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普通铅对LA-ICP-MS磷灰石U-Pb定年结果的影响及校正方法
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作者 罗涛 王瀚林 +2 位作者 朱松柏 卿丽媛 胡兆初 《岩矿测试》 CAS 北大核心 2025年第1期51-62,共12页
磷灰石是火成岩、变质岩和沉积岩中广泛分布的含铀矿物,开展磷灰石U-Pb年代学研究对揭示岩浆演化过程、示踪溯源等方面具有重要意义。激光剥蚀电感耦合等离子体质谱法(LA-ICP-MS)是开展磷灰石U-Pb年龄微区分析的重要手段之一。当前,基... 磷灰石是火成岩、变质岩和沉积岩中广泛分布的含铀矿物,开展磷灰石U-Pb年代学研究对揭示岩浆演化过程、示踪溯源等方面具有重要意义。激光剥蚀电感耦合等离子体质谱法(LA-ICP-MS)是开展磷灰石U-Pb年龄微区分析的重要手段之一。当前,基体匹配磷灰石U-Pb定年矿物标样缺乏和标样中不可避免的普通铅是制约LA-ICP-MS高精度磷灰石U-Pb年龄分析的主要瓶颈。本文对比研究了标样中普通铅对LA-ICP-MS磷灰石U-Pb定年结果的影响,采用含普通铅的磷灰石MAD作外标直接开展U-Pb年龄校正,获得的被测样品年龄会产生显著的系统偏差(最大约6%);采用207Pb法或Tera-Wasserburg图解法先校正标样中普通铅,再利用校正后的数据进行元素分馏和仪器漂移校正则可获得准确的磷灰石U-Pb年龄,与推荐值偏差在2%以内。另一方面,为消除标样中普通铅对分析结果的影响,本文还采用水蒸气辅助激光剥蚀方法,实现以NIST612玻璃作为外标准确分析磷灰石U-Pb年龄,解决了磷灰石U-Pb定年微区分析高质量标样缺乏的难题。本研究通过对标样中普通铅进行预校正或采用非基体匹配分析,建立了高精度LA-ICP-MS磷灰石U-Pb定年新方法,将促进磷灰石U-Pb年代学在地球科学研究中的应用。 展开更多
关键词 激光剥蚀电感耦合等离子体质谱法 磷灰石 U-pb定年 普通铅校正 非基体匹配分析
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激光剥蚀-扇形磁场电感耦合等离子体质谱法同时测定锆石U-Pb年龄和微量元素含量 被引量:2
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作者 赵令浩 孙冬阳 +3 位作者 胡明月 袁继海 范晨子 詹秀春 《岩矿测试》 CAS CSCD 北大核心 2024年第1期47-62,共16页
激光剥蚀-扇形磁场电感耦合等离子体质谱(LA-SF-ICP-MS)具有高灵敏度特征,被广泛应用于锆石等含U矿物原位微区U-Pb定年研究,但磁偏转式质量分析器的使用导致该质谱仪扫描速度相对较慢,可能影响U-Pb同位素与其他关键微量元素的同时采集... 激光剥蚀-扇形磁场电感耦合等离子体质谱(LA-SF-ICP-MS)具有高灵敏度特征,被广泛应用于锆石等含U矿物原位微区U-Pb定年研究,但磁偏转式质量分析器的使用导致该质谱仪扫描速度相对较慢,可能影响U-Pb同位素与其他关键微量元素的同时采集。本文通过优化仪器信号稳定性和实验方法,对目前常用的7种锆石U-Pb标准样品进行U-Pb定年和Ti、REEs、Hf等关键元素同时定量分析,探讨了多元素同时分析方法的可行性及对于U-Pb定年结果的影响。实验结果表明,相对于LA-SF-ICP-MS仅检测U-Pb同位素方法,同时开展多元素含量检测可能会使U-Pb同位素信号强度稳定性下降,导致单点U-Pb年龄结果误差及离散程度增大。与仅测定U-Pb同位素年龄的测定结果相比较,根据不同锆石样品中U-Pb同位素含量高低,多元素同时检测获得分析点的206Pb/238U年龄和207Pb/235U年龄变化范围不同程度地增大,其中207Pb/235U年龄受影响明显,单点207Pb/235U年龄误差从~1.5%增大至~2.0%,单点年龄的相对标准偏差(RSD)从0.5%~1.3%增大至1.2%~3.3%。尽管如此,多元素同时检测方法对于各样品最终测定年龄没有明显的影响,相对于TIMS年龄,各样品的谐和年龄和206Pb/238U加权平均年龄偏差分别小于1.0%和0.7%,完全满足U-Pb同位素地质年代学测试要求。同时测定锆石样品中的关键微量元素含与其推荐值相对误差小于10%。因此,采用LA-SF-ICP-MS可以同时准确地测定锆石U-Pb年龄和微量元素含量,该方法亦可用于其他副矿物U-Pb年龄与关键微量元素同时测定。 展开更多
