Isotope Geochemistry of the Xinchang -Yongjia Silver (Lead-Zinc)Ore Belt in Eastern Zhejiang Province

In the Xinchang-Yongjia silver (lead-zinc) ore belt, there mainly occur the large to medium-sized Haoshi, Bamao, Dalingkou and Wubu silver deposits or silver-bearing lead-zinc deposits. On the basis of researches on these typical deposits, the mechanism of leaching-drawing mineralization of Mesozoic geothermal water and the related model are put forward in this paper in the light of the time interval between rock and formation ages as well as hydrogen, oxygen, sulphur and lead isotope geochemical characteristics. The major metallogenic process occurred in volcanic rock layers. The ore-forming fluids are geothermal water coming from meteoric water and circulating at shallow layers. This geothermal water leached and absorbed ore-forming materials from its country rocks during its flowing (such metallogenic elements as silver, lead-zinc and sulphur mainly came from consolidated volcanic rocks), leading to the formation of meso - epithermal silver deposits.

延边天宝山矿集区新兴铅锌(银)矿床成矿岩体的年代学与地球化学特征

新兴铅锌（银）矿床位于兴蒙造山带东段的天宝山矿集区,主矿体受花岗闪长岩体中的角砾岩筒控制。为确定该矿床的成岩成矿时代、物质源区和构造背景,对与成矿作用关系密切的花岗闪长岩进行了LA-ICP-MS锆石U-Th-Pb同位素测定和岩石地球化学分析。结果表明：花岗闪长岩中锆石U-Pb年龄的加权平均值为264.6±4.4 Ma（n=15）,表明该岩体侵位于中二叠世;新兴花岗闪长岩的元素地球化学特征上表现为富钠（Na2O/K2O为1.36-1.85,均〉1）、准铝质（A/CNK值为0.96-1.04,均值0.99）和中等偏高的Al2O3含量（16.04%-16.34%）,属I型花岗岩和高钾钙碱性-钙碱性岩石系列,具有岛弧岩浆岩的地球化学属性;微量元素组成上,富集轻稀土[（La/Yb）N=8.44-16.64],具弱的负Ce异常（δCe=0.72-0.91,均值为0.83）和弱的正Eu异常（δEu=1.00-1.15,均值为1.06）,富集大离子亲石元素（LILE）Ba、Rb、K及不相容元素Th、U,相对亏损高场强元素（HFSE）Ta、Nb和Ti等,微量元素比值介于地壳和地幔平均值之间,均表明新兴成矿岩体形成过程中壳源物质的贡献。结合东北地区晚古生代区域构造演化,认为该花岗闪长岩体及相关热液成矿事件是中二叠世古亚洲洋板块俯冲作用的结果。该期岩浆-成矿事件的识别对区内区域成矿作用及成矿规律研究具重要意义。

延边天宝山矿集区晚古生代岩浆-热液成矿的年代学证据——以新兴铅锌(银)矿床为例

延边天宝山矿集区已发现矽卡岩型铅锌铜矿床(立山和选厂后山)、隐爆角砾岩型铅锌(银)矿床(新兴)、沉积变质-热液改造型铜铅锌矿床(东风南山)和斑岩型钼矿床(东风北山)等四种成因类型、十余个矿床(点)。为确定矿集区内多金属成矿作用的期次,在已有工作基础上,本文首次采用LA-ICP-MS锆石U-Pb法和金属硫化物Rb-Sr法,对新兴铅锌(银)矿床开展了同位素年代学研究。结果表明,与角砾岩型铅锌(银)矿化密切相关的新兴花岗闪长岩的16个锆石测点的206Pb/238U年龄加权平均值为261. 1±3. 5Ma(MSWD=0. 46),角砾岩型矿石6件金属硫化物的Rb-Sr等时线年龄为259±3Ma(MSWD=1. 05),锶同位素初始值ISr=0. 71359,表明新兴矿床的成岩成矿时代为中二叠世晚期。结合矿集区内其它矿床的同位素测年资料分析认为,天宝山矿集区至少发生过晚古生代和早中生代两期岩浆-热液成矿事件,在中-晚二叠世形成了立山、选厂后山和新兴等多金属矿床,在早侏罗世则形成了东风北山斑岩型钼矿床。新兴矿床6件金属硫化物的Rb、Sr含量分别介于0. 1238×10-6～0. 7536×10-6和0. 3786×10-6～3. 247×10-6之间,初始Sr同位素比值(87Sr/86Sr)i介于0. 71350～0. 71371之间,均值为0. 71361,表明成矿物质以壳源为主,并有少量幔源物质的加入。综合研究表明,在中-晚二叠世(255～265Ma),受古亚洲洋俯冲作用的影响,天宝山矿集区发生了深源岩浆侵入,引发地壳物质同熔,形成富含Cu、Pb、Zn、Ag等金属元素的花岗闪长质岩浆,沿着构造裂隙上升至地壳浅部,侵位形成了矿集区内的立山、新兴、东风北山等多个晚古生代成矿(含矿)中酸性岩体。在花岗闪长岩与大理岩接触带附近,通过含矿热液交代作用,形成了立山、选厂后山等矽卡岩型铅锌铜矿床;随着岩浆期后热液在岩浆房顶部的不断聚集,挥发分的增加,当内压大于上部围岩压力时,发生隐爆作用,形成隐爆角砾岩,压力骤减引起流体不混溶,导致铅、锌、银等金属组分沉淀富集,形成新兴隐爆角砾岩型铅锌(银)矿床。