Hickman's fast nonadiabatic collision model for the ion-pair formation reaction A+BC→A^++BC^- was improved,where the classical trajectory has been represented by solution of motion equation UR=-dV(R)/dR, here V(R...Hickman's fast nonadiabatic collision model for the ion-pair formation reaction A+BC→A^++BC^- was improved,where the classical trajectory has been represented by solution of motion equation UR=-dV(R)/dR, here V(R)is Morse potential.Employing this model to the CS+O_2→CS^++O_2^-reaction,a satisfactory agreement with experimental data has been obtained.展开更多
A modified version of the NCAR/RegCM2 has been developed at the National Climate Center （NCC）, China Meteorological Administration, through a series of sensitivity experiments and multi-year simulations and hindcast...A modified version of the NCAR/RegCM2 has been developed at the National Climate Center （NCC）, China Meteorological Administration, through a series of sensitivity experiments and multi-year simulations and hindcasts, with a special emphasis on the adequate choice of physical parameterization schemes suitable for the East Asian monsoon climate. This regional climate model is nested with the NCC/IAP （Institute of Atmospheric Physics） T63 coupled GCM to make an experimental seasonal prediction for China and East Asia. The four-year （2001 to 2004） prediction results are encouraging. This paper is the first part of a two-part paper, and it mainly describes the sensitivity study of the physical process paraxneterization represented in the model. The systematic errors produced by the different physical parameterization schemes such as the land surface processes, convective precipitation, cloud-radiation transfer process, boundary layer process and large-scale terrain features have been identified based on multi-year and extreme flooding event simulations. A number of comparative experiments has shown that the mass flux scheme （MFS） and Betts-Miller scheme （BM） for convective precipitation, the LPMI （land surface process model I） and LPMII （land surface process model Ⅱ） for the land surface process, the CCM3 radiation transfer scheme for cloud-radiation transfer processes, the TKE （turbulent kinetic energy） scheme for the boundary layer processes and the topography treatment schemes for the Tibetan Plateau are suitable for simulations and prediction of the East Asia monsoon climate in rainy seasons. Based on the above sensitivity study, a modified version of the RegCM2 （RegCM_NCC） has been set up for climate simulations and seasonal predictions.展开更多
The conventional and intensive observational data of the China Heavy Rain Experiment and Study (CHeRES) are used to specially analyze the heavy rainfall process in the mei-yu front that occurred during 20-21 June 2002...The conventional and intensive observational data of the China Heavy Rain Experiment and Study (CHeRES) are used to specially analyze the heavy rainfall process in the mei-yu front that occurred during 20-21 June 2002, focusing on the meso-β system. A mesoscale convective system (MCS) formed in the warm-moist southwesterly to the south of the shear line over the Dabie Mountains and over the gorge between the Dabie and Jiuhua Mountains. The mei-yu front and shear line provide a favorable synoptic condition for the development of convection. The GPS observation indicates that the precipitable water increased obviously about 2-3 h earlier than the occurrence of rainfall and decreased after that. The abundant moisture transportation by southwesterly wind was favorable to the maintenance of convective instability and the accumulation of convective available potential energy (CAPE). Radar detection reveals that meso-β and -γ systems were very active in the MaCS. Several convection lines developed during the evolution of the MaCS, and these are associated with surface convergence lines. The boundary outflow of the convection line may have triggered another convection line. The convection line moved with the mesoscale surface convergence line, but the convective cells embedded in the convergence line propagated along the line. On the basis of the analyses of the intensive observation data, a multi-scale conceptual model of heavy rainfall in the mei-yu front for this particular case is proposed.展开更多
The numerical forecasts of mei-yu front rainstorms in China has been an important issue. The intensity and pattern of the frontal rainfall are greatly influenced by the initial fields of the numerical model. The 4-dim...The numerical forecasts of mei-yu front rainstorms in China has been an important issue. The intensity and pattern of the frontal rainfall are greatly influenced by the initial fields of the numerical model. The 4-dimensional variational data assimilation technology (4DVAR) can effectively assimilate all kinds of observed data, including rainfall data at the observed stations, so that the initial fields and the precipitation forecast can both be greatly improved. The non-hydrostatic meso-scale model (MM5) and its adjoint model are used to study the development of the mei-yu front rainstorm from 1200 UTC 25 June to 0600 UTC 26 June 1999. By numerical simulation experiments and assimilation experiments, the T106 data and the observed 6-hour rainfall data are assimilated. The influences of many factors, such as the choice of the assimilated variables and the weighting coefficient, on the precipitation forecast results are studied. The numerical results show that 4DVAR is valuable and important to mei-yu front rainfall prediction.展开更多
The experimental solubility of CBZ (Carbobenzoxy) derivatized amino acids namely N-CBZ valine, N-CBZ proline, N-CBZ aspartic acid in supercritical carbon dioxide were correlated by Soave-Red- lich-Kwong Equation state...The experimental solubility of CBZ (Carbobenzoxy) derivatized amino acids namely N-CBZ valine, N-CBZ proline, N-CBZ aspartic acid in supercritical carbon dioxide were correlated by Soave-Red- lich-Kwong Equation state based on fugacity determination and group contribution method using extrapolated critical parameters and mixing rules and other two different empirical models proposed by Yu (1994) and Gordillo-coworkers (1999). The SRK EOS prediction showed very high deviation of % AARD of 9% - 59%. The Yu model had three derivatized amino acids with average absolute deviation from 2.04, 8.17, 10.96, while the Gordillo model had 0.245, 1.067 and 1.144 for CBZ-valine, CBZ-proline and CBZ-aspartic acid successively. The correlated values had better fit with Gordillo model. The predictive capability and applicability for these amino acid derivatives for both the models demonstrated with correlation coefficient around 0.99 for all the experimental solubility observed.展开更多
文摘Hickman's fast nonadiabatic collision model for the ion-pair formation reaction A+BC→A^++BC^- was improved,where the classical trajectory has been represented by solution of motion equation UR=-dV(R)/dR, here V(R)is Morse potential.Employing this model to the CS+O_2→CS^++O_2^-reaction,a satisfactory agreement with experimental data has been obtained.
