A new route to prepare zeolitic material was introduced in this work. Compared with traditional methods, the new route showed lower energy consume. The effect of pre-treatment conditions on structure and crystalline p...A new route to prepare zeolitic material was introduced in this work. Compared with traditional methods, the new route showed lower energy consume. The effect of pre-treatment conditions on structure and crystalline phase was investigated, revealing that the mullite crystalline phase in fly ash could be converted to amorphous phase by alkali at low temperature. The removal performance of heavy metal ions on designed material was also investigated, and we found that the intermediate product showed higher adsorption capacity on Ni^(2+) than zeolite A.展开更多
This paper aimed to improve the water-retention performance and basic physical properties of sulfoaluminate cement（SAC）-based planting cementitious material. The effect of natural zeolite on the performance of SAC-b...This paper aimed to improve the water-retention performance and basic physical properties of sulfoaluminate cement（SAC）-based planting cementitious material. The effect of natural zeolite on the performance of SAC-based planting material was investigated. The water-retention performance, porosity, compressive strength, and alkalinity had been tested and TG-DSC analysis had been adopted in this paper. Experimental results showed that zeolite was effective to improve the water-retention capacity and 10%, 20% and 30% natural zeolite increased the pore volume of the hardened pastes by 10.6%, 26.0%, and 38.6%, especially pore size below 0.1 μm was increased by 9.7%, 26.2% and 17.5%. And 10% zeolite was beneficial to the compressive strengths of cementitious material and 1, 3, and 28 d compressive strength reached up to 35.9, 55.0, 80.3 MPa. Furthermore zeolite decreased the alkalinity of pore fluid of hardened cementitious material, while the addition of zeolite reached up to 30%, the alkalinity of pore fluid of hardened cementitious material decreased by 8.9%. Therefore zeolite was suitable for improving the performance of SAC-based planting cementitious material.展开更多
Trimodal hierarchical yolk-shell materials consisting of TS-1 core and mesoporous carbon shell （YS-TS- I@MC） was successfully synthesized by using TS-l@mesosilica as hard template, sucrose as carbon source and organ...Trimodal hierarchical yolk-shell materials consisting of TS-1 core and mesoporous carbon shell （YS-TS- I@MC） was successfully synthesized by using TS-l@mesosilica as hard template, sucrose as carbon source and organic base tetrapropylammonium hydroxide （TPAOH） as silica etching agent. The resultant YS-TS-I@MC contains the micropores （0.51 nm） in TS-1 core, the mesopores （2.9 rim） in carbon shell as well as a void or a stack pore between TS-1 fragements （TS-1 intercrystal mesopores, -18.4 nm）. Under the rigorous etching conditions, the crystalline structure of TS-1 core was well retained. The YS-TS- I@MC served as a good support for palladium nano-particles （Pd NPs） or Rh（OH）x species, giving rise to efficient bifunctional catalysts for the tandem reactions including one-pot synthesis of propylene oxide or amides.展开更多
基金supported by the 2016 Key Program of China Guodian Corporation,and the grant number is2015G1PU00200
文摘A new route to prepare zeolitic material was introduced in this work. Compared with traditional methods, the new route showed lower energy consume. The effect of pre-treatment conditions on structure and crystalline phase was investigated, revealing that the mullite crystalline phase in fly ash could be converted to amorphous phase by alkali at low temperature. The removal performance of heavy metal ions on designed material was also investigated, and we found that the intermediate product showed higher adsorption capacity on Ni^(2+) than zeolite A.
基金Funded by the National Natural Science Foundation of China(Nos.51302104,51472109)Science and Technology Development Plan of Shandong Province(No.2014G-ZX208001)the Program for Scientific Research Innovation Team in Colleges and Universities of Shandong Province
文摘This paper aimed to improve the water-retention performance and basic physical properties of sulfoaluminate cement（SAC）-based planting cementitious material. The effect of natural zeolite on the performance of SAC-based planting material was investigated. The water-retention performance, porosity, compressive strength, and alkalinity had been tested and TG-DSC analysis had been adopted in this paper. Experimental results showed that zeolite was effective to improve the water-retention capacity and 10%, 20% and 30% natural zeolite increased the pore volume of the hardened pastes by 10.6%, 26.0%, and 38.6%, especially pore size below 0.1 μm was increased by 9.7%, 26.2% and 17.5%. And 10% zeolite was beneficial to the compressive strengths of cementitious material and 1, 3, and 28 d compressive strength reached up to 35.9, 55.0, 80.3 MPa. Furthermore zeolite decreased the alkalinity of pore fluid of hardened cementitious material, while the addition of zeolite reached up to 30%, the alkalinity of pore fluid of hardened cementitious material decreased by 8.9%. Therefore zeolite was suitable for improving the performance of SAC-based planting cementitious material.
基金the National Natural Science Foundation of China(No.21273076,U1162102)the National Key Technology R&D Program(No.2012BAE05B02)+1 种基金Ph.D Programs Foundation of Ministry of Education(No.2012007613000)the Shanghai Leading Academic Discipline Project(B409)
文摘Trimodal hierarchical yolk-shell materials consisting of TS-1 core and mesoporous carbon shell （YS-TS- I@MC） was successfully synthesized by using TS-l@mesosilica as hard template, sucrose as carbon source and organic base tetrapropylammonium hydroxide （TPAOH） as silica etching agent. The resultant YS-TS-I@MC contains the micropores （0.51 nm） in TS-1 core, the mesopores （2.9 rim） in carbon shell as well as a void or a stack pore between TS-1 fragements （TS-1 intercrystal mesopores, -18.4 nm）. Under the rigorous etching conditions, the crystalline structure of TS-1 core was well retained. The YS-TS- I@MC served as a good support for palladium nano-particles （Pd NPs） or Rh（OH）x species, giving rise to efficient bifunctional catalysts for the tandem reactions including one-pot synthesis of propylene oxide or amides.
