Polymetamorphism of the ultrahigh-temperature granulites in the Rauer Group,East Antarctica:new evidence from zircon SHRIMP U-Pb ages

The Rauer Group is located on the eastern margin of the early Paleozoic Prydz Belt in East Antarctica,and the typical ultrahigh-temperature(UHT,>900℃)granulites outcrop on Mather Peninsula.However,the timing of UHT metamorphism and P–T path of the UHT granulites have long been debated,which is critical to understanding the tectonic nature and evolution history of the Prydz Belt.Thus,both a sapphirine-bearing UHT metapelitic granulite and a garnet-bearing UHT mafic granulite are selected for zircon SHRIMP U-Pb age dating.The results show that metamorphic zircon mantles yield weighted mean^(206)Pb/^(238)U ages of 918±29 Ma and 901±29 Ma for the metapelitic and mafic granulites,respectively,while zircon rims and newly grown zircons yield weighted mean^(206)Pb/^(238)U ages of 523±9 Ma and 532±11 Ma,respectively.These new zircon age data suggest that the UHT granulites may have experienced polymetamorphism,in which pre-peak prograde stage occurred in the early Neoproterozoic Grenvillian orogenesis(1000–900 Ma),whereas the UHT metamorphism occurred in the late Neoproterozoic to early Paleozoic Pan-African orogenesis(580–460 Ma).This implies that P–T path of the UHT granulites should consist of two separate high-grade metamorphic events including the Grenvillian and Pan-African events,which are supposed to be related to assembly of Rodinia and Gondwana supercontinents respectively,and hence the overprinting UHT metamorphic event may actually reflect an important intracontinental reworking.

Discovery of the Dagele Eclogite in East Kunlun,Western China and Its Zircon SHRIMP U-Pb Ages:New Constrains on the Central Kunlun Suture Zone

Objective Eclogites are important indicators of ancient plate boundaries or paleosuture zones. Despite their great geological significance, very few investigations have been carried out in the Kunlun region. The Central East Kunlun fault zone was believed to be an Early Paleozoic suture zone, but there has been no reliable evidence for this, though studies on ophiolite, granite, and basic granulite indicate that the Early Paleozoic orogeny occurred in the East Kunlun. This work focused on the Dagele eclogites in Central East Kunlun to provide new constraints for the Central East Kunlun suture zone.

New Zircon SHRIMP U-Pb Ages of the Langjiu Formation Volcanic Rocks in the Shiquanhe Area,Western Lhasa Terrane and their Implications

Objective The potassic and ultrapotassic rocks relating to the India-Eurasia collision and continual plate convergence are widely distributed in the Lhasa terrane. These rocks are very important to understand the deep processes of the India-Eurasia collision and the uplift and evolution of the Tibetan Plateau. Although high-potassic volcanic rocks are also exposed in the western Lhasa terrane, their formation time is still uncertain for the lack of reliable dating. We carried out zircon U-Pb geochronological study on the Langjiu Formation volcanic rocks, which are part of the Early Cretaceous Zenong group volcanic rocks based on 1：250000 scale Shiquanhe regional geological survey report, in the Shiquanhe area of the western Lhasa terrane. These new age data not only offer chronological basis for the regional stratigraphic correlation and classification, but also provide an essential opportunity for revealing signatures of magmatic pulses hidden in the deep crust of the Lhasa terrane.

Zircon SHRIMP U-Pb Ages,Geochemistry and Nd-Hf Isotopes of~1.0 Ga A-Type Felsic Rocks in the Southwestern Yangtze Block,South China:Petrogenesis and Tectonic Implications

