Geochemistry, zircon U–Pb geochronology, and Hf isotopes of S-type granite in the Baoshan block, constraints on the age and evolution of the Proto-Tethys

Geochemistry, zircon U–Pb geochronology, and Hf isotope data for the Early Paleozoic granites in the Baoshan Block reveal the Early Paleozoic tectonic evolution of the Proto-Tethys. The samples are high-K, calcalkaline, strongly peraluminous rocks with A/CNK values of 1.37–1.46, are enriched in SiO2, K2O, and Rb, and are depleted in Nb, P, Ti, Eu, and heavy rare earth elements,which indicates the crystallization fractionation of the granitic magma. Zircon U–Pb dating indicates that they formed in ca. 480 Ma. The Nansa granites have εHf(t) values ranging from-16.04 to 4.36 with corresponding TC DMages of 2.10–0.81 Ga, which suggests the magmas derived from the partial melting of ancient metasedimentary with minor involvement of mantle-derived components. A synthesis of data for the Early Paleozoic igneous rocks in the Baoshan block and adjacent(Tengchong,Qiangtang, Sibumasu, Himalaya, etc.) blocks indicates that these blocks were all aligned along the proto-Tethyan margin of East Gondwana in the Early Paleozoic. The Early Paleozoic S-type granites from Nansa were generated in a high-temperature and low-pressure(HTLP) extensional tectonic setting, which resulted from Andean-type orogeny instead of the final assembly of Gondwana or crustal extension in a non-arc environment. In certain places, an expanding environment may exist in opposition to the tectonic backdrop of the lithosphere’s thickening and shortening, leading the crust to melt and decompress,mantle-derived materials to mix, and a small quantity of peraluminous granite to emerge.

Mineral Chemistry,Trace Elements,Isotopic Analysis and Zircon U-Pb Dating in the Hesar Pluton,Northern UDMA,Iran:Implications for Pre-Collisional Magma Mixing

The Hesar pluton in the northern Urumieh-Dokhtar magmatic arc hosts numerous mafic-microgranular enclaves(MMEs).Whole rock geochemistry,mineral chemistry,zircon U-Pb and Sr-Nd isotopes were measured.It is suggested that the rocks are metaluminous(A/CNK=1.32-1.45),subduction-related I-type calc-alkaline gabbro to diorite with similar mineral assemblages and geochemical signatures.The host rocks yielded an U-Pb crystallization age of 37.3±0.4 Ma for gabbro-diorite.MMEs have relatively low SiO_(2) contents(52.9-56.6 wt%)and high Mg^(#)(49.8-58.7),probably reflecting a mantle-derived origin.Chondrite-and mantle-normalized trace element patterns are characterized by LREE and LILE enrichment,HREE and HFSE depletion with slight negative Eu anomalies(Eu/Eu^(*)=0.86-1.03).The host rocks yield(^(87)Sr/^(86)Sr)_(i) ratios of 0.70492-0.70510,positive ε_(Nd)(t)values of+1.55-+2.06 and T_(DM2)of 707-736 Ma,which is consistent with the associated mafic microgranular enclaves((^(87)Sr/^(86)Sr)_(i)=0.705014,ε_(Nd)(t)=+1.75,T_(DM2)=729 Ma).All data suggest magma-mixing for enclave and host rock formation,showing a complete equilibration between mixed-mafic and felsic magmas,followed by rapid diffusion.The T_(DM1)(Nd)and T_(DM2)(Nd)model ages and U-Pb dating indicate that the host pluton was produced by partial melting of the lower continental crust and subsequent mixing with injected lithospheric mantlederived magmas in a pre-collisional setting of Arabian-Eurasian plates.Clinopyroxene composition indicates a crystallization temperature of~1000℃ and a depth of~9 km.

Petrogenesis and Tectonic Implications of the Early Triassic Nianzi Adakitic Granite Unit in the Yanshan Fold and Thrust Belt:New Constraints from U-Pb Geochronology and Sr-Nd-Hf Isotopes