关键词 激光剥蚀-扇形磁场电感耦合等离子体质谱(LA-SF-ICP-MS) 锆石 U-pb定年 微量元素
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伟晶岩中不同副矿物U-Pb同位素定年和示踪的问题与应用 被引量:1
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作者 蒋少涌 张浩翔 +4 位作者 刘思祺 李雯恬 尹燕梁 车玉滢 苏慧敏 《地质学报》 EI CAS CSCD 北大核心 2024年第5期1573-1599,共27页
定年和示踪一直是伟晶岩成岩成矿过程和稀有金属富集机制研究的关键问题。副矿物不仅是伟晶岩中稀有稀土元素的重要载体,还蕴含丰富的微量元素并常常具有较高的U-Th含量,是研究伟晶岩年代学、成岩成矿过程和物质源区的“理想探针”。伟... 定年和示踪一直是伟晶岩成岩成矿过程和稀有金属富集机制研究的关键问题。副矿物不仅是伟晶岩中稀有稀土元素的重要载体,还蕴含丰富的微量元素并常常具有较高的U-Th含量,是研究伟晶岩年代学、成岩成矿过程和物质源区的“理想探针”。伟晶岩中常用的适合于U-Pb同位素定年的副矿物有锆石、铌钽铁矿、独居石、锡石、榍石、褐帘石、磷钇矿和磷灰石等。由于封闭温度、矿物学特性和不同性质流体中元素行为的差异,伟晶岩中不同副矿物的U-Pb系统常表现出复杂的年龄谱系,可能记录了伟晶岩中潜在的后期地质过程,如:自交代、后期变质与流体改造等。因此,基于前期光学显微镜、扫描电镜、冷阴极发光、激光拉曼光谱分析等矿物微观结构研究,对不同期次或世代的副矿物进行原位微区U-Pb定年及主微量元素和同位素地球化学分析,对于全面认知多期地质事件和伟晶岩成岩成矿过程演化历史,进而更准确地构建其构造-岩浆-热液-成矿作用时空框架具有重要的科学意义。 展开更多
关键词 伟晶岩 副矿物 U-pb同位素定年 地球化学示踪
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江西九岭南缘古阳寨地区铍矿化伟晶岩独居石U-Pb定年及其地质意义 被引量:1
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作者 徐喆 张福神 +6 位作者 张芳荣 张勇 周渝 徐进 黄成伟 贺彬 龙立学 《东华理工大学学报(自然科学版)》 CAS 北大核心 2024年第1期13-21,共9页
以江西九岭南缘古阳寨地区铍矿化伟晶岩为研究对象,选取规模较大的藏龙洞铍矿化伟晶岩脉,通过野外地质调查和LA-ICP-MS测定独居石U-Pb年龄测定,初步了解了九岭南缘古阳寨地区花岗伟晶岩地质特征。结果表明,九岭南缘古阳寨地区铍矿化伟... 以江西九岭南缘古阳寨地区铍矿化伟晶岩为研究对象,选取规模较大的藏龙洞铍矿化伟晶岩脉,通过野外地质调查和LA-ICP-MS测定独居石U-Pb年龄测定,初步了解了九岭南缘古阳寨地区花岗伟晶岩地质特征。结果表明,九岭南缘古阳寨地区铍矿化伟晶岩成岩成矿年龄为(138.57±0.78) Ma,归属于早白垩世。铍矿化伟晶岩侵入于九岭南缘古阳寨中细粒含斑二云母二长花岗岩体内部,形成时代略晚于燕山期古阳寨岩体,显示两者在空间和时间上具有密切的成因联系,推测古阳寨地区铍矿化伟晶岩为古阳寨岩体二云母二长花岗岩结晶分异而成。建议针对古阳寨二云母二长花岗岩体内部和外接触带0~5 km范围内,加强调查力度,以期实现该区域内伟晶岩型铍矿找矿突破。 展开更多
关键词 独居石U-pb定年 铍矿化伟晶岩 古阳寨地区 九岭南缘
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华北克拉通栖霞地区~2.9Ga变质基性火山岩锆石SHRIMP U-Pb定年、Hf-O同位素特征及构造意义
