The EPR parameters (zerofield splitting D and g factors g∥, g⊥) for V2+ ion in YAG crystal are calculated from the highorder perturbation formulas. From these calculations, the defect struc...The EPR parameters (zerofield splitting D and g factors g∥, g⊥) for V2+ ion in YAG crystal are calculated from the highorder perturbation formulas. From these calculations, the defect structure of V2+ center is determined. The results are discussed.展开更多
YAG： Ce^3 ＋ phosphor particles were prepared using polyacrylamide gel method. The structure evolution of powders during annealing process was followed by X-ray diffraction determination. It is found that some interm...YAG： Ce^3 ＋ phosphor particles were prepared using polyacrylamide gel method. The structure evolution of powders during annealing process was followed by X-ray diffraction determination. It is found that some intermediate phases, including θ-Al2O3, YAM and YAP, are formed when calcining polyacrylamide gel, however, the pure YAG phase can be formed directly when calcining polyacrylamide gel with α-Al2O3 as seed crystal. These facts show that the existence of α- Al2O3 seed crystal can block the formation of θ-Al2O3, YAM and YAP, and accelerate its reaction with Y2O3 to form YAG phase directly at lower temperature. The emission peak of prepared YAG ： Ce^3 ＋ phosphor is wide with maximum at 550 nm and the exitation band has two peaks, the major one is around at 460 nm, which matches the blue emission of GaN LED and is suitable for the assemble of white LED. Some fluxes can enhance the photoluminescence intensity of phosphor particles, that can be attributed both to the improvement of crystallization processes of YAG and to the stabilization of trivalence cerium ion in YAG：Ce^3 ＋.展开更多
Crystallographic texture control is a major challenge in directionally solidified multiphase eutectic ceramics with complex faceted growth characteristics.In this study,the Czochralski(CZ)technique is proposed to prep...Crystallographic texture control is a major challenge in directionally solidified multiphase eutectic ceramics with complex faceted growth characteristics.In this study,the Czochralski(CZ)technique is proposed to prepare eutectic single crystal ceramic with large size(30 mm×125 mm).A highly oriented and unique texture of Al_(2)O_(3)/Y_(3)Al_(5)O_(12)(YAG)eutectic ceramic is formed via the 112¯0Al_(2)O_(3) single crystal seed induction based on crystallographic orientation tailoring.The orientations of Al_(2)O_(3)/YAG eutectic are more strictly constrained by single crystal seed induction on the basis of the minimum interface energy principle,resulting in a defined single orientation relationship along the solidification direction.In particular,the single crystallographic orientation can be obtained in a short competitive solidification distance under the influence of epitaxial solidification from single crystal seed.Therefore,it has been confirmed that the orientations of 112¯0Al_(2)O_(3) and 111YAG are preferentially stabilized with the minimum under-cooling during directional solidification.Crystallographic orientation disturbances and instabilities due to polycrystalline crystal seed are avoided.Finally,the successful texture control inducted by 112¯0Al_(2)O_(3) single crystal seed can provide a promising orientation design pathway for faced oxide eutectic solidification.展开更多
We report a double Q-switched 946 nm laser with a magnesium-oxide-doped LiNbO3 （MgO：LN） electro-optic （EO） crystal and a monolayer molybdenum diselenide （MoSe2） saturable absorber （SA）. A pulsed laser diode s...We report a double Q-switched 946 nm laser with a magnesium-oxide-doped LiNbO3 （MgO：LN） electro-optic （EO） crystal and a monolayer molybdenum diselenide （MoSe2） saturable absorber （SA）. A pulsed laser diode side-pumped long neodymium-doped yttrium aluminum garnet rod （φ3×65 mm） is used as the gain medium. Large pulse energy up to 3.15 mJ and peak power up to 346 kW are generated at the repetition rate of 550 Hz, corresponding to the beam quality factors of Mx^2=3.849, My^2=3.868. Monolayer MoSe2 nanosheets applied in the experiment would be a promising SA for a passive Q-switching operation.展开更多
文摘The EPR parameters (zerofield splitting D and g factors g∥, g⊥) for V2+ ion in YAG crystal are calculated from the highorder perturbation formulas. From these calculations, the defect structure of V2+ center is determined. The results are discussed.