The Nianzi granite unit,which includes the Nianzi,Xiaolianghou and Xiawopu granitic intrusions,is a significant component of the northern part of the North China Craton(NCC)and is situated in the Yanshan fold and thrust belt(YFTB).However,there is still debate regarding the tectonic evolutionary history of the YFTB during the late Permian to Triassic period,specifically regarding the timing of subduction and collision between the NCC and the Paleo-Asian Ocean.The Nianzi granite unit exhibits unique petrological,geochronological and geochemical signatures that shed light on the tectonic evolutionary history of the YFTB.This study presents detailed petrology,whole-rock geochemistry,together with Sr-Nd isotopic,zircon U-Pb dating and Lu-Hf isotopic data of the granites within the Nianzi granite unit.Our findings demonstrate that the granites primarily consist of subhedral K-feldspar,plagioclase,quartz,minor biotite and hornblende,with accessory titanite,apatite,magnetite and zircon.Zircon U-Pb dating indicates that the Xiaolianghou granite was emplaced at 247.5±0.62 Ma.Additionally,the adakitic characteristics of the Nianzi,Xiawopu and Xiaolianghou granitic intrusions,such as high Sr and Ba contents and high ratios of Sr/Y and(La/Yb)N,combined with negative Sr-Nd and Lu-Hf isotopes(87Sr/86Sr)i=0.705681–0.7057433,εNd(t)=−21.98 to−20.97,zirconεHf(t)=−20.26 to−9.92,as well as the I-type granite features of high SiO_(2),Na_(2)O and K_(2)O/Na_(2)O ratios,enriched Rb,K,Sr and Ba,along with depleted Th,U,Nb,Ta,P and Ti,suggest that the Nianzi granitic unit was mainly derived from the partial melting of a thickened lower crust containing hydrous,calc-alkaline to high-K calc-alkaline,mafic to intermediate metamorphic rocks.In light of these parameters,we further integrate our data with previous studies and conclude that the Nianzi granitic unit was generated in a post-collisional extensional environment during the Early Triassic.

Zircon U-Pb geochronology,Hf isotopes,and geochemistry constraints on the age and tectonic affinity of the basement granitoids from the Qiongdongnan Basin,northern South China Sea

Studies in the northern South China Sea(SCS)basement remain important for understanding the evolution of the Southeast Asian continental margin.Due to a thick cover of sediments and scarce borehole penetration,little is known about the age and tectonic affinity of this basement.In this study,an integrated study of zircon U-Pb geochronology,Hf isotopes,and whole-rock major and trace elements on seven basement granitoids from seven boreholes of Qiongdongnan Basin has been carried out.New zircon U-Pb results for these granitoids present middle-late Permian((270.0±1.2)Ma;(253±3.4)Ma),middle to late Triassic((246.2±3.4)Ma;(239.3±0.96)Ma;(237.9±0.99)Ma;(228.9±1.0)Ma)and Late Cretaceous ages((120.6±0.6)Ma).New data from this study,in combination with the previous dataset,indicates that granitoid ages in northern SCS basement vary from 270 Ma to 70.5 Ma,with three age groups of 270–196 Ma,162–142 Ma,and 137–71 Ma,respectively.Except for the late Paleozoic-Mesozoic rocks in the basement of the northern SCS,a few old zircon grains with the age of(2708.1±17)Ma to(2166.6±19)Ma provide clues to the existence of the pre-Proterozoic components.The geochemical signatures indicate that the middle Permian-early Cretaceous granitoids from the Qiongdongnan Basin are I-type granites formed in a volcanic arc environment,which were probably related to the subduction of the Paleo-Pacific Plate.

Single-grained zircon U-Pb isotope dating of Precambrian volcanic rocks in western Zhejiang and its implications

The Precambrian calc-alkaline volcanic rocks of western Zhejiang Province

Garnet and Zircon U-Pb Geochronology and Geochemistry Reveal Genesis of the Dafang Au-Pb-Zn-Ag Deposit,Southern Hunan

Garnet is a primary mineral in skarn deposits and plays a significant role in recording copious mineralization and metallogenic information.This study systematically investigates the geochemistry and geochronology of garnet and zircon in the Dafang Au-Pb-Zn-Ag deposit,which represents prominent gold mineralization in southern Hunan,China.Garnet samples with distinct zoning patterns and compositional variations were identified using various analytical techniques,including Backscattered Electron(BSE)imaging,Cathodoluminescence(CL)response,textural characterization,and analysis of rare-earth elements(REE),major contents,and trace element compositions.The garnet was dated U-Pb dating,which yielded a lower intercept age of 161.06±1.93 Ma.This age is older than the underlying granodiorite porphyry,which has a concordia age of 155.13±0.95 Ma determined by zircon U-Pb dating.These results suggest that the gold mineralization may be related to the concealed granite.Two groups of garnet changed from depleted Al garnet to enriched Al garnet,and the rare earth element(REE)patterns of these groups were converted from light REE(LREE)-enriched and heavy REE(HREE)-depleted with positive europium(Eu)anomalies to medium REE(MREE)-enriched from core to rim zoning.The different REE patterns of garnet in various zones may be attributed to changes in the fluid environment and late superposition alteration.The development of distal skarn in the southern Hunan could be a significant indicator for identifying gold mineralization.