The petrogenesis and tectonic affinity of Late Mesoproterozoic igneous rocks in the Yangtze Block are important to understand its tectonic evolution within the context of the Rodinia supercontinent’s reconstruction.Here,we report the SHRIMP zircon U-Pb ages,geochemistry,and Nd-Hf isotopic data for dacite from the Zegu Formation of the Dengxiangying Group in southwestern Yangtze Block.The crystallization age of the Zegu dacite is 1037 Ma.These rocks have relatively high Ga,Zr,Hf,and HREE contents,as well as high(10000×Ga)/Al(2.7-2.9)and FeOt/MgO(3.8-10.5)ratios,showing a geochemical affinity of A-type granitoids.Moreover,they are characterized by negativeεNd(t)(-3.6 to-7.5)and zirconεHf(t)values(-0.3 to-14.4),indicating that they likely generated via partial melting of an ancient continental crust source.The tectonic discriminant diagrams showed that the Zegu dacites have high Y and Nb contents(plotted in the‘within-plate’magmatic rocks field).In conclusion,the geochemistry and isotopic data indicated that the 1037 Ma felsic volcanic rock in the Dengxiangying Group generated during an intra-plate rift basin along a passive margin.Our work thus argues against a Grenvillian orogen’s existence in the Yangtze Block.In view of the subsequent Neoproterozoic subduction-related magmatism in the region,we suggest that the Yangtze Block might have been along the periphery of the Rodinia.

Zircon SHRIMP U-Pb ages and trace element geochemistry of the Kuhai gabbro and the Dur'ngoi diorite in the southern east Kunlun tectonic belt, Qinghai, Western China and their geological implications

Timing of the intermediate-basic igneous rocks developed in the area of Kuhai-A'nyêmaqên along the southern east Kunlun tectonic belt is a controversial issue. This paper presents new zircon SHRIMP U-Pb dating data for igneous zircons from the Kuhai gabbro and the Dur'ngoi diorite in the Kuhai-A'nyemaqen tectonic belt, which are 555±9 Ma and 493±6 Ma, respectively. The trace element geochemical features of the Kuhai gabbro and the Dur'ngoi diorite are similar to those of ocean island basalts (OIB) and island arc basalts (IAB), respectively. Thus, the Kuhai gabbro with the age of 555±9 Ma and OIB geochemical features is similar to the Yushigou oceanic ophiolite in the North Qilian orogen, whereas the Dur'ngoi diorite with the age of 493±6 Ma and IAB geochemical features is similar to the island arc volcanic rocks developed in the north Qaidam. The Late Neoproterozoic to Early Ordovician ophiolite complex in the area of Kuhai-A'nyêmaqên suggests that the southern margin of the "Qilian-Qaidam-Kunlun" archipelagic ocean in this period was located in the southern east Kunlun tectonic belt. Therefore, the southern east Kunlun tectonic belt in the early Paleozoic is not comparable to the Mianlüe tectonic belt in the Qinling orogenic belt.

High-pressure granulite from Western Kunlun,northwestern China:Its metamorphic evolution,zircon SHRIMP U-Pb ages and tectonic implication

High-pressure mafic granulites occurring as lenticular bodies within garnet-amphibolites in Kangxiwar Fault have been first reported in this paper. The P-T conditions of two metamorphic stages were obtained using calibrated geothermal barometers and ThermoCalc Program. The peak metamorphic condition of these high-pressure granulites is about 760–820°C, 1.0–1.2 GPa and the retrograde metamorphic condition is about 620–720°C, 0.7–0.8 GPa. The petrological studies show that they have a near-isobaric cooling P-T path which suggests that the Western Kunlun underwent initial crustal thickening, subsequent exhumation and cooling. The SHRIMP zircon U-Pb dating gives two groups of ages for high-pressure granulites. One is 177±6 Ma which is obtained from the rim of the zircon. We consider this age should be the metamorphic age. And the other is 456±30 Ma which is obtained from the core of the zircon and should be the protolith age. The formation of these high-pressure granulites in western Kunlun is closely correlated with the evolution of the Paleo-Tethys and has important implications for the research on Tethys and Paleo-Asian tectonic zone.