文摘YAG： Ce^3 ＋ phosphor particles were prepared using polyacrylamide gel method. The structure evolution of powders during annealing process was followed by X-ray diffraction determination. It is found that some intermediate phases, including θ-Al2O3, YAM and YAP, are formed when calcining polyacrylamide gel, however, the pure YAG phase can be formed directly when calcining polyacrylamide gel with α-Al2O3 as seed crystal. These facts show that the existence of α- Al2O3 seed crystal can block the formation of θ-Al2O3, YAM and YAP, and accelerate its reaction with Y2O3 to form YAG phase directly at lower temperature. The emission peak of prepared YAG ： Ce^3 ＋ phosphor is wide with maximum at 550 nm and the exitation band has two peaks, the major one is around at 460 nm, which matches the blue emission of GaN LED and is suitable for the assemble of white LED. Some fluxes can enhance the photoluminescence intensity of phosphor particles, that can be attributed both to the improvement of crystallization processes of YAG and to the stabilization of trivalence cerium ion in YAG：Ce^3 ＋.
基金supported by the National Natural Science Foundation of China(Nos.52130204,52174376 and 51822405)the Guangdong Basic and Applied Basic Research Foundation(No.21201910250000848)+4 种基金the Science and Technology Innovation Team Plan of Shaan Xi Province(No.2021TD-17)the Joint Research Funds of the Department of Science&Technology of Shaanxi Province and NPU(No.2020GXLH-Z-024)The Youth Innovation Team of Shaanxi Universities,the Key R&D Program of Shaanxi Province(No.2019ZDLGY 04-04)the Fundamental Research Funds for the Central Universities(No.D5000210902)the Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University(Nos.CX2021056,CX2021066 and CX2022033),China.
文摘Crystallographic texture control is a major challenge in directionally solidified multiphase eutectic ceramics with complex faceted growth characteristics.In this study,the Czochralski(CZ)technique is proposed to prepare eutectic single crystal ceramic with large size(30 mm×125 mm).A highly oriented and unique texture of Al_(2)O_(3)/Y_(3)Al_(5)O_(12)(YAG)eutectic ceramic is formed via the 112¯0Al_(2)O_(3) single crystal seed induction based on crystallographic orientation tailoring.The orientations of Al_(2)O_(3)/YAG eutectic are more strictly constrained by single crystal seed induction on the basis of the minimum interface energy principle,resulting in a defined single orientation relationship along the solidification direction.In particular,the single crystallographic orientation can be obtained in a short competitive solidification distance under the influence of epitaxial solidification from single crystal seed.Therefore,it has been confirmed that the orientations of 112¯0Al_(2)O_(3) and 111YAG are preferentially stabilized with the minimum under-cooling during directional solidification.Crystallographic orientation disturbances and instabilities due to polycrystalline crystal seed are avoided.Finally,the successful texture control inducted by 112¯0Al_(2)O_(3) single crystal seed can provide a promising orientation design pathway for faced oxide eutectic solidification.
基金supported by the National Natural Science Foundation of China(No.61205114)the Science & Technology Coordinator Innovation Plan Project of the Shaanxi Province(No.2011KTCL01-06)the Key Laboratory Project of Shaanxi(No.2010JS112)
文摘We report a double Q-switched 946 nm laser with a magnesium-oxide-doped LiNbO3 （MgO：LN） electro-optic （EO） crystal and a monolayer molybdenum diselenide （MoSe2） saturable absorber （SA）. A pulsed laser diode side-pumped long neodymium-doped yttrium aluminum garnet rod （φ3×65 mm） is used as the gain medium. Large pulse energy up to 3.15 mJ and peak power up to 346 kW are generated at the repetition rate of 550 Hz, corresponding to the beam quality factors of Mx^2=3.849, My^2=3.868. Monolayer MoSe2 nanosheets applied in the experiment would be a promising SA for a passive Q-switching operation.