Polymetamorphism of the ultrahigh-temperature granulites in the Rauer Group,East Antarctica:new evidence from zircon SHRIMP U-Pb ages

The Rauer Group is located on the eastern margin of the early Paleozoic Prydz Belt in East Antarctica,and the typical ultrahigh-temperature(UHT,>900℃)granulites outcrop on Mather Peninsula.However,the timing of UHT metamorphism and P–T path of the UHT granulites have long been debated,which is critical to understanding the tectonic nature and evolution history of the Prydz Belt.Thus,both a sapphirine-bearing UHT metapelitic granulite and a garnet-bearing UHT mafic granulite are selected for zircon SHRIMP U-Pb age dating.The results show that metamorphic zircon mantles yield weighted mean^(206)Pb/^(238)U ages of 918±29 Ma and 901±29 Ma for the metapelitic and mafic granulites,respectively,while zircon rims and newly grown zircons yield weighted mean^(206)Pb/^(238)U ages of 523±9 Ma and 532±11 Ma,respectively.These new zircon age data suggest that the UHT granulites may have experienced polymetamorphism,in which pre-peak prograde stage occurred in the early Neoproterozoic Grenvillian orogenesis(1000–900 Ma),whereas the UHT metamorphism occurred in the late Neoproterozoic to early Paleozoic Pan-African orogenesis(580–460 Ma).This implies that P–T path of the UHT granulites should consist of two separate high-grade metamorphic events including the Grenvillian and Pan-African events,which are supposed to be related to assembly of Rodinia and Gondwana supercontinents respectively,and hence the overprinting UHT metamorphic event may actually reflect an important intracontinental reworking.

Petrogenesis of the Xihuashan Granite in Southern Jiangxi Province,South China:Constraints from Zircon U-Pb Geochronology,Geochemistry and Nd Isotopes

Mesozoic granitic intrusions are widely distributed in the Nanling region, South China. Yanshanian granites are closely connected with the formation of tungsten deposits. The Xihuashan granite is a typical representative of tungsten-bearing granite. The Xihuashan granite consists mainly of medium-grained porphyritic biotite granite, medium-grained biotite granite and fine-grained twomica granite, which correspond to LA-ICP-MS zircon U-Pb ages of 555.5±0.4 Ma, 553.0±0.6 Ma and 552.8±0.9 Ma, respectively. Rocks from the Xihuashan mining area displays high SlOe （73.85% to 76.49%） and NaeO＋K20 contents （8.09% to 9.43%）, belonging to high-K calc-alkaline series. They are metaluminous to weakly peraluminous with A/CNK values ranging from 0.96 to 5.06. All granites in this study area are rich in Rb, Th, U and Pb, and depleted in Ba, Sr, P, Ti, Nb and Eu, especially depleted in medium-grained biotite granite and fine-grained two-mica granite. The medium-grained porphyritic biotite granites usually have high LREE concentrations, whereas medium-grained biotite granite and fine-grained two-mica granite displays high HREE contents. Our geochemical data reveal that the studied rocks are highly fractionated I-type granite. The magma underwent strong magma differentiation with decreasing temperature and increasing oxygen fugacity, which may explain the formation of three types of distinct granites. Variations of Rb, Sr and Ba concentrations in different type granites were controlled by fractional crystallization of biotite and feldspar. Fractional crystallization of monazite, allanite and apatite resulted in LREE changes in granite, and formation of garnet mainly caused HREE changes. Granites from the Xihuashan mining area have relatively high εd（t） values （-9.77 to -55.46）, indicating that they were probably generated by partial melting of underlying Proterozoic metasedimentary rocks with minor addition of juvenile crust or mantlederived magmas.

U-Pb Age and Hf Isotope Study of Detrital Zircons from the Wanzi Supracrustals:Constraints on the Tectonic Setting and Evolution of the Fuping Complex,Trans-North China Orogen

