The top-seeded infiltration and growth process (TSIG) is very effective method for the preparation of YBa2Cu3O7-x (YBCO) bulk superconductors. In order to improve the levitation force of the samples, a series of singl...The top-seeded infiltration and growth process (TSIG) is very effective method for the preparation of YBa2Cu3O7-x (YBCO) bulk superconductors. In order to improve the levitation force of the samples, a series of single domain YBCO bulk superconductors with different ratios of nanoscale Y2Ba4CuBiOy (YBi2411) inclusions in the solid phase pellet is successfully fabricated by the TSIG technique on the basis of previous research. In the present work, the results of YBCO bulk superconductors with YBi2411 and CeO2 (1 wt%) codoping system indicate that, the optimum doping of YBi2411 is 2 wt%, the size of Y211 particles is reduced compared with the samples without CeO2 doping;the largest levitation force is about 15 N obtained in the samples with optimum YBi2411, which is about two times higher than that of the sample without CeO2 doping. The results are very helpful for the fabrication of high quality single domain YBCO bulk superconductors.展开更多
Bulk YBa2Cu3O7 samples were prepared by PMP method. Through adjusting ingredients and preparation procedures, a pellet with 3. 5 cm in diameter and 0. 9 cm in thickness was synthesized. A mass of 1. 3 kg on a magnet c...Bulk YBa2Cu3O7 samples were prepared by PMP method. Through adjusting ingredients and preparation procedures, a pellet with 3. 5 cm in diameter and 0. 9 cm in thickness was synthesized. A mass of 1. 3 kg on a magnet can be levitated at about 1 mm height at 77 K. The XRD and SEM indicated that magnetic lifting property can be enhanced by addition of Ag2O and Y2BaCuO5.展开更多
顶部籽晶熔融织构生长法(TSMTG)是制备大尺寸单畴YBCO超导块材最有效的方法之一,然而,TSMTG法却存在着样品易收缩、变形等严重问题.为了解决这一问题,人们发明了顶部籽晶熔渗生长法(TSIG).但传统的TSIG法需要制备Y2Ba Cu O5(Y211),YBa2C...顶部籽晶熔融织构生长法(TSMTG)是制备大尺寸单畴YBCO超导块材最有效的方法之一,然而,TSMTG法却存在着样品易收缩、变形等严重问题.为了解决这一问题,人们发明了顶部籽晶熔渗生长法(TSIG).但传统的TSIG法需要制备Y2Ba Cu O5(Y211),YBa2Cu3Oy(Y123),Ba Cu O2三种粉体,不仅过程复杂、费时费力、耗能污染,且最大的缺陷是无法控制样品中的Y211粒子含量.为了解决这些技术难题,发明了一种新TSIG法,用Y2O3+1.2Ba Cu O2混合粉替代传统的Y211固相源,用Y2O3,Ba Cu O2和Cu O混合粉替代传统的(Y123+3Ba Cu O2+2Cu O)液相源.采用这种新TSIG法,成功地制备出了直径为59和93 mm的单畴YBCO超导块材.通过对采用传统和新TSIG法制备单畴YBCO超导块材的生长速率、磁悬浮力和微观结构的研究发现:(1)采用新TSIG法后,YBCO超导块材的生长速率达到传统方法的1.7倍;(2)采用新TSIG法制备的单畴YBCO超导块材的磁悬浮力比传统方法制备的样品高出65%以上;(3)采用新TSIG法制备单畴YBCO超导块材,样品中的Y211粒子平均粒径约为1μm,明显小于传统TSIG方法所制备样品的3.4μm,而且分布更合理、均匀,有效地提高了样品的磁通钉扎能力.在此基础上,制备出了目前国内最大尺寸(直径93 mm)单畴YBCO超导块材.这些结果表明,新TSIG法对于促进低成本、大尺寸、高质量单畴REBCO超导块材的产业化及其应用进程具有非常重要的指导意义和实用价值.展开更多
文摘The top-seeded infiltration and growth process (TSIG) is very effective method for the preparation of YBa2Cu3O7-x (YBCO) bulk superconductors. In order to improve the levitation force of the samples, a series of single domain YBCO bulk superconductors with different ratios of nanoscale Y2Ba4CuBiOy (YBi2411) inclusions in the solid phase pellet is successfully fabricated by the TSIG technique on the basis of previous research. In the present work, the results of YBCO bulk superconductors with YBi2411 and CeO2 (1 wt%) codoping system indicate that, the optimum doping of YBi2411 is 2 wt%, the size of Y211 particles is reduced compared with the samples without CeO2 doping;the largest levitation force is about 15 N obtained in the samples with optimum YBi2411, which is about two times higher than that of the sample without CeO2 doping. The results are very helpful for the fabrication of high quality single domain YBCO bulk superconductors.
文摘Bulk YBa2Cu3O7 samples were prepared by PMP method. Through adjusting ingredients and preparation procedures, a pellet with 3. 5 cm in diameter and 0. 9 cm in thickness was synthesized. A mass of 1. 3 kg on a magnet can be levitated at about 1 mm height at 77 K. The XRD and SEM indicated that magnetic lifting property can be enhanced by addition of Ag2O and Y2BaCuO5.
文摘顶部籽晶熔融织构生长法(TSMTG)是制备大尺寸单畴YBCO超导块材最有效的方法之一,然而,TSMTG法却存在着样品易收缩、变形等严重问题.为了解决这一问题,人们发明了顶部籽晶熔渗生长法(TSIG).但传统的TSIG法需要制备Y2Ba Cu O5(Y211),YBa2Cu3Oy(Y123),Ba Cu O2三种粉体,不仅过程复杂、费时费力、耗能污染,且最大的缺陷是无法控制样品中的Y211粒子含量.为了解决这些技术难题,发明了一种新TSIG法,用Y2O3+1.2Ba Cu O2混合粉替代传统的Y211固相源,用Y2O3,Ba Cu O2和Cu O混合粉替代传统的(Y123+3Ba Cu O2+2Cu O)液相源.采用这种新TSIG法,成功地制备出了直径为59和93 mm的单畴YBCO超导块材.通过对采用传统和新TSIG法制备单畴YBCO超导块材的生长速率、磁悬浮力和微观结构的研究发现:(1)采用新TSIG法后,YBCO超导块材的生长速率达到传统方法的1.7倍;(2)采用新TSIG法制备的单畴YBCO超导块材的磁悬浮力比传统方法制备的样品高出65%以上;(3)采用新TSIG法制备单畴YBCO超导块材,样品中的Y211粒子平均粒径约为1μm,明显小于传统TSIG方法所制备样品的3.4μm,而且分布更合理、均匀,有效地提高了样品的磁通钉扎能力.在此基础上,制备出了目前国内最大尺寸(直径93 mm)单畴YBCO超导块材.这些结果表明,新TSIG法对于促进低成本、大尺寸、高质量单畴REBCO超导块材的产业化及其应用进程具有非常重要的指导意义和实用价值.
