The surface plasmonic resonance(SPR)effect of Bi can effectively improve the light absorption abilities and photogenerated charge carrier separation rate.In this study,a novel ternary heterojunction of g-C3N4/Bi2MoO6/...The surface plasmonic resonance(SPR)effect of Bi can effectively improve the light absorption abilities and photogenerated charge carrier separation rate.In this study,a novel ternary heterojunction of g-C3N4/Bi2MoO6/Bi(CN/BMO/Bi)hollow microsphere was successfully fabricated through solvothermal and in situ reduction methods.The results revealed that the optimal ternary 0.4 CN/BMO/9 Bi photocatalyst exhibited the highest photocatalytic efficiency toward rhodamine B(RhB)degradation with nine times that of pure BMO.The DRS and valence band of the X-ray photoelectron spectroscopy spectrum demonstrate that the band structure of 0.4 CN/BMO/9 Bi is a z-scheme structure.Quenching experiments also provided solid evidence that the·O^2-(at-0.33 eV)is the main species during dye degradation,and the conduction band of g-C3N4 is only the reaction site,demonstrating that the transfer of photogenerated charge carriers of g-C3N4/Bi2 MoO 6/Bi is through an indirect z-scheme structure.Thus,the enhanced photocatalytic performance was mainly ascribed to the synergetic effect of heterojunction structures between g-C3N4 and Bi2MoO6 and the SPR effect of Bi doping,resulting in better optical absorption ability and a lower combination rate of photogenerated charge carriers.The findings in this work provide insight into the synergism of heterostructures and the SPR absorption ability in wastewater treatment.展开更多
To discuss the relationship between stability and bullwhip effect in the supply chain system,a basic model in a production-inventory control system is developed using difference equations.Z-transform techniques are ap...To discuss the relationship between stability and bullwhip effect in the supply chain system,a basic model in a production-inventory control system is developed using difference equations.Z-transform techniques are applied to investigate the production ordering and inventory dynamics.For the two operational regimes of sufficient inventory coverage and insufficient inventory coverage,the scope of decision parameters which make the system stable or instable is investigated.Under two operational regimes and the actual system,production release rates,stability/instability and bullwhip effect in the stable region and instable region are examined based on different demand functions,and then the numerical simulation results are given.The results show that reasonable choices of fractional adjustment of inventory and supply line can make the system stable and decrease bullwhip effect.It is summarized that the piecewise linearization based on the stability analysis approach is a valid approximation to the analysis of production-inventory ordering systems with nonlinearities.Some interesting results are obtained and they have important implications for improving inventory and order decisions in supply chain systems.展开更多
基金financially supported by the Science Foundation of China University of Petroleum,Beijing(2462017YJRC048,2462018BJC005)the National Natural Science Foundation of China(51802351)~~
文摘The surface plasmonic resonance(SPR)effect of Bi can effectively improve the light absorption abilities and photogenerated charge carrier separation rate.In this study,a novel ternary heterojunction of g-C3N4/Bi2MoO6/Bi(CN/BMO/Bi)hollow microsphere was successfully fabricated through solvothermal and in situ reduction methods.The results revealed that the optimal ternary 0.4 CN/BMO/9 Bi photocatalyst exhibited the highest photocatalytic efficiency toward rhodamine B(RhB)degradation with nine times that of pure BMO.The DRS and valence band of the X-ray photoelectron spectroscopy spectrum demonstrate that the band structure of 0.4 CN/BMO/9 Bi is a z-scheme structure.Quenching experiments also provided solid evidence that the·O^2-(at-0.33 eV)is the main species during dye degradation,and the conduction band of g-C3N4 is only the reaction site,demonstrating that the transfer of photogenerated charge carriers of g-C3N4/Bi2 MoO 6/Bi is through an indirect z-scheme structure.Thus,the enhanced photocatalytic performance was mainly ascribed to the synergetic effect of heterojunction structures between g-C3N4 and Bi2MoO6 and the SPR effect of Bi doping,resulting in better optical absorption ability and a lower combination rate of photogenerated charge carriers.The findings in this work provide insight into the synergism of heterostructures and the SPR absorption ability in wastewater treatment.
文摘To discuss the relationship between stability and bullwhip effect in the supply chain system,a basic model in a production-inventory control system is developed using difference equations.Z-transform techniques are applied to investigate the production ordering and inventory dynamics.For the two operational regimes of sufficient inventory coverage and insufficient inventory coverage,the scope of decision parameters which make the system stable or instable is investigated.Under two operational regimes and the actual system,production release rates,stability/instability and bullwhip effect in the stable region and instable region are examined based on different demand functions,and then the numerical simulation results are given.The results show that reasonable choices of fractional adjustment of inventory and supply line can make the system stable and decrease bullwhip effect.It is summarized that the piecewise linearization based on the stability analysis approach is a valid approximation to the analysis of production-inventory ordering systems with nonlinearities.Some interesting results are obtained and they have important implications for improving inventory and order decisions in supply chain systems.