Located in the middle segment of the Trans-North China Orogen, the Fuping Complex is considered as a critical area in understanding the evolution history of the North China Craton （NCC）. The complex is composed of various high-grade and multiply deformed rocks, including gray gneiss, basic granulite, amphibolite, fine-grained gneiss and marble, metamorphosed to upper amphibolite or granulite facies. It can be divided into four rock units： the Fuping TTG gneisses, Longquanguan augen gneisses, Wanzi supracrustals, and Nanying granitic gneisses. U-Pb age and Hf isotope compositions of about 200 detrital zircons from the Wanzi supracrustals of the Fuping Complex have been analyzed. The data on metamorphic zircon rims give ages of 1.82-1.84 Ga, corresponding to the final amalgamation event of the NCC, whereas the data for igneous zircon cores yield two age populations at -2.10 and -2.51 Ga, with some inherited ages scattering between 2.5 and 2.9 Ga. These results suggest that the Wanzi supracrustals were derived from the Fuping TTG gneisses （-2.5 Ga） and the Nanying granitic gneisses （2.0-2.1 Ga） and deposited between 2.10 and 1.84 Ga. All zircons with -2.51 Ga age have positive initial εHf values from ＋1.4 to ＋10.9, suggesting an important crustal growth event at -2.5 Ga through the addition of juvenile materials from the mantle. The Hf isotope data for the detrital zircons further imply that the 2.8 Ga rocks are important components in the lower crust, which is consistent with a suggestion from Nd isotope data for the Eastern Block. The zircons of 2.10 Ga population have initial εHf values of-4.9 to ＋6.1, interpreted as mixing of crustal re-melt with minor juvenile material contribution at 2.1 Ga. These results are distinct from that for the Western Block, supporting that the Fuping Complex was emplaced in a tectonic active environment at the western margin of the Eastern Block.

Petrogenesis of Kejie Granite in the Northern Changning-Menglian Zone, Western Yunnan: Constraints from Zircon U-Pb Geochronology, Geochemistry and Hf Isotope

The Kejie pluton is located in the north of the Changning-Menglian suture zone. The rock types are mainly biotite-granite. Zircon LA-ICP-MS U-Pb dating indicates that the Kejie pluton emplaced at about 80-77 Ma, Late Cretaceous. The Kejie pluton samples are characterized by high SiO2 （71.68%-72.47%）, K2O （4.73%-5.54%）, total alkali （K2O ＋ Na2O = 8.21%-8.53%）, K2O/Na2O ratios （1.36-1.94） and low P2O5 （0.13%-0.17%）, with A/CNK of 1.025-1.055; enriched in U, Th, and K, depleted in Ba, Nb, St, Ti, P and Eu. They are highly fractionated, slightly peraluminous 1-type granite. The two samples of the Kejie pluton give a large variation of εHf（t） values （-5.04 to 1.96） and Hf isotope crustal model ages of 1.16-1.5 Ga. Zircon Hf isotopes and zircon saturation temperatures of whole-rock （801℃-823℃） show that the mantle-derived materials maybe have played a vital role in the generation of the Kejie pluton. The Kejie pluton was most likely generated in a setting associated with the eastward subduction of the neo-Tethys ocean, where intrusion of mantle wedge basaltic magmas in the crust caused the anatexis of the latter, forming hybrid melts, which subsequently experienced high-degree fractional crystallization.

Emplacement Ages and Petrogenesis of the Molybdenum-bearing Granites in the Jinduicheng Area of East Qinling, China: Constraints from Zircon U-Pb Ages and Hf Isotopes

The Mesozoic porphyry assemblage in the Jinduicheng area is a special molybdenum area in China, the Mo deposits, including the Jinduicheng, Balipo, Shijiawan, Huanglongpu, are distributed. The emplacement age and geochemical features of the granites in the Jinduicheng area can provide essential information for the exploration and development of the porphyry molybdenum deposit. In this study, we report LA-ICP-MS zircon U-Pb age and zircon Hf isotopic compositions of granite porphyries from the Jinduicheng area, and provide insights on the petrogensis and source characteristics of the granites. The results show that the zircon U-Pb ages of the Jinduicheng granite porphyry （143±1 Ma） and the Balipo granite （154±1 Ma）, agree well with the Re-Os ages of molybdenite in the Jinduicheng molybdenum polymetallic deposit （139±3 Ma） and the Balipo molybdenum polymetallic deposit （156±2 Ma）, indicating that the emplacement of granite porphyries occurred between Late Jurassic and Early Cretaceous. Zircons granite from the Jinduicheng area give the εHf（t） values mainly ranging from -10 to -16, and -20 to -24, respectively, corresponding to two- stage model ages （tDM2： mainly focused on 1.86-2.0 Ga, and 2.2-2.6 Ga, respectively） of zircons of the granite from the Jinduicheng values. The ore-forming materials are mainly derived from crust, with minor mantle substances. Zircons of the granite from the Balipo area give εHf（t） values ranging from -18 to -20, -28 to -38, and -42 to -44, respectively, corresponding to two-stage model ages （tDM2： mainly focused on 1.88-3.0 Ga, and 3.2-3.90 Ga, respectively）. the εHf（t） values of the Jinduicheng porphyry more than that of the Balipo porphyry, and two-stage model ages （tDM2） less than that of the Balipo porphyry, shows that he source of the porphyries originated from ancient lower crustal materials in the Jinduicheng area, and mixed younger components, more younger components contributed for the source of the Jinduicheng porphyry.