SHRIMP Zircon U-Pb Ages of the Wajilitag Igneous Complex: Constraints on the Origin of A-type Granitoids in the Tarim Large Igneous Province, NW China

Objective Large igneous provinces （LIPs） are sites of spatially contiguous, rapidly emplaced magmatic rocks, which represent the physical and chemical transfer of material from the mantle to the crust. Exposed within some continental LIPs are felsic and rnafic plutonic and volcanic rocks. Although their volumes are minor compared to the flood basalts, the plutonic rocks of continental LIPs are often associated with economic deposits of precious metals. Within the Permian Tarim LIP of NW China, there are at least two layered ultramafic-mafic intrusions （e.g. Wajilitag and Piqiang） contain economically important Fe- Ti-V oxide deposits. Spatially associated with these layered ultramafic-mafic intrusions are syenitic and granitic plutons, which have chemical characteristics of A- type granitoids.

Geochemistry and SHRIMP Zircon U-Pb Age of Post-Collisional Granites in the Southwest Tianshan Orogenic Belt of China:Examples from the Heiyingshan and Laohutai Plutons

The Heiyingshan granite and the Laohutai granite plutons exposed in the Southwest Tianshan resemble A-type granites geochemically. Analysis shows that the both are ferron calc-alkalic peraluminous or ferron alkali-calcic peraluminous with a relatively high concentration of SiO2 （〉70%）, high alkali contents （Na20 ＋ K20 = 7.14%-8.56%; K20〉N20; A/CNK = 0.99-1.20）, and pronounced negative anomales in Eu, Ba, St, P and Ti. A SHRIMP zircon U-Pb age of 285±4 Ma was obtained for the Heiyingshan hornblende biotite granite intrusion. The geochemical and age dating data reported in this paper indicate that these granites were formed during the post-collisional crustal extension of the Southwest Tianshan orogenic belt, in agreement with the published data for the granites in the South Tianshan.

Protracted zircon growth in migmatites and In situ melt of Higher Himalayan Crystallines:U-Pb ages from Bhagirathi valley, NW Himalaya,India

The Higher Himalayan Crystallines(HHC), in western Garhwal, Uttarakhand are located in a regionalscale intracontinental ductile shear zone(15-20 km wide) bounded by the Main Central Thrust at the base, and the South Tibetan Detachment System at the top. The migmatite zone in the centre has the highest grade of metamorphism in the NW Himalayas and show evidence of flowage. Zircons extracted from samples of metasediment, migmatite, biotite granite and in situ partial melt(tourmaline-bearing leucogranite) along the Bhagirathi Valley, preserve U-Pb isotopic evidence of magmatic history, magma source and effects of the Himalayan orogeny in the region. Three distinct periods of zircon growth in the leucogranite record the episodic influx of magma between 46 Ma and 20 Ma indicating a time span of more than 25 Ma between the onset of fluid-fluxed partial melting in the mid-crustal intracontinental shear zone and the emplacement of the magma into the upper crust in a post-collisional extensional setting. Metamorphic zircon growth was initiated about 46 Ma, when the partial melts were generated as the migmatite zone was exhumed.

Cretaceous Volcanic Events in Southeastern Jilin Province,China:Evidence from Single Zircon U-Pb Ages

Mesozoic volcanic rocks in southeastern Jilin Province are an important component of the huge Mesozoic volcanic belt in the northeastern area. Study of the age of their formation is of great significance to recognize Mesozoic volcanic rule in northeastern China. Along with the research of rare Mesozoic biota and extensive Mesozoic mineralization in western Liaoning, a number of researchers have focused on Mesozoic volcanic events. The authors studied the ages of the Cretaceous volcanic rocks in southeastern Jilin Province using single Zircon U-Pb. The result shows that the Sankeyushu Formation volcanic rocks in the Tonghua area are 119.2 Ma in age, the Yingcheng Formation in the Jiutai area 113.4±3.1 Ma, the Jinjiatun Formation in Pinggang Town of Liaoyuan City and the Wufeng volcanic rocks in the Yanji area 103.2±4.7 Ma and 103.6±1 Ma, respectively. Combined with the data of recent publication on volcanic rocks ages; the Cretaceous volcanic events in southeastern Jilin Province can be tentatively subdivided into three eruption periods： 119 Ma, 113 Ma and 103 Ma. The result not only provides important chronology data for subdividing Mesozoic strata in southeastern Jilin Province, establishing Mesozoic volcanic event sequence, discussing geological tectonic background, and surveying the relation between noble metals to the Cretaceous volcanic rocks, but also offers important information of Mesozoic volcanism in northeastern China.

