The synthesis and structure of the title complex K_2[Y Ⅲ(dtpa)(H_2O)]·7H_2O (dtpa=diethylenetriaminepentaacetate) were studied. The crystal and molecular structures of the complex were determined by single-crys...The synthesis and structure of the title complex K_2[Y Ⅲ(dtpa)(H_2O)]·7H_2O (dtpa=diethylenetriaminepentaacetate) were studied. The crystal and molecular structures of the complex were determined by single-crystal X-ray structure analysis. The crystal of the complex K_2[Y Ⅲ(dtpa)(H_2O)]·7H_2O belongs to triclinic crystal system and P(-1) space group.The crystal data are as follows:a=0.9671(2)nm,b=1.1327(2)nm,c=1.3389(3)nm,β=86.76(3)°,γ=68.72(3)°,V=1.3324(5)nm3,Z=2,M=699.53,D_C=1.744 g·cm -3,μ=2.586 mm -1 and F(000)=720. The final R and R_W are 0.0467 and 0.1195 for 4524(I>2σ(I)) unique reflections, respectively. The complex anion [Y Ⅲ(dtpa)(H_2O)] 2- has a pseudo-monocapped square antiprismatic nine-coordinate structure in which eight coordinate atoms, three N and five O are from a dtpa ligand and one water molecule coordinates to Y Ⅲ ion directly as the ninth ligand.展开更多
The electroreduction of Y(Ⅲ)on tungsten electrode in NaCl-KCl-YCl_3 melt has been investi- gated by cyclic voltammetry.Deposition of Y(Ⅲ)to Y(0)is reversible in one step.The cyclic voltammetry, convolution voltammet...The electroreduction of Y(Ⅲ)on tungsten electrode in NaCl-KCl-YCl_3 melt has been investi- gated by cyclic voltammetry.Deposition of Y(Ⅲ)to Y(0)is reversible in one step.The cyclic voltammetry, convolution voltammetry,potential-time curve after potentiostatic electrolysis and X-ray diffraction analy- sis were used to study the electrode process of Y(Ⅲ)reduced on iron electrode.Several Y-Fe intermetallic compounds are formed before the deposition of metallic yttrium.The diffusion coefficient and diffusion activation energy of Y in Y_6Fe_(23) were determined by current-time curve at potential step. The results indicate the diffusion of Y in its alloy phase is so slow that this step will control the electrode pro- cess.展开更多
A novel compound, {[Y（HPIDC）（OX）1/2（H2O）]·2H2O}n （1, H3PIDC = 2-（pyridin-4- yl）-1H-imidazole-4,5-dicarboxylic acid, H2OX = oxalic acid）, has been synthesized under hydrothermal conditions and characteri...A novel compound, {[Y（HPIDC）（OX）1/2（H2O）]·2H2O}n （1, H3PIDC = 2-（pyridin-4- yl）-1H-imidazole-4,5-dicarboxylic acid, H2OX = oxalic acid）, has been synthesized under hydrothermal conditions and characterized by thermal analysis （TGA）, powder X-ray diffraction （PXRD）, and single-crystal X-ray diffraction. Complex 1 crystallizes in monoclinic space group P21/c with a = 8.342（8）, b = 14.61（1）, c = 11.487（1）, β = 90.78（9）°, V = 1400.4（2）3, Z = 4, C11H11N3O9Y, Mr = 418.14, Dc = 1.983 g/cm3, F（000） = 836, Rint = 0.0509, T = 293（2） K, μ = 4.240 mm-1, the final R = 0.0477 and wR = 0.1125 for 2770 observed reflections with I 2σ（I）. Compound 1 exhibits a 3D framework and generates the 1D open channels filled with free water molecules. The structure of 1 can be rationalized as a diamondoid network when the atom yttrium is regarded as a 4-connected node linking four surrounding yttrium atoms. The luminescent property of compound 1 is also investigated.展开更多
The adsorption behavior and mechanism of a novel chelate resin, iminodiacetic acid resin (IDAAR) for Y? were investigated. The statically saturated adsorption capacity is 102mg· g- 1 resin at 298K in HAc NaAc med...The adsorption behavior and mechanism of a novel chelate resin, iminodiacetic acid resin (IDAAR) for Y? were investigated. The statically saturated adsorption capacity is 102mg· g- 1 resin at 298K in HAc NaAc medium at pH 5.7. Y? adsorbed on IDAAR can be reductively eluted by 1.0～ 4.0mol· L- 1 HCl used as eluant and the elution percentages are almost as high as 100% . The resin can be regenerated and reused without apparent decrease in adsorption capacity. The apparent adsorption rate constant is k298=3.36× 10- 5s- 1. The adsorption behavior of IDAAR for Y? conforms to Freundlich′ s model reasonably. The thermodynamic adsorption parameter, enthalpy change Δ H of IDAAR for Y? is 18.6kJ· mol- 1. The complex molar ratio of the functional group of IDAAR to Y? is about 3∶ 1. The adsorption mechanism of IDAAR for Y? was examined by using chemical method and IR spectrometry.展开更多
文摘The synthesis and structure of the title complex K_2[Y Ⅲ(dtpa)(H_2O)]·7H_2O (dtpa=diethylenetriaminepentaacetate) were studied. The crystal and molecular structures of the complex were determined by single-crystal X-ray structure analysis. The crystal of the complex K_2[Y Ⅲ(dtpa)(H_2O)]·7H_2O belongs to triclinic crystal system and P(-1) space group.The crystal data are as follows:a=0.9671(2)nm,b=1.1327(2)nm,c=1.3389(3)nm,β=86.76(3)°,γ=68.72(3)°,V=1.3324(5)nm3,Z=2,M=699.53,D_C=1.744 g·cm -3,μ=2.586 mm -1 and F(000)=720. The final R and R_W are 0.0467 and 0.1195 for 4524(I>2σ(I)) unique reflections, respectively. The complex anion [Y Ⅲ(dtpa)(H_2O)] 2- has a pseudo-monocapped square antiprismatic nine-coordinate structure in which eight coordinate atoms, three N and five O are from a dtpa ligand and one water molecule coordinates to Y Ⅲ ion directly as the ninth ligand.
