The effect of annealing temperature on the martensitic transformation of a Ti49.2Ni50.8 alloy processed by equal channel angular pressing （ECAP） was investigated by X-ray diffraction （XRD）, transmission electron m...The effect of annealing temperature on the martensitic transformation of a Ti49.2Ni50.8 alloy processed by equal channel angular pressing （ECAP） was investigated by X-ray diffraction （XRD）, transmission electron microscopy （TEM） and differential scanning calorimetry （DSC）. The as-ECAP processed and subsequently annealed Ti49.2Ni50.8 alloys consist of B2 parent phase, Ti4Ni2O phase and B19′ martensite at room temperature. Upon cooling, all samples show B2→R→B19′ two-stage transformation. Upon heating, when the annealing temperature is less than 400℃, the samples show B19′→R→B2 two-stage transformation; when the annealing temperature is higher than 500 ℃, the samples show B19′→B2 single-stage transformation. The B2-R transformation is characterized by wide interval due to the dislocations introduced during ECAP.展开更多
A Ni-rich TiNi alloy was processed by Equal Channel Angular Extrusion (ECAE) at 500℃. After four passes ECAE treatment, microstructure of the alloy was refined but slightly inhomogeneous, to sub-micron scale, approxi...A Ni-rich TiNi alloy was processed by Equal Channel Angular Extrusion (ECAE) at 500℃. After four passes ECAE treatment, microstructure of the alloy was refined but slightly inhomogeneous, to sub-micron scale, approximately 0.5～0.6 μm. Comparing with the solution-treated TiNi specimen, the martensitic transformations start (Ms) and peak temperatures (Mp) of TiNi specimens processed by ECAE were dramatically lowered. After ECAE treatment, the R-phase transformation was stimulated and separated from martensitic transformation, but occurred within a larger temperature range. Super-elasticity characteristics of TiNi alloy were tested by tensile loading and unloading cycles. The results revealed that at a tensile strain of 6% or smaller, TiNi alloy processed by four passes ECAE showed better super-elasticity, with less residual strain retained, than solution-treated sample. After tensile strain exceeded 6%, up to 8%, the maximum recoverable strain of TiNi alloy ECAE treated was decreased. Microstructure evolution and its effect on phase transformations and super-elasticity characteristics were discussed.展开更多
基金Project(51001035)supported by the National Natural Science Foundation of ChinaProject(LBH-Q14035)supported by the Postdoctoral Funds for Scientific Research Initiation of Heilongjiang Province,ChinaProject(HEUCF20151002)supported by the Fundamental Research Funds for the Central Universities,China
文摘The effect of annealing temperature on the martensitic transformation of a Ti49.2Ni50.8 alloy processed by equal channel angular pressing （ECAP） was investigated by X-ray diffraction （XRD）, transmission electron microscopy （TEM） and differential scanning calorimetry （DSC）. The as-ECAP processed and subsequently annealed Ti49.2Ni50.8 alloys consist of B2 parent phase, Ti4Ni2O phase and B19′ martensite at room temperature. Upon cooling, all samples show B2→R→B19′ two-stage transformation. Upon heating, when the annealing temperature is less than 400℃, the samples show B19′→R→B2 two-stage transformation; when the annealing temperature is higher than 500 ℃, the samples show B19′→B2 single-stage transformation. The B2-R transformation is characterized by wide interval due to the dislocations introduced during ECAP.
基金the National Science Fund of China (No.A50671067)
文摘A Ni-rich TiNi alloy was processed by Equal Channel Angular Extrusion (ECAE) at 500℃. After four passes ECAE treatment, microstructure of the alloy was refined but slightly inhomogeneous, to sub-micron scale, approximately 0.5～0.6 μm. Comparing with the solution-treated TiNi specimen, the martensitic transformations start (Ms) and peak temperatures (Mp) of TiNi specimens processed by ECAE were dramatically lowered. After ECAE treatment, the R-phase transformation was stimulated and separated from martensitic transformation, but occurred within a larger temperature range. Super-elasticity characteristics of TiNi alloy were tested by tensile loading and unloading cycles. The results revealed that at a tensile strain of 6% or smaller, TiNi alloy processed by four passes ECAE showed better super-elasticity, with less residual strain retained, than solution-treated sample. After tensile strain exceeded 6%, up to 8%, the maximum recoverable strain of TiNi alloy ECAE treated was decreased. Microstructure evolution and its effect on phase transformations and super-elasticity characteristics were discussed.