Constraints on sedimentary ages of the Chuanlinggou Formation in the Ming Tombs, Beijing, North China Craton: LA-ICP-MS and SHRIMP U–Pb dating of detrital zircons

Detrital zircons in five sedimentary samples, MC1 to MC5, from the bottom of the Chuanlinggou Formation in the Ming Tombs District, Beijing, were dated with the LA-ICP-MS and SHRIMP U-Pb methods. Age spectra of the five samples show a major peak at 2500 Ma and a secondary peak at 2000 Ma, suggesting their provenances were mainly from the crystalline basement of the North China Craton and the Trans-North China Orogen. The youngest zircon has an age of 1673 d： 44 Ma, indicating that the Chuanlinggou Formation was deposited after this age. From sample MC4 to MC5, lithology changed from a clastic rock （fine-grained sandstone） to a carbonate rock （fine-grained dolomite）, suggesting that the depositional basin became progressively deeper. The age spectrum of sample MC5 shows a major peak at 2500 Ma and a secondary peak at 2000 Ma. Sample MC4, which is stratigraphically lower than sample MC5, only had one peak at 2500 Ma. We conclude that there was a transgressive event when sediments represented by MC5 was deposited, and seawater carried ca. 2000 Ma clastic materials to the basin where the Chuanlinggou Formation was deposited, leading to the addition of ca. 2000 Ma detritus. Our research indicates that the source area for the sediments became more extensive with time. We conclude that the Chuanlinggou Formation in the Ming Tombs District was deposited in a low-energy mud fiat sedimentary environment in the inter-supra tidal zone because it is mainly composed of silty mudstone and fine-grained sandstone with relatively simple sedimentary structures.

Zircon U-Pb Ages and Geochemistry of Permo-Carboniferous Mafic Intrusions in the Xilinhot Area, Inner Mongolia: Constraints on the Northward Subduction of the Paleo-Asian Ocean

The Central Asian Orogenic Belt(CAOB) resulted from accretion during the Paleozoic subduction of the PaleoAsian Ocean. The Xilinhot area in Inner Mongolia is located in the northern subduction zone of the central-eastern CAOB and outcropped a large number of late Paleozoic mafic intrusions. The characteristics of magma source and tectonic setting of the mafic intrusions and their response to the closure process of the Paleo-Asian Ocean are still controversial. This study presents LA-ICPMS zircon U-Pb ages and geochemical features of mafic intrusions in the Xilinhot area to constrain the northward subduction of the Paleo-Asian Ocean. The mafic intrusions consist of gabbro, hornblende gabbro, and diabase. Their intrusion times can be divided into three stages of 326-321 Ma, 276 Ma and 254 Ma by zircon U-Pb ages. The first two stages of the 326-276 Ma intrusions mostly originated from subduction-modified continental lithospheric mantle sources that underwent a variable degree partial melting(5-30%), recording the subduction of oceanic crust. The third stage of the 254 Ma mafic rocks also show arc-related features. The primary magma compositions calculated by PRIMELT2 modeling on three samples of ~326 Ma and two samples of ~254 Ma show that these mafic samples are characterized by a variable range in SiO2(47.51-51.47 wt%), Al2O3(11.46-15.55 wt%), ΣFeO(8.27-9.61 wt%), MgO(13.01-15.18 wt%) and CaO(9.13-11.67 wt%), consisting with the features between enriched mantle and lower continental crust. The source mantle melting of mafic intrusions occurred under temperatures of 1302-1351°C and pressures of 0.92-1.30 GPa. The magmatic processes occurred near the crust-mantle boundary at about 33-45 km underground. Combined with previous studies, it is concluded that Carboniferous to early Permian(~326-275 Ma) northward subduction of the Paleo-Asian oceanic crust led to the formation of the mafic magmatism in the Baolidao arc zone. The whole region had entered the collision environment at ~254 Ma, but with subduction-related environments locally. The final collision between the North China craton and the South Mongolian microcontinent may have lasted until ca. 230 Ma.