基金The project supported by the National Natural Science Foundation of China
文摘The electroreduction of Y(Ⅲ)on tungsten electrode in NaCl-KCl-YCl_3 melt has been investi- gated by cyclic voltammetry.Deposition of Y(Ⅲ)to Y(0)is reversible in one step.The cyclic voltammetry, convolution voltammetry,potential-time curve after potentiostatic electrolysis and X-ray diffraction analy- sis were used to study the electrode process of Y(Ⅲ)reduced on iron electrode.Several Y-Fe intermetallic compounds are formed before the deposition of metallic yttrium.The diffusion coefficient and diffusion activation energy of Y in Y_6Fe_(23) were determined by current-time curve at potential step. The results indicate the diffusion of Y in its alloy phase is so slow that this step will control the electrode pro- cess.
基金supported by the 973 key program of the MOST(2010CB933501,2012CB821705)the Chinese Academy of Sciences(KJCX2-YW-319,KJCX2-EW-H01)+1 种基金the National Natural Science Foundation of China(20873150,20821061,20973173,50772113 and 91022008)the Natural Science Foundation of Fujian Province(2007HZ0001-1,2009HZ0004-1,2009HZ0005-1,2009HZ0006-1,2006L2005)
文摘A novel compound, {[Y（HPIDC）（OX）1/2（H2O）]·2H2O}n （1, H3PIDC = 2-（pyridin-4- yl）-1H-imidazole-4,5-dicarboxylic acid, H2OX = oxalic acid）, has been synthesized under hydrothermal conditions and characterized by thermal analysis （TGA）, powder X-ray diffraction （PXRD）, and single-crystal X-ray diffraction. Complex 1 crystallizes in monoclinic space group P21/c with a = 8.342（8）, b = 14.61（1）, c = 11.487（1）, β = 90.78（9）°, V = 1400.4（2）3, Z = 4, C11H11N3O9Y, Mr = 418.14, Dc = 1.983 g/cm3, F（000） = 836, Rint = 0.0509, T = 293（2） K, μ = 4.240 mm-1, the final R = 0.0477 and wR = 0.1125 for 2770 observed reflections with I 2σ（I）. Compound 1 exhibits a 3D framework and generates the 1D open channels filled with free water molecules. The structure of 1 can be rationalized as a diamondoid network when the atom yttrium is regarded as a 4-connected node linking four surrounding yttrium atoms. The luminescent property of compound 1 is also investigated.
文摘The adsorption behavior and mechanism of a novel chelate resin, iminodiacetic acid resin (IDAAR) for Y? were investigated. The statically saturated adsorption capacity is 102mg· g- 1 resin at 298K in HAc NaAc medium at pH 5.7. Y? adsorbed on IDAAR can be reductively eluted by 1.0～ 4.0mol· L- 1 HCl used as eluant and the elution percentages are almost as high as 100% . The resin can be regenerated and reused without apparent decrease in adsorption capacity. The apparent adsorption rate constant is k298=3.36× 10- 5s- 1. The adsorption behavior of IDAAR for Y? conforms to Freundlich′ s model reasonably. The thermodynamic adsorption parameter, enthalpy change Δ H of IDAAR for Y? is 18.6kJ· mol- 1. The complex molar ratio of the functional group of IDAAR to Y? is about 3∶ 1. The adsorption mechanism of IDAAR for Y? was examined by using chemical method and IR spectrometry.
