Comparative investigations of gas sensing characteristics of Fe2O3 in both thin film as well as bulk forms have been performed. Thin film sensors were realized by first depositing Fe films using electron-beam evaporat...Comparative investigations of gas sensing characteristics of Fe2O3 in both thin film as well as bulk forms have been performed. Thin film sensors were realized by first depositing Fe films using electron-beam evaporation followed by thermal oxidation. Bulk sensors in the form of pellets were prepared by cold pressing commercial Fe2O3 powder with subsequent sintering. Both thin film and bulk Fe2O3 sensors exhibited a selective and reversible response characteristics towards H2S with maximum response at an operating temperature of 250°C and 200°C, respectively. A negligible response towards other interfering gases was observed. Thin film sensors exhibited an enhanced response in comparison to that of pellets.展开更多
There is a great demand for high-performance hydrogen sulfide(H_(2)S)sensors with low operating temperatures.Ag/In_(2)O_(3)hexagonal tubes with different proportions were prepared by the calcination of Ag+-impregnated...There is a great demand for high-performance hydrogen sulfide(H_(2)S)sensors with low operating temperatures.Ag/In_(2)O_(3)hexagonal tubes with different proportions were prepared by the calcination of Ag+-impregnated indium-organic frameworks(CPP-3(In)),and the developed sensors exhibit enhanced gas-sensing performance toward H_(2)S.Gas sensing measurements indicate that the response of Ag/In_(2)O_(3)(2.5 wt%)sensor to 5 ppm H_(2)S has the highest response(119),operated at 70℃.The Ag/In_(2)O_(3)(2.5 wt%)based sensor exhibits short response time(20 s),low detection limit(300 ppb),and good selectivity toward H_(2)S gas,which imply that the CPP-3(In)-derived Ag/In_(2)O_(3)hexagonal tube is a promising candidate to be constructed a low power-consumption H_(2)S sensor.展开更多
文摘Comparative investigations of gas sensing characteristics of Fe2O3 in both thin film as well as bulk forms have been performed. Thin film sensors were realized by first depositing Fe films using electron-beam evaporation followed by thermal oxidation. Bulk sensors in the form of pellets were prepared by cold pressing commercial Fe2O3 powder with subsequent sintering. Both thin film and bulk Fe2O3 sensors exhibited a selective and reversible response characteristics towards H2S with maximum response at an operating temperature of 250°C and 200°C, respectively. A negligible response towards other interfering gases was observed. Thin film sensors exhibited an enhanced response in comparison to that of pellets.
基金supported by the National Natural Science Foundation of China(No.61471233)Shanghai Sailing Program(No.21YF1431400)。
文摘There is a great demand for high-performance hydrogen sulfide(H_(2)S)sensors with low operating temperatures.Ag/In_(2)O_(3)hexagonal tubes with different proportions were prepared by the calcination of Ag+-impregnated indium-organic frameworks(CPP-3(In)),and the developed sensors exhibit enhanced gas-sensing performance toward H_(2)S.Gas sensing measurements indicate that the response of Ag/In_(2)O_(3)(2.5 wt%)sensor to 5 ppm H_(2)S has the highest response(119),operated at 70℃.The Ag/In_(2)O_(3)(2.5 wt%)based sensor exhibits short response time(20 s),low detection limit(300 ppb),and good selectivity toward H_(2)S gas,which imply that the CPP-3(In)-derived Ag/In_(2)O_(3)hexagonal tube is a promising candidate to be constructed a low power-consumption H_(2)S sensor.