New detrital zircon U-Pb ages from BIF-related metasediments in the Ntem Complex (Congo craton) of southern Cameroon, West Africa

Banded Iron Formations (BIFs) were formed by contemporaneous events of active sediments supply and the venting of a hydrothermal fluid source at the Mid-Ocean-Ridge. BIFs within the Ntem Complex at the northern edge of the Congo Craton are intercalated with metasandstones and siltstones. SHRIMP U-Pb analysis on detrital zircons obtained from these metasediments gave variable ages from over 3000 Ma to 1000 Ma with the maximum age of deposition clustered around 1200 Ma and the peak of deposition at 1800 Ma. This age range suggested that the sub-basin was opened sometime in the Archean and remained active up till the Neoproterozoic. Zircons with Archean ages have a provenance linked to the charnockitic suite and the high-K granites within the Ntem Complex. The Paleoproterozoic ages are attributed to clastic inputs from the neigbouring Nyong Series west of the Ntem Complex. Also the peak of deposition in the Proterozoic could probably be explained by the globally recognized intense crust-forming processes in the Early Proterozoic time. The provenance of the younger Neoproterozoic ages is tied to various lithologies within the northern mobile belts of the Adamawa-Yade massifs and correlates with Neoproterozoic sedimentation ages in the Yaoundé, Lom and Poli series. The Neoproterozoic ages obtained are comparable to those obtained from metasediments of the Amazonian Craton and provide evidence of Pre-Gondwana assemblage of the Congo and the S?o Francisco Cratons.

Age and Origin of Paleogene Granitoids from Western Yunnan Province,China:Geochemistry,SHRIMP Zircon Ages,and Hf-in-Zircon Isotopic Compositions

We report geochemical data, SHRIMP zircon ages and Hf-in-zircon isotopic compositions for Cenozoic granitoids from major fault systems in the Tethyan belt in western Yunnan Province, southwestern China.Four magmatic pulses occurred in the Paleogene, namely at ca.57 Ma, ca.50 Ma, 45–40 Ma, and 38–34 Ma.Early magmatism of this episode（57–50 Ma） produced S-type granites whose zircons yielded εHf（t） values of-5.0 to-0.3.In contrast, late magmatism of this episode reflects heterogeneous sources.Zircons from a granite porphyry along the Ailaoshan-Red River fault system have slightly positive εHf（t） values suggesting derivation from relatively young crust and/or a juvenile source.However, zircons from a granite along the Gaoligong fault system have strongly negative εHf（t） values and suggest derivation from a Paleoproterozoic crustal source.The composition of the granitoids varies with age（from ca.57 Ma to ca.34 Ma） from peraluminous to metaluminous and also suggests a change from syn-collisional to late-orogenic tectonic setting.A new tectonic model, impacting lithospheric wedge（ILW） is shown for the origin of Paleogene granitoids in this paper.

LA-ICPMS U-Pb Ages of Zircon from Metaleucosomes, Olongbuluke Microcontinent, North Qaidam, and Implications on the Response to the Global Rodinia Supercontinent Assembly Event in NW China

U-Pb dating was conducted on different domains of zircons from metamorphosed leucosomes in Delingha （ 德令哈） complex, the lower basement rocks of the Olongbuluke （欧龙布鲁克 ） microcontinent, North Qaidam, in order to review its complex tectonothermal history. The zircon core is comprised of highly-modified magmatic zircon relicts, the zircon mantle was produced in response to anatexis of a Late Protoproterozoic thermal event; age and isotopic composition of both the zircon core and the zircon mantle have been seriously disturbed due to the thermal event related with growth of the zircon overgrowth rim. The 207 PIV 206 Pb apparent age of the overgrowth rim was estimated to be - 1 030 Ma. This Late Mesoproterozoic thermal event has been interpreted as a response to the global Rodinia supercontinent assembly event in the Olongbuluke microcontinent, Northwest China.