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作者 智云宝 李秀章 +5 位作者 孙斌 王立功 王巧云 戴广凯 赵西强 郭艳 《岩石学报》 SCIE EI CAS CSCD 北大核心 2024年第6期1907-1921,共15页
胶东地区是华北克拉通重要的早前寒武纪研究区之一。中太古代唐家庄岩群在形成时代、岩石成因及构造环境等方面一直少有研究。作者在栖霞地区对出露的唐家庄岩群变质表壳岩进行系统地质调查研究基础上,开展了变质基性火山岩全岩地球化... 胶东地区是华北克拉通重要的早前寒武纪研究区之一。中太古代唐家庄岩群在形成时代、岩石成因及构造环境等方面一直少有研究。作者在栖霞地区对出露的唐家庄岩群变质表壳岩进行系统地质调查研究基础上,开展了变质基性火山岩全岩地球化学、锆石SHRIMP U-Pb和Hf-O同位素等分析研究。结果显示,变质基性火山岩岩浆锆石年龄为2907.9±6.3Ma,代表了中太古代唐家庄岩群的形成时间,并遭受新太古代早、晚期变质作用。这是~2.9Ga唐家庄岩群变质基性火山岩在胶东地区首次报道。岩石地球化学特征表现为相对富集大离子亲石元素K、Rb、Sr等,Th、Nb、Zr、Hf等高场强元素相对亏损,具有中等分异的REE配分模式。岩石中岩浆锆石具有相似的Hf、O同位素组成,εHf(t)值介于-0.68~+4.21,δ18 O值介于1.38‰~6.73‰。结合前人的工作,我们得出的主要结论如下:(1)胶东地区经历~2.9Ga岩浆事件,局部地段仍保留下了同时期的变质表壳岩;(2)唐家庄岩群是中太古代初始的洋盆环境中所形成的一套火山-沉积建造;(3)华北克拉通中太古代晚期是亏损地幔新生地壳加积的主要时期,局部地壳再循环了较老的陆源物质;(4)华北克拉通新太古代晚期经历了伸展构造背景,岩浆底侵作用使岩石发生强烈变质作用。 展开更多
关键词 栖霞 变质基性火山岩 锆石SHRIMP U-pb定年 地球化学 构造意义
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甘肃合黎山古元古代花岗岩锆石U-Pb年龄、岩石地球化学特征及其对阿拉善地块南缘构造环境的约束
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作者 董国强 余君鹏 +2 位作者 吴义布 刘涛 张炜 《地质通报》 CAS CSCD 北大核心 2024年第10期1830-1840,共11页
分布于阿拉善地块南缘的龙首山岩群是金川镍矿的直接围岩,其形成时代和构造背景存在较大争议。在阿拉善地块南缘新发现的侵入于龙首山岩群的合黎山古元古代花岗岩体岩性为二长花岗岩、正长花岗岩及正长岩。岩石地球化学分析结果显示,合... 分布于阿拉善地块南缘的龙首山岩群是金川镍矿的直接围岩,其形成时代和构造背景存在较大争议。在阿拉善地块南缘新发现的侵入于龙首山岩群的合黎山古元古代花岗岩体岩性为二长花岗岩、正长花岗岩及正长岩。岩石地球化学分析结果显示,合黎山花岗岩Al_(2)O_(3)/(CaO+Na_(2)O+K_(2)O)值为0.91~1.06,K_(2)O/Na_(2)O为1.10~1.44,属钾质碱钙性花岗岩,岩石相对富集Rb、Ba、Th、K等大离子亲石元素,亏损Ta、Nb、P、Zr、Hf、Ti等高场强元素,具有弧岩浆的地球化学特征,形成于俯冲带岩浆弧构造环境。LA−ICP−MS锆石U−Pb测年结果表明,合黎山二长花岗岩的形成年龄为1859±12 Ma,侵位于古元古代晚期,揭示龙首山岩群变质地层的形成时代大于1.85 Ga,反映阿拉善地块南缘在古元古代晚期可能处于俯冲消减过程。 展开更多
关键词 花岗岩 锆石U-pb定年 古元古代 岩石地球化学 岩浆弧构造环境 阿拉善地块南缘
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鄂东北地区典型锰矿床锆石U-Pb年代学:对锰成矿时代的制约