文摘A modified version of the NCAR/RegCM2 has been developed at the National Climate Center （NCC）, China Meteorological Administration, through a series of sensitivity experiments and multi-year simulations and hindcasts, with a special emphasis on the adequate choice of physical parameterization schemes suitable for the East Asian monsoon climate. This regional climate model is nested with the NCC/IAP （Institute of Atmospheric Physics） T63 coupled GCM to make an experimental seasonal prediction for China and East Asia. The four-year （2001 to 2004） prediction results are encouraging. This paper is the first part of a two-part paper, and it mainly describes the sensitivity study of the physical process paraxneterization represented in the model. The systematic errors produced by the different physical parameterization schemes such as the land surface processes, convective precipitation, cloud-radiation transfer process, boundary layer process and large-scale terrain features have been identified based on multi-year and extreme flooding event simulations. A number of comparative experiments has shown that the mass flux scheme （MFS） and Betts-Miller scheme （BM） for convective precipitation, the LPMI （land surface process model I） and LPMII （land surface process model Ⅱ） for the land surface process, the CCM3 radiation transfer scheme for cloud-radiation transfer processes, the TKE （turbulent kinetic energy） scheme for the boundary layer processes and the topography treatment schemes for the Tibetan Plateau are suitable for simulations and prediction of the East Asia monsoon climate in rainy seasons. Based on the above sensitivity study, a modified version of the RegCM2 （RegCM_NCC） has been set up for climate simulations and seasonal predictions.
基金This project was supported by the National Key Basic Research and Development Project 2004CB418301the National Natural Science Foundation of China under Grant No.40405008.
文摘The conventional and intensive observational data of the China Heavy Rain Experiment and Study (CHeRES) are used to specially analyze the heavy rainfall process in the mei-yu front that occurred during 20-21 June 2002, focusing on the meso-β system. A mesoscale convective system (MCS) formed in the warm-moist southwesterly to the south of the shear line over the Dabie Mountains and over the gorge between the Dabie and Jiuhua Mountains. The mei-yu front and shear line provide a favorable synoptic condition for the development of convection. The GPS observation indicates that the precipitable water increased obviously about 2-3 h earlier than the occurrence of rainfall and decreased after that. The abundant moisture transportation by southwesterly wind was favorable to the maintenance of convective instability and the accumulation of convective available potential energy (CAPE). Radar detection reveals that meso-β and -γ systems were very active in the MaCS. Several convection lines developed during the evolution of the MaCS, and these are associated with surface convergence lines. The boundary outflow of the convection line may have triggered another convection line. The convection line moved with the mesoscale surface convergence line, but the convective cells embedded in the convergence line propagated along the line. On the basis of the analyses of the intensive observation data, a multi-scale conceptual model of heavy rainfall in the mei-yu front for this particular case is proposed.
基金This work was supported by the National Natural Science Foundation of China under Grant Nos.40105012,49928504,and 40221503“973”Project under Grant No.G1999032801the Key Innovation Direction Project of the Chinese Academy of Sciences under Grant No.KZCX2208.The authors warmly thank Wu Rongsheng and Wang Yuan of N anjing University for their valuable advice.
文摘The numerical forecasts of mei-yu front rainstorms in China has been an important issue. The intensity and pattern of the frontal rainfall are greatly influenced by the initial fields of the numerical model. The 4-dimensional variational data assimilation technology (4DVAR) can effectively assimilate all kinds of observed data, including rainfall data at the observed stations, so that the initial fields and the precipitation forecast can both be greatly improved. The non-hydrostatic meso-scale model (MM5) and its adjoint model are used to study the development of the mei-yu front rainstorm from 1200 UTC 25 June to 0600 UTC 26 June 1999. By numerical simulation experiments and assimilation experiments, the T106 data and the observed 6-hour rainfall data are assimilated. The influences of many factors, such as the choice of the assimilated variables and the weighting coefficient, on the precipitation forecast results are studied. The numerical results show that 4DVAR is valuable and important to mei-yu front rainfall prediction.
文摘The experimental solubility of CBZ (Carbobenzoxy) derivatized amino acids namely N-CBZ valine, N-CBZ proline, N-CBZ aspartic acid in supercritical carbon dioxide were correlated by Soave-Red- lich-Kwong Equation state based on fugacity determination and group contribution method using extrapolated critical parameters and mixing rules and other two different empirical models proposed by Yu (1994) and Gordillo-coworkers (1999). The SRK EOS prediction showed very high deviation of % AARD of 9% - 59%. The Yu model had three derivatized amino acids with average absolute deviation from 2.04, 8.17, 10.96, while the Gordillo model had 0.245, 1.067 and 1.144 for CBZ-valine, CBZ-proline and CBZ-aspartic acid successively. The correlated values had better fit with Gordillo model. The predictive capability and applicability for these amino acid derivatives for both the models demonstrated with correlation coefficient around 0.99 for all the experimental solubility observed.