Discovery of rhyolitic tuffaceous slate in the southwestern margin of Yangtze Craton:Zircon U-Pb ages(2491 Ma)and tectonic-thermal events

The Mesoproterozoic Dongchuan Group that is widely exposed in Yimen area,central Yunnan Province is a series of sedimentary sort of low-grade metamorphic rocks interbedded with volcanic rocks,which are closely related to the early tectonic evolution of the Earth.However,its formation era,sedimentary filling sequence,and geotectonic characteristics have always been in dispute.In this study,several rhyolitic tuffaceous slate interlayers with a centimeter-level thickness were found in the previously determined Heishan Formation of the Dongchuan Group located to the western part of Yimen-Luoci fault zone.This paper focuses on the study of the rhyolitic tuffaceous slate in Qifulangqing Village,Tongchang Township,Yimen County.LA-ICP-MS zircon dating was conducted,achieving the crystallization age of magma of 2491±15 Ma and the metamorphic ages of about 2.3 Ga,2.0 Ga,and 1.8 Ga for the first time.Meanwhile,according to in-situ Hf isotope analysis,the zirconεHf(t)values were determined to range from−3.0 to 7.6,with an average of 2.7.Furthermore,the first-stage Hf model age(TDM1)was determined to be 2513−2916 Ma,indicating that the provenance of the rhyolitic tuffaceous slate is the depleted mantle or juvenile crust between the Middle Mesoarchean and the Late Neoarchean.Therefore,it is believed that the strata of the slate were deposited in the Late Neoarchean,instead of the Mesoproterozoic as determined by previous researchers.Accordingly,it is not appropriate to group the strata into the Mesoproterozoic Dongchuan Group.Instead,they should be classified as the Maolu Formation of the Neoarchean Puduhe Group given the lithologic association and regional information.Furthermore,the magma ages of 2491±15 Ma are highly consistent with the eras of the large-scale Late Neoarchean orogenic magmatic activities on the northern margin of the Yangtze Craton,and thus reflect the orogenic process consisting of subduction and collision from Late Neoarchean to Early Paleoproterozoic.The magmatic activities during this period were possibly caused by the convergence of the supercontinent Kenorland.Meanwhile,the metamorphic ages of 2.3 Ga,2.0 Ga,and 1.8 Ga are highly consistent with three metamorphic ages of 2.36 Ga,1.95 Ga,and 1.85 Ga of the northern margin of the Yangtze Craton,indicating that the strata experienced Paleoproterozoic tectonic-thermal events.The study area is located on the eastern margin of Qinghai-Tibet Plateau,and thus was possibly re-transformed by magmatism subjected to the subduction of the Meso-Tethys Ocean during the Early Cretaceous.The discoveries made in this study will provide strong petrological and chronological evidence for analyzing the early crustal evolution of the Yangtze block.

Zircon U-Pb ages and Hf isotopic characteristics of the Dehe biotite monzonitic gneiss pluton in the North Qinling orogen and their geological significance

The Dehe granitic pluton intruded the Xiahe Group which is in the core complex of the North Qinling Orogenic Belt(NQOB).It shows gneissic bedding and possesses typical S-type granite minerals such as muscovite and garnet.LA-ICP-MS U-Pb isotopic dating of the Dehe granite yielded a weighted average age of 925±23 Ma which represents the emplacement age of the pluton.Most of the εHf(t) values are negative,and the two-stage model ages are consistent with the age of the Qinling Group.The isotope data show that the Dehe granite was formed in the following geological setting:in the syn-collision setting of the NQOB in the Neoproterozoic,crustal thickening induced partial melting of materials derived from the Qinling complex,and then the maga upwelled and intruded into the Xiahe Group.The formation of the Dehe S-type granite implied the occurrence of a convergent event in the QOB during the Neoproterozoic.