Petrogenesis of Late Cretaceous Jiangla＇angzong I-Type Granite in Central Lhasa Terrane, Tibet, China： Constraints from Whole-Rock Geochemistry, Zircon U-Pb Geochronology, and Sr-Nd-Pb-Hf Isotopes

The Jiangla＇angzong granite in the northern part of the Central Lhasa Terrane is composed of syenogranite and adamellite. LA-ICP-MS zircon U-Pb analyses suggest that syenogranite has a weighted mean 2±6pb/23SU age of 86±1 Ma （mean square weighted deviation=0.37）, which is in accordance with the muscovite Ar-Ar age （85±1 Ma） of Cu-Au ore-bearing skarns and the zircon U-Pb age （84±1 Ma） of adamellite. This suggests that the Jiangla＇angzong magmatism and Cu-Au mineralization events took place during the Late Cretaceous. The granite contains hornblende, biotite, and pyroxene, and does not contain Al-bearing minerals, such as muscovite, cordierite, and garnet. It has high contents of SiO2 （65.10 -70.91wt%）, K20 （3.44-5.17wt%）, and total K20＋Na20 （7.13-8.15wt%）, and moderate contents of A12Oa （14.14-16.45wt%） and CaO （2.33-4.11wt%）, with a Reitman index （δ43） of 2.18 to 2.33, and A/ CNK values of 0.88 to 1.02. The P205 contents show a negative correlation with SiO2, whereas Pb contents show a positive correlation with SiO2. Th and Y contents are relatively low and show a negative correlation with the Rb contents. These characteristics suggest that the Jiangla＇angzong granite is a high K calc-alkaline metaluminous I-type granite. It is enriched in light rare earth elements （LREE） and large ion lithofile elements （LILE）, and depleted in heavy rare earth elements （HREE） and high field strength elements （HFSE）, with LREE/HREE ratios of 11.7 to 18.1. The granite has negative Eu anomalies of 0.58 to 0.94 without obvious Ce anomalies （δCe=l.00-1.04）. The relatively low initial a7Sr/a6Sr ratios of 0.7106 to 0.7179, positive ε±nt（t） values of 1.0 to 4.1, and two-stage Hf model ages （TDM2） ranging from 889 Ma to 1082 Ma, These geochemical features indicate that the granite derived from a juvenile crust. The （143Nd/144Nd）t values from the Jiangla＇angzong granite range from 0.5121 to 0.5123, its eNd（t） values range from -10.17 to -6.10, its （^206pb /^204pb）t values range from 18.683 to 18.746, its （^207pb /^204pb）t values range from 15.695 to 15.700, and its （^208pb /^204pb）t values range from 39.012 to 39.071. These data indicate that the granite was formed by melting of the upper crust with the addition of some mantle materials. We propose that the Jiangla＇angzong granite was formed during the post- collision extension of the Qiangtang and Lhasa terranes.

Genesis of the Weiquan Ag-Polymetallic Deposit in East Tianshan, China： Evidence from Zircon U-Pb Geochronology and C-H-O-S-Pb Isotope Systematics

