperatures along extensional fractures.Samples of rodingite were collected along a profile from the center to the margin of a rodingitized intrusive igneous rock(^10 m×30 m),and they record wide variations in bulk composition,mineralogy,and texture.The mineral assemblages,from center to margin,vary from(1)relics of primary clinopyroxene(Cpx_(r))and primary amphibole(Amp_(r))+newly formed late amphibole(Act)+primary plagioclase(Pl_(r))+clinozoisite+prehnite+albite+chlorite+titanite+ilmenite(R1 rodingite),through(2)relics of primary clinopyroxene(Cpx_(r))+newly formed late clinopyroxene(Cpx_(n))+primary and late amphiboles(Amp_(r)+Act)+clinozoisite+prehnite+albite+chlorite+titanite(R2 rodingite),to(3)newly formed late clinopyroxene(Cpx_(n))and amphibole(Act)+clinozoisite+prehnite+albite+chlorite+titanite(R3 rodingite).As a result of the metasomatic process of rodingitization,the content of CaO in the whole rock chemical composition from R1 to R3 increases,SiO_(2) decreases,and Na_(2)O+K_(2)O is almost completely removed.Massbalance diagrams show enrichments in large ion lithophile elements such as Rb,Cs,Ba,and Pb as well as Ni during rodingitization.The central part of the rodingitized intrusion(R1 rodingite)was only slightly affected by metasomatism.On the other hand,the contents of the rare earth elements(REEs),high field strength elements(HFSEs;e.g.Zr,Nb,Ta,Hf,and Y),and some highly compatible elements such as Cr and Sc decreased slightly during rodingitization.Thermodynamic modeling based on equilibrium mineral assemblages indicates that the rodingite of the Xialu Massif formed in an H_(2)O-saturated,CO_(2)-rich environment.The estimated conditions of metamorphism were-281-323℃and 0.4-3.9 kbar,representing the subgreenschist facies.In this environment,REEs and HFSEs were soluble in the fluids and partly removed.Moreover,these prehnite rodingites formed in a progressively reducing and less alkaline environment,as indicated by decreases in f(O_(2))and bulk-rock Fe^(3+)/Fe^(2+) ratios,and the records of fluidΔpH from the center to the margin of the studied rodingitized intrusion.
文摘Meso\| and microstructural characteristics of cataclastic fault rocks developed in the Xialu chert are described. The Xialu chert represents pelagic and deep marine sediments (Middle Jurassic—Lower Cretaceous), and occupies the southern marginal part of the E—W trending Yarlung Zangbo suture zone. The apparent total thickness of siliceous deposits exceeds 1km. The current study is concentrated along the two measured sections, Xialu\|E and Xialu\|W. The Xialu\|E section is composed mainly of red chert associated with reddish purple siliceous mudstone and greenish gray mudstone. The beds steeply dip north or south. The 45m section studied is divided into three units (chert unit, chert\|siliceous mudstone unit, and melange unit from north to south). They are in fault contact with each other. In the southern half of the chert unit and the northernmost of the chert\|siliceous mudstone unit, a 15m thick cohesive cataclasite zone can be defined. The cataclasites are composed of chert fragments in a fine grained matrix, and deformed with jigsaw puzzle structures. The chert\|siliceous mudstone unit is made up of four slabs of chert\|siliceous mudstone sequence. Mesoscopic duplex zones in thickness from 1 to 3m are recognized at slab boundaries. Flat and ramp structure and associated P foliations, R1 shears, Y surfaces are developed. Shear spacing range from 1 to 10cm. The slip senses are dextral strike\|slip movement along these duplex zones. The cataclasite zone is cut by the duplex zone along the southern boundary.