Effect of CaO doping on corrosion resistance of Cu/(NiFe_2O_4-10NiO) cermet inert anode for aluminum electrolysis

The CaO-doped Cu/（NiFe2O4-10NiO） cermet inert anodes were prepared by the cold isostatie pressing-sintering process, and their corrosion resistance to Na3AlF6-K3AlF6-Al203 melt was studied. The results show that the relative density of 5Cu/（NiFe2O4-10NiO） cermet sintered at 1 200 ℃ increases from 82.83% to 97.63% when 2% CaO （mass fraction） is added. During the electrolysis, the relative density of cermet inert anode descends owing to the chemical dissolution of additive CaO at ceramic grain boundary, which accelerates the penetration of electrolyte. Thus, the corrosion resistance to melts of Cu/（NiFe2O4-10NiO） cermet inert anode is reduced. To improve the corrosion resistance of the cermet inert anode, the content of CaO doped should be decreased and the technology of cleaning the ceramic grain boundary should be applied.

深冷处理对ZQAl10-4-4铝青铜压缩性能的影响

利用光学显微镜、扫描电镜及电子万能试验机对深冷处理前后ZQAl10-4-4铝青铜的微观组织、压缩断口形貌及抗压强度进行了观察与测试,探讨了深冷处理对ZQAl10-4-4铝青铜压缩性能的影响。结果表明,深冷处理能降低铸态铝青铜的抗压强度,深冷处理后再经600℃×5 min回火,铝青铜的抗压强度得到明显提高,铝青铜的显微组织与抗压强度有良好的对应关系。