The Weiquan Ag-polymetallic deposit is located on the southern margin of the Central Asian Orogenic Belt and in the western segment of the Aqishan-Yamansu arc belt in East Tianshan,northwestern China. Its orebodies, controlled by faults, occur in the lower Carboniferous volcanosedimentary rocks of the Yamansu Formation as irregular veins and lenses. Four stages of mineralization have been recognized on the basis of mineral assemblages, ore fabrics, and crosscutting relationships among the ore veins. Stage I is the skarn stage(garnet + pyroxene), Stage Ⅱ is the retrograde alteration stage(epidote + chlorite + magnetite ± hematite 士 actinolite ± quartz),Stage Ⅲ is the sulfide stage(Ag and Bi minerals + pyrite + chalcopyrite + galena + sphalerite + quartz ± calcite ± tetrahedrite),and Stage IV is the carbonate stage(quartz + calcite ± pyrite). Skarnization,silicification, carbonatization,epidotization,chloritization, sericitization, and actinolitization are the principal types of hydrothermal alteration. LAICP-MS U-Pb dating yielded ages of 326.5±4.5 and 298.5±1.5 Ma for zircons from the tuff and diorite porphyry, respectively. Given that the tuff is wall rock and that the orebodies are cut by a late diorite porphyry dike, the ages of the tuff and the diorite porphyry provide lower and upper time limits on the age of ore formation. The δ13C values of the calcite samples range from-2.5‰ to 2.3‰, the δ18OH2 Oand δDVSMOWvalues of the sulfide stage(Stage Ⅲ) vary from 1.1‰ to 5.2‰ and-111.7‰ to-66.1‰, respectively,and the δ13C, δ18OH2 Oand δDV-SMOWvalues of calcite in one Stage IV sample are 1.5‰,-0.3‰, and-115.6‰, respectively. Carbon, hydrogen, and oxygen isotopic compositions indicate that the ore-forming fluids evolved gradually from magmatic to meteoric sources. The δ34SV-CDTvalues of the sulfides have a large range from-6.9‰ to 1.4‰, with an average of-2.2‰, indicating a magmatic source, possibly with sedimentary contributions. The206Pb/204Pb,207Pb/204Pb, and208Pb/204Pb ratios of the sulfides are 17.9848-18.2785,15.5188-15.6536, and 37.8125-38.4650, respectively, and one whole-rock sample at Weiquan yields206Pb/204Pb,207Pb/204Pb, and208Pb/204Pb ratios of 18.2060, 15.5674, and 38.0511,respectively. Lead isotopic systems suggest that the ore-forming materials of the Weiquan deposit were derived from a mixed source involving mantle and crustal components. Based on geological features, zircon U-Pb dating, and C-H-OS-Pb isotopic data, it can be concluded that the Weiquan polymetallic deposit is a skarn type that formed in a tectonic setting spanning a period from subduction to post-collision. The ore materials were sourced from magmatic ore-forming fluids that mixed with components derived from host rocks during their ascent, and a gradual mixing with meteoric water took place in the later stages.

Zircon U-Pb age,trace element and Hf isotope composition of Sepon Au-Cu deposit, Laos:tectonic and metallogenic implications

The Truong Son Fold Belt,located at the northeastern margin of the Indochina Block,is considered to be tectonically linked to the subduction of the Paleotethys Ocean and subsequent collision.Sepon is one of the most important super large deposits of the Truong Son Fold Belt.Our LA-ICP-MS zircon U-Pb dating results show that granodiorite porphyry samples from the Sepon deposit have ages of 302.1-4-2.9 Ma, which is a crucial phase for magmatic-tectonical activities from the Late Carboniferous to Early Permian and has avital influence on the mineralization of copper and gold.Zircon from granodiorite porphyry yields εHf (t)values of 4.32 to 9.64,and TDM2 has an average age of 914 Ma,suggesting that the source of the granodiorite porphyry in the region were mainly mantle components but underwent mixing and contamination of crust materials.The Ce^4+/Ce^3+ value of zircon in the granodiorite porphyry varys greatly from 2.4 to 1438.29,which shows magma mixing might occur.Considering the characteristics of trace elements in the zircon and the whole rock geochemical characteristics of intrusion rocks as well as the characteristics of regional volcanic-sedimentary association,it is indicated that the tectonic setting may be the continental arc environment.The Sepon Au-Cu deposit is derived from emplacement of calc-alkaline intermediate-acid magma with coming from deep sources in the subduction process of the Paleotethys Ocean,forming porphyry Mo-Cu,skam Cu-Au mineralization and a hydrothermal sedimentary-hosted Au mineralization in the wall rocks.

Sao Francisco-Congo Craton break-up delimited by U-Pb-Hf isotopes and trace-elements of zircon from metasediments of the Aracuaí Belt

Detrital zircon U-Pb geochronology combined with Hf isotopic and trace element data from metasedimentary rocks of the Aracuai Belt in southeastern Brazil provide evidence for break-up of the Congo-Sao Francisco Craton. The U-Pb age spectra of detrital zircons from metasediments of the Rio Doce Group(RDG) range from 900-650 Ma and define a maximum depositional age of ca. 650 Ma. Zircon trace element and whole rock data constrain an oceanic island arc as source for the deposition setting of the protoliths to the metasediments. Zircon ε_(Hf)(t) values from these rocks are positive between +1 and +15, supporting previous evidence of a Neoproterozoic extensional phase and oceanic crust formation in a precursor basin to the Aracuai Belt. Recrystallization of detrital zircon at ca. 630 Ma is compatible with a regional metamorphic event associated with terrane accretion to the Paleoproterozoic basement after transition from an extensional to a convergent regime. The juvenile nature, age spectra and trace element composition recorded in detrital zircons of metasediments from the Aracuai Belt correspond with zircons from metasedimentary rocks and oceanic crust remnants of other orogenic belts to its south. This suggests that rifting and oceanic crust formation of the entire orogenic system, the so-called Mantiqueira Province, was contemporaneous, most likely related to the opening of a large ocean. It further indicates that the cratonic blocks involved in the orogenic evolution of the Mantiqueira Province were spatially connected as early as 900 Ma.