Zircon U-Pb Ages of Bottom and Top Parts of the Zhangjiakou Formation in Lingyuan Area(West Liaoning Province) and Luanping Area (North Hebei Province) and Their Significance

In Lingyuan region of West Liaoning Province, the Zhangjiakou Formation (J_3z) and the Yixian Formation (K_1y) display an angular unconformity. That is, the Lower Mesozoic strata of the Zhangjiakou Formation are ENE (near E-W) oriented, while the overlying strata of the Yixian Formation exhibit an NNE orientation. The results of LA-ICP-MS zircon U-Pb ages show the Zhangjiakou Formation formed from about 130 Ma to 132 Ma in Lingyuan and 135 Ma to 136 Ma in Luanping (North Hebei Province), respectively. Three conclusions can be drawn: (1) The Zhangjiakou Formation in Lingyuan is comparable to that in Luanping, with the volcanic rocks of the Zhangjiakou Formation from Lingyuan being younger than those from Luanping. (2) 5-6 Ma difference between the top of the Zhangjiakou Formation and the bottom of the Yixian Formation in Lingyuan proves the angular unconformity between the two formations; and it reflects that the 5-6 Ma interval period is the main period of the transition of tectonic framework in Mesozoic in North Hebei and West Liaoning. In the interval period, the magmatic action went up to high tide in Mesozoic in the northeast of China. Moreover, after the interval period, the “Rehe fauna” developed into “erupted” period. This reflects that the interval period is also an important biological interface in Northern Hebei and Western Liaoning. (3) The Dabeigou Formation in Luanping should correspond to the upper part of the Zhangjiakou Formation, but not to the lower part of the Yixian Formation.

Geochemistry and zircon U-Pb ages of the Oligocene sediments in the Baiyun Sag, Zhujiang River Mouth Basin

In this study,element geochemistry and zircon chronology are used to analyze the Oligocene sediments in the Baiyun Sag,Zhujiang River Mouth Basin.The experimental results are discussed with respect to weathering conditions,parent rock lithologies,and provenances.The chemical index of alteration and the chemical index of weathering values of mudstone samples from the lower Oligocene Enping Formation indicate that clastic particles in the study area underwent moderate weathering.Mudstone samples exhibit relatively enriched light rare earth elements and depleted heavy rare earth elements,"V"-shaped negative Eu anomalies,and negligible Ce anomalies.The rare earth element distribution curves are obviously right-inclined,with shapes and contents similar to those of post-Archean Australian shale and upper continental crust,indicating that the samples originated from acid rocks in the upper crust.The Hf-La/Th and La/Sc-Co/Th diagrams show this same origin for the sediments in the study area.For the samples from the upper Enping deltas,the overall age spectrum shows four major age peaks ca.59–68 Ma,98–136 Ma,153–168 Ma and 239–260 Ma.For the Zhuhai Formation samples,the overall age spectrum shows three major age peaks ca.149 Ma,252 Ma and 380 Ma.The detrital zircon shapes and U-Pb ages reveal that during Oligocene sedimentation,the sediments on the northwestern margin of the Baiyun Sag were supplied jointly from two provenances:Precambrian-Paleozoic metamorphic rocks in the extrabasinal South China fold zone and Mesozoic volcanic rocks in the intrabasinal Panyu Low Uplift,and the former supply became stronger through time.Thus,the provenance of the Oligocene deltas experienced a transition from an early proximal intrabasinal source to a late distal extrabasinal source.

First Report of Zircon U-Pb Ages from Lubei Cu-Ni Sulfide Deposit in East Tianshan of Central Asian Orogenic Belt, NW China

Objective The East Tianshan mafic-ultramafic rocks belt mainly produced in the eastern Jueluotage belt is an important part of the Central Asia Orogenic Belt （CAOB）. The well- known deposits including Huangshan, Huangshandong, Tulaergen, Hulu, Xiangshan were have been consecutively discovered in this belt （Duan Xingxing et al., 2016）. The new discovery of the Lubei Cu-Ni sulfide deposit in recent years, which locates in the west of Jueluotage belt, has great significance to the westward extension of the East Tianshan Cu-Ni metallogenic belt. To determine whether the mineralization age of the Lubei Cu-Ni sulfide deposit is consistent with other typical deposits, this study conducted zircon U-Pb geochronology on the diorite from the Lubei Cu-Ni sulfide deposit in order to provide new information for further exploring direction of Cu-Ni prospecting in East Tianshan.