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作者 刘锐 孙唯衡 +5 位作者 代吉祥 邹院兵 陈松 蒋之飞 刘兴平 杨振 《大地构造与成矿学》 EI CAS CSCD 北大核心 2024年第6期1286-1298,I0001-I0008,共21页
鄂东北地区黄麦岭组广泛发育沉积变质型锰矿床(如鹰咀山、四方山-团山沟和孙冲等锰矿床),含锰地层为一套片岩和大理岩组合,目前这些变质岩原岩的形成时代还不清楚。锰矿床赋矿地层沉积时代的确定对于该类矿床的成因研究有重要意义。本... 鄂东北地区黄麦岭组广泛发育沉积变质型锰矿床(如鹰咀山、四方山-团山沟和孙冲等锰矿床),含锰地层为一套片岩和大理岩组合,目前这些变质岩原岩的形成时代还不清楚。锰矿床赋矿地层沉积时代的确定对于该类矿床的成因研究有重要意义。本文对该区鹰咀山和团山沟锰矿床中的5件变(火山)沉积岩样品进行了LA-ICP-MS锆石U-Pb定年。结果表明,鹰咀山锰矿床2件含锰变沉积岩样品(绿泥石石英片岩17YZS04和硅质大理岩16YZS05)中最年轻的碎屑锆石年龄为687 Ma,代表了该区黄麦岭组的最大沉积年龄;团山沟锰矿床含锰变火山岩夹层中的绿片岩(TCK1-02)获得~650 Ma的原岩形成年龄,表明鄂东北地区锰沉积作用时间为~650 Ma。鹰咀山4件变沉积岩样品中碎屑锆石年龄峰值集中于0.68~0.80 Ga、~1.97 Ga和~2.45 Ga,表明黄麦岭组沉积物源主要为古元古代和新元古代物质。年龄对比研究显示,大悟-红安地区在新元古代应为扬子克拉通的一部分,扬子北缘也可能广泛发育古元古代基底。鄂东北地区锰矿成矿时代(~650 Ma)与扬子东南缘湘黔渝地区新元古代大规模锰成矿作用时间几乎一致,表明前者亦可能为Sturtian-Marinoan间冰期沉积的产物。该期锰沉积事件可能与Rodinia超大陆裂解在扬子北缘形成的浅海相沉积有关。 展开更多
关键词 锰矿床 变(火山)沉积岩 碎屑锆石 锆石U-pb定年 鄂东北
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江苏沉积变质型磷矿带含磷岩系LA-ICP-MS锆石U-Pb年龄及其地质意义
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作者 陈冬 胡森林 +2 位作者 缪柏虎 关俊朋 孙清钟 《矿产勘查》 2024年第2期190-198,共9页
江苏沉积变质型磷矿带位于大别—苏鲁造山带东段,锦屏岩组是带内唯一赋矿地层,因其遭受过多期强烈的变形变质作用改造,层序杂乱,勘查难度大,研究程度低,目前其形成时代尚无定论。本文应用LAICP-MS锆石U-Pb定年方法,对锦屏岩组各类岩性... 江苏沉积变质型磷矿带位于大别—苏鲁造山带东段,锦屏岩组是带内唯一赋矿地层,因其遭受过多期强烈的变形变质作用改造,层序杂乱,勘查难度大,研究程度低,目前其形成时代尚无定论。本文应用LAICP-MS锆石U-Pb定年方法,对锦屏岩组各类岩性进行测试,获得绿色片岩类岩石原岩年龄为(956±7)Ma~(691±14)Ma,浅色片岩类岩石原岩年龄不早于(833±39)Ma,片麻岩类岩石原岩年龄不早于(772±31)Ma。结合成矿带内含磷岩系中古生物化石资料,将锦屏岩组原岩形成时代界定为新元古代,将磷矿原始沉积时间限定在震旦纪,为江苏磷矿勘查与研究提供了新的基础资料。 展开更多
关键词 沉积变质型磷矿床 锆石U-pb定年 大别—苏鲁造山带 江苏省
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青海大柴旦塔温查干哈达顶志留世花岗岩岩石地球化学和U⁃Pb同位素约束
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作者 马国杰 《资源信息与工程》 2024年第3期10-13,共4页