Zircon U-Pb and Lu-Hf isotope constraints on Archean crustal evolution in Southeastern Guyana Shield

The southeastern Guyana Shield,northeast Amazonian Craton,in the north of Brazil,is part of a widespread orogenic belt developed during the Transamazonian orogenic cycle(2.26-1.95 Ga)that includes a large Archean continental landmass strongly reworked during the Transamazonian orogeny,named Amapa Block.It consists mainly of a high-grade metamorphic granulitic-migmatitic-gneiss complex,of Meso-to Neoarchean age and Rhyacian granitoids and supracrustal sequences.For the first time,coupled U-Pb and Lu-Hf isotope data were obtained on zircon by LA-ICP-MS from five tectono-stratigraphic units of the Archean basement and one Paleoproterozoic intrusive rock,in order to investigate the main episodes of crustal growth and reworking.Whole-rock Sm-Nd isotope data were compared to the zircon Lu-Hf data.Three main magmatic episodes were defined by U-Pb zircon dating,two in the Mesoarchean(~3.19 Ga and 2.85 Ga)and one in the Neoarchean(~2.69-2.65 Ga).SubchondriticεHf(t)values obtained for almost all investigated units indicate that crustal reworking processes were predominant during the formation of rocks that today make up the Amapa Block.Hf-TDMC model ages,ranging from2.99 Ga to 3.97 Ga,indicate that at least two important periods of mantle extraction and continental crust formation occurred during the Archean in southeastern Guyana Shield,an older one in the Eoarchean(~4.0 Ga)and a younger one in the Mesoarchean(~3.0-3.1 Ga).The latter is recognized as an important period of crustal accretion worldwide.The recognition of an Eoarchean episode to the southeastern most part of the Guyana Shield is unprecedented and was not recorded by whole-rock Sm-Nd data,which were restricted to the Meso-Paleoarchean(2.83 Ga to 3.51 Ga).This finding reveals t hat continental crust generation in the Amazonian Craton began at least 500 Ma earlier than previously suggested by the SmNd systematics.

Precambrian Tectonic Affinity of the Southern Langshan Area, Northeastern Margin of the Alxa Block: Evidence from Zircon U-Pb Dating and Lu-Hf Isotopes

The Alxa Block is the westernmost part of the North China Craton(NCC), and is regarded as one of the basement components of the NCC. Its geological evolution is of great significance for the understanding of the NCC.However, the Precambrian basement of the Alxa Block is still poorly studied. In this study, we present new in situ LA-ICPMS zircon U-Pb and Lu-Hf isotope data from the Diebusige Metamorphic Complex(DMC) which located in the eastern Alxa Block. Field and petrological studies show that the DMC consists mainly of metamorphic supracrustal rocks and minor metamorphic plutonic rocks and has experienced amphibolite-granulite facies metamorphism. Zircon U-Pb dating results suggested that the amphibolite sample yields a crystallization age of 2636 ± 14 Ma and metamorphic ages of 2517–2454 Ma and 1988–1952 Ma, proving the existence of exposed Archean rocks in the Langshan area and indicating that late Neoarchean to Paleoproterozoic metamorphic events existed in the Alxa Block. Two paragneiss samples show that the magmatic detrital zircons from the DMC yield 207Pb/206Pb ages ranging from 2.48 Ga to 2.10 Ga with two youngest peaks at 2.13 Ga and 2.16 Ga, respectively, and they were also overprinted by metamorphic events at 1.97–1.90 Ga and 1.89–1.79Ga. Compilation of U-Pb ages of magmatic detrital and metamorphic zircons suggested that the main part of the DMC may have been formed at 2.1–2.0 Ga. Zircon Lu-Hf isotope data show that the source materials of the main part of the DMC were originated from the reworking of ancient Archean crust(3.45–2.78 Ga). The Hf isotope characteristics and the tectonothermal event records exhibit different evolution history with the Khondalite Belt and the Yinshan Block and the other basements of the Alxa Block, indicating that the Langshan was likely an independent terrain before the middle Paleoproterozoic and was subjected to the middle to late Paleoproterozoic tectonothermal events with the Khondalite Belt as a whole.

