In order to study the stress corrosion cracking (SCC) of X70 pipeline steel and its weld joint in acid soil environment of southeast of China, two simulating methods were used here. The one was to obtain the bad mic...In order to study the stress corrosion cracking (SCC) of X70 pipeline steel and its weld joint in acid soil environment of southeast of China, two simulating methods were used here. The one was to obtain the bad microstructures in heat affected zone by annealing at 1300℃ for 10 min and air cooling to room temperature, the other was to get a series of simulating solutions of the acid soil environment. SCC susceptibilities of X70 pipeline steels'before and after being normalized in the simulated solutions were studied by slow strain rate test (SSRT) and microstructural observation of fracture areas. Potentiodynamic polarization curves were used to study the electrochemical behaviour of different microstructures. SCC does occur to both the as-received material and normalized microstructure after heat treatment as the polarization potential decreased. Hydrogen embrittlement (HE) is indicated occurring to all tested materials at -850 mV (vs SCE) and -1200 mV(vs SCE). The SCC mechanisms are different within varying potential range. Anodic dissolution is the key cause as polarization potential higher than null current potential, and HE will play a more important role as polarization potential lower than the null current potential.展开更多
采用电化学阻抗和慢应变速率方法,结合扫描电子显微镜,研究了不同阴极极化电位下X80钢在鹰潭土壤模拟溶液中的应力腐蚀行为。结果表明:鹰潭土壤模拟溶液中,X80钢/溶液界面处电荷转移电阻随阴极极化程度增加先升后降。在自腐蚀电位条件...采用电化学阻抗和慢应变速率方法,结合扫描电子显微镜,研究了不同阴极极化电位下X80钢在鹰潭土壤模拟溶液中的应力腐蚀行为。结果表明:鹰潭土壤模拟溶液中,X80钢/溶液界面处电荷转移电阻随阴极极化程度增加先升后降。在自腐蚀电位条件下开裂机理为阳极溶解,当外加电位为-1000 m V(vs SCE),应力腐蚀敏感性最低,此电位为最佳保护电位;继续增大阴极极化程度,应力腐蚀敏感性增加,此时开裂机制为氢和应力协同作用下的氢致开裂。展开更多
基金supported by the Chinese National Sci-ence and Technology Infrastructure Platforms Construc-tion Project (No. 2005DKA 10400)the Major Foun-dation in the Tenth Five-Year Development Plan of China(No. 50499333-08).
文摘In order to study the stress corrosion cracking (SCC) of X70 pipeline steel and its weld joint in acid soil environment of southeast of China, two simulating methods were used here. The one was to obtain the bad microstructures in heat affected zone by annealing at 1300℃ for 10 min and air cooling to room temperature, the other was to get a series of simulating solutions of the acid soil environment. SCC susceptibilities of X70 pipeline steels'before and after being normalized in the simulated solutions were studied by slow strain rate test (SSRT) and microstructural observation of fracture areas. Potentiodynamic polarization curves were used to study the electrochemical behaviour of different microstructures. SCC does occur to both the as-received material and normalized microstructure after heat treatment as the polarization potential decreased. Hydrogen embrittlement (HE) is indicated occurring to all tested materials at -850 mV (vs SCE) and -1200 mV(vs SCE). The SCC mechanisms are different within varying potential range. Anodic dissolution is the key cause as polarization potential higher than null current potential, and HE will play a more important role as polarization potential lower than the null current potential.
文摘采用电化学阻抗和慢应变速率方法,结合扫描电子显微镜,研究了不同阴极极化电位下X80钢在鹰潭土壤模拟溶液中的应力腐蚀行为。结果表明:鹰潭土壤模拟溶液中,X80钢/溶液界面处电荷转移电阻随阴极极化程度增加先升后降。在自腐蚀电位条件下开裂机理为阳极溶解,当外加电位为-1000 m V(vs SCE),应力腐蚀敏感性最低,此电位为最佳保护电位;继续增大阴极极化程度,应力腐蚀敏感性增加,此时开裂机制为氢和应力协同作用下的氢致开裂。