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沉积速率对MOCVD-Y(Gd)BCO超导薄膜结构与性能的影响研究
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作者 杨帆 赵睿鹏 +2 位作者 陈曦 黄涛 陶伯万 《电子元件与材料》 CAS CSCD 北大核心 2021年第8期788-794,共7页
第二代高温超导带材制备中提升超导层的沉积速率有助于降低带材成本。本文基于自主设计的MOCVD系统在LaMnO_(3)/epi-MgO/IBAD-MgO/Y_(2)O_(3)/Al_(2)O_(3)/哈氏合金模板基带上沉积Y(Gd)BCO高温超导薄膜。通过改变前驱体进液速率实现沉... 第二代高温超导带材制备中提升超导层的沉积速率有助于降低带材成本。本文基于自主设计的MOCVD系统在LaMnO_(3)/epi-MgO/IBAD-MgO/Y_(2)O_(3)/Al_(2)O_(3)/哈氏合金模板基带上沉积Y(Gd)BCO高温超导薄膜。通过改变前驱体进液速率实现沉积速率的调控,采用多种分析测试方法研究Gd_(0.5)Y_(0.5)Ba_(2)Cu_(3)O_(7)-δ(Y(Gd)BCO)薄膜结构与性能。在加热温度和气氛等工艺条件保持不变的前提下,调节沉积速率为520 nm/min时,制备得到约250 nm厚的Y(Gd)BCO超导层结构性能良好,在0 T,77 K的条件下,临界电流密度(J_(c))可达到3.5 MA/cm^(2),临界电流(I_(c))为89 A/cm,面内、面外半高宽值分别为2.36°和1.69°。即使提高沉积速率到1000 nm/min,虽然Y(Gd)BCO薄膜表面出现了a轴晶粒,但是Jc仍能保持在一个较优的水平。实验结果表明,MOCVD方法可以实现高温超导薄膜的高速率沉积。 展开更多
关键词 高温超导带材 y(gd)bco MOCVD 沉积速率
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Fabrication and Properties of (Y,Gd)BCO Superconductors 被引量:1
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作者 焦玉磊 肖玲 +1 位作者 任洪涛 郑明辉 《Journal of Rare Earths》 SCIE EI CAS CSCD 2004年第6期867-870,共4页
The microstructures and superconducting properties of melt textured(Y_(1-x)Gd_x)BCO bulk samples were studied. It was found that the peritectic decomposition temperature(T_m)of(Y_(1-x)Gd_x)BCO samples increases with i... The microstructures and superconducting properties of melt textured(Y_(1-x)Gd_x)BCO bulk samples were studied. It was found that the peritectic decomposition temperature(T_m)of(Y_(1-x)Gd_x)BCO samples increases with increasing x. Large single domain growth in air is readily obtained in all the composites. The results of X-ray distribution maps of x=0.4 composite indicate that the RE123 matrix is homogeneous and Y and Gd elements in the RE site forms a perfect solid solution. The onset T_c values exceeding 91 K with relatively broad transitions are obtained for almost all the samples. Magnetization measurements show no marked indication for the formation of a peak effect in the J_c-B curves, and the highest J_c measured is 3.08×10~4 A·cm^(-2) for x=0.4 sample at 77 K and self-field. The results clearly indicate that Y dominates the superconducting properties of x=0.2 and (0.4) composites. 展开更多
关键词 y gd)bco SUPERCONDUCTOR melt processing peritectic decomposition temperature rare earths
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