New Insights into the Late Triassic Nadigangri Formation of Northern Qiangtang, Tibet, China： Constraints from U-Pb Ages and Hf Isotopes of Detrital and Magmatic Zircons

We report here U-Pb age and in situ Hf isotopic results for detrital and magmatic zircons from one conglomerate and four tuffite samples from the Late Triassic Nadigangri Formation across the North Qiangtang depression, Tibet. Coupled with previously published data in the region, this paper proposes new insights into the geochronological framework for the Nadigangri Formation. The deposition ages of tuffite from top to bottom in the Woruo Mountain, Quem Co and Dongqu River, are 203 Ma, 226 Ma, 221.5 Ma and 221.1 Ma, respectively. The detrital zircons yield a younger cluster of ages of 201.5-225 Ma from the conglomerate of the Quem Co Formation. The Late Triassic Nadigangri Formation defines a temporal range approximately between 201 and 225 Ma （Norian-Rhaetian）, including three predominant groups of 220-225 Ma, 210-217 Ma and 201-205 Ma, which correspond with the three main rifting episodes of initial rifting, further rifting and final rifting. Positive ~Hf（t） value and low model ages in younger detrital zircons suggests a juvenile character. However, the Hf isotopes of magmatic zircons display the presence of reworked ancient crust with 1.1-1.8 Ga. These results provide strong constraints not only on the temporal range of the Late Triassic Nadigangri Formation, but also on the onset of the Qiangtang Mesozoic rift basin.

Attribution of the Langshan Tectonic Belt: Evidence from zircon U-Pb ages and Hf isotope compositions

This study describes a previously unidentified Neoproterozoic mafic dyke emplaced in the northern flank of the Langshan Tectonic Belt. This dyke intruded into the micaquartz schist of the Zhaertaishan Group, and yielded an age of 908 ± 8 Ma. The youngest U-Pb ages of micaquartz schist from the Zhaertaishan Group in the Langshan area were 1118 ± 33 Ma,1187 ± 3 Ma and 1189 ± 39 Ma,suggesting that the depositional age of the protolith of the schist was between 908 ± 8 Ma and 1118 ± 33 Ma. In addition, 436 U-Pb age data and 155 Lu-Hf isotopic data from six samples in the Langshan Tectonic Belt and one Permian greywacke from the Wuhai area show distinct differences between the northern and southern flanks of the Main Langshan area. The U-Pb ages of the northern flank are primarily Meso-Neoproterozoic; similar ages have not been identified in the southern flank to date.Moreover, two-stage Hf model ages of the northern flank feature three age peaks at ～900 Ma,～1700 Ma and ～2600 Ma; this differs from Hf model ages of the southern flank, which feature one strong age peak at ～2700 Ma. These results suggest that the northern and southern flanks of the Main Langshan area have different geochronologic characteristics and should be divided further. Based on the U-Pb ages and Hf model ages, the northern and southern flanks of the Main Langshan area are named the North and South Langshan Tectonic Belts. Comparison of the U-Pb age and two-stage Hf model age distributions from the North Langshan Tectonic Belt, South Langshan Tectonic Belt, Alxa Block and the North China Craton(NCC) reveal that the North Langshan Tectonic Belt is similar to the Alxa Block and that the South Langshan Tectonic Belt is similar to the NCC. In addition, the zircon U-Pb age of 860 ±7 Ma commonly observed in the Alxa Block was detected in the Permian greywacke from the Wuhai area of the NCC, which suggests that the amalgamation of the North and South Langshan Tectonic belts(i.e.,the amalgamation of the Alxa Block and the NCC), occurred between Devonian and late Permian.

A ca. 2.2Ga Acidic Magmatic Event at the Northern Margin of the Yangtze Craton: Evidence from U-Pb Dating and Hf Isotope Analysis of Zircons from the Kongling Complex

Objective The Yangtze craton collisional orogeny at ca. extensional events at ca. 1 experienced Paleoproterozoic 1.95-2.0 Ga and post-orogenic 85 Ga related to amalgamation of the Columbia （Nuna） supercontinent （Zhao and Cawood, 2012）. A ca. 2.15 Ga suprasubduction zone ophiolitic melange was recongized in the Archean- Paleoproterozoic Kongling Complex of the northern Yangtze craton （Han et al., 2017）. However, the tectonic evolution in early Paleoproterozoic from 2.4 Ga to 2.2 Ga remains unclear. We report here the presence of a suite of Paleoproterozoic （2.2 Ga） granites in the Huangling dome, northern Yangtze craton, which may provide important insights into crustal growth processes in the craton prior to the assembly of Columbia.