The previous work found that the additive kaolin could scavenge not only sodium(Na)but also calcium(Ca)and magnesium(Mg),which is the important ash fluxing agents in low rank coal combustion.Such scavenging effects of...The previous work found that the additive kaolin could scavenge not only sodium(Na)but also calcium(Ca)and magnesium(Mg),which is the important ash fluxing agents in low rank coal combustion.Such scavenging effects of kaolin on fine ash formation were studied in the present work.A typical Zhundong coal and its blends with kaolin at dosages of 1,2 and 4 wt%were combusted in an electrically heated drop tube furnace(DTF)at 1300℃.The fine ashes generated were collected and size segregated by a low pressure impactor(LPI).The morphology and chemical composition of fine ash were analyzed by scanning electron microscopy equipped with an energydispersive spectrometer(SEM-EDS).In addition,char/ash particles were sampled at various positions of DTF to elucidate how kaolin additive affected the fine ash formation process.The results further showed that apart from the scavenging of volatile Na,kaolin additive could also strongly scavenge the refractory Ca,Mg and Fe in the fine ash during Zhundong coal combustion,which transformed the sintered particles with irregular shape into melted spherical particles,and finally resulted in the considerable decrease of these elements in both PM_(0.4)and PM_(0.4-10)by melting and agglomeration.The close contacts between kaolin particles and coal resulted from physically mixing were a key factor responsible for the reaction of kaolin with the refractory Ca,Mg and Fe.展开更多
The steam gasification kinetics of Zhundong raw coal and the washed coal by deionized water or hydrochloric acid with/without addition of CaO were tested by thermogravimetric analyzer(TGA)at medium temperatures(650℃ ...The steam gasification kinetics of Zhundong raw coal and the washed coal by deionized water or hydrochloric acid with/without addition of CaO were tested by thermogravimetric analyzer(TGA)at medium temperatures(650℃ to 800℃).The cation contents of potassium and sodium in samples were determined by Inductively Coupled Plasma Optical Emission Spectrometer(ICP-OES).The Brunauer-Emmett-Teller(BET)surface area of the samples was tested by N2 adsorption,and the morphologies of the samples were characterized by scanning electron microscopy(SEM).Experimental results showed that the organic sodium was the main catalyst for the gasification of the pyrolysis char,and the gasification rate of the char could be enhanced further with the introduction of CaO.The inherent alkali metals in coal and the introduced CaO showed a synergistic effect that occurred obviously above 735℃.The char conversion curves with or without CaO were fitted by the modified volumetric model(MVM).The calculated results indicated that the addition of CaO increased the pre-exponential factor obviously,but made little changes on the activation energy.It was proposed that the synergistic effect was resulted from the co-melting of the sodium and CaO,which facilitated the migration of the catalyst ions and the generation of C(O)intermediates for the gasification.展开更多
基金the National Key Research and Development Program of China(No.2016YFB0600601)National Natural Science Foundation of China(Nos.51676075 and 51520105008).
文摘The previous work found that the additive kaolin could scavenge not only sodium(Na)but also calcium(Ca)and magnesium(Mg),which is the important ash fluxing agents in low rank coal combustion.Such scavenging effects of kaolin on fine ash formation were studied in the present work.A typical Zhundong coal and its blends with kaolin at dosages of 1,2 and 4 wt%were combusted in an electrically heated drop tube furnace(DTF)at 1300℃.The fine ashes generated were collected and size segregated by a low pressure impactor(LPI).The morphology and chemical composition of fine ash were analyzed by scanning electron microscopy equipped with an energydispersive spectrometer(SEM-EDS).In addition,char/ash particles were sampled at various positions of DTF to elucidate how kaolin additive affected the fine ash formation process.The results further showed that apart from the scavenging of volatile Na,kaolin additive could also strongly scavenge the refractory Ca,Mg and Fe in the fine ash during Zhundong coal combustion,which transformed the sintered particles with irregular shape into melted spherical particles,and finally resulted in the considerable decrease of these elements in both PM_(0.4)and PM_(0.4-10)by melting and agglomeration.The close contacts between kaolin particles and coal resulted from physically mixing were a key factor responsible for the reaction of kaolin with the refractory Ca,Mg and Fe.
基金financially supported by the research project“Advancing and Demonstration of the Technology of CO2 Capture,Storage and Usage”(2016YFE0102500)National Natural Science Foundation of China(51606194)。
文摘The steam gasification kinetics of Zhundong raw coal and the washed coal by deionized water or hydrochloric acid with/without addition of CaO were tested by thermogravimetric analyzer(TGA)at medium temperatures(650℃ to 800℃).The cation contents of potassium and sodium in samples were determined by Inductively Coupled Plasma Optical Emission Spectrometer(ICP-OES).The Brunauer-Emmett-Teller(BET)surface area of the samples was tested by N2 adsorption,and the morphologies of the samples were characterized by scanning electron microscopy(SEM).Experimental results showed that the organic sodium was the main catalyst for the gasification of the pyrolysis char,and the gasification rate of the char could be enhanced further with the introduction of CaO.The inherent alkali metals in coal and the introduced CaO showed a synergistic effect that occurred obviously above 735℃.The char conversion curves with or without CaO were fitted by the modified volumetric model(MVM).The calculated results indicated that the addition of CaO increased the pre-exponential factor obviously,but made little changes on the activation energy.It was proposed that the synergistic effect was resulted from the co-melting of the sodium and CaO,which facilitated the migration of the catalyst ions and the generation of C(O)intermediates for the gasification.