青海大柴旦塔温查干哈达顶志留世花岗岩位于宗务隆山断裂以南,主体为花岗斑岩、粗粒似斑状二长花岗岩。岩石SiO_(2)质量分数为67.11%~73.73%,Al_(2)O_(3)质量分数为13.62%~14.57%,K_(2)O和Na_(2)O质量分数比为1.11~1.96,具有偏铝质高钾... 青海大柴旦塔温查干哈达顶志留世花岗岩位于宗务隆山断裂以南,主体为花岗斑岩、粗粒似斑状二长花岗岩。岩石SiO_(2)质量分数为67.11%~73.73%,Al_(2)O_(3)质量分数为13.62%~14.57%,K_(2)O和Na_(2)O质量分数比为1.11~1.96,具有偏铝质高钾钙碱性系列岩石的特征。U⁃Pb年龄测试花岗斑岩的结晶年龄为(417.9±3.9)Ma,表明形成地质时期为顶志留世,属加里东期构造岩浆岩带。岩石地球化学分析认为,塔温查干哈达侵入岩属板内花岗岩类,可能为I⁃S型花岗岩,该期侵入岩属同碰撞构造前环境。岩浆活动总趋势由深到浅发展,随时间推移岩浆房逐渐趋近于地表。 展开更多
关键词 花岗岩 岩石地球化学 U⁃pb测年 大柴旦
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柴北缘孤山一带侵入岩U-Pb年代学约束及构造环境特征
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作者 马国杰 《资源信息与工程》 2024年第2期1-4,共4页
研究区位于祁连山脉南西部,岩体呈不规则的残块状、条带状混杂侵入于早元古代达肯大坂群中—深变质岩中,现已变质为中细粒二云花岗片麻岩。岩石中TiO_(2)质量分数为0.61%,Al_(2)O_(3)质量分数为12.5%,Na_(2)O和K_(2)O质量分数共7.43%,Fe... 研究区位于祁连山脉南西部,岩体呈不规则的残块状、条带状混杂侵入于早元古代达肯大坂群中—深变质岩中,现已变质为中细粒二云花岗片麻岩。岩石中TiO_(2)质量分数为0.61%,Al_(2)O_(3)质量分数为12.5%,Na_(2)O和K_(2)O质量分数共7.43%,Fe_(2)O_(3)质量分数为0.94%,具有高Ti、Al、Fe和富钾的特征。锆石U-Pb加权平均值为766.1 Ma±5.4 Ma,侵位于新元古代南华纪。侵位方式为被动的岩墙扩张,为火山弧型花岗岩,形成于同碰撞构造环境,可能为I-S型花岗岩。 展开更多
关键词 柴北缘 花岗岩 岩石地球化学 U-pb测年
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Timing of carbonatite-hosted U-polymetallic mineralization in the supergiant Huayangchuan deposit,Qinling Orogen:Constraints from titanite U-Pb and molybdenite Re-Os dating 被引量:10
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作者 Hui Zheng Huayong Chen +3 位作者 Dengfeng Li Chao Wu Xi Chen Chun-kit Lai 《Geoscience Frontiers》 SCIE CAS CSCD 2020年第5期1581-1592,共12页
The newly-discovered supergiant Huayangchuan uranium(U)-polymetallic(Sr,Se,REEs,Ba,Nb and Pb)deposit is located in the Qinling Orogen,central China.The deposit underwent multistage mineralization,with the main carbona... The newly-discovered supergiant Huayangchuan uranium(U)-polymetallic(Sr,Se,REEs,Ba,Nb and Pb)deposit is located in the Qinling Orogen,central China.The deposit underwent multistage mineralization,with the main carbonatite ore stage being the most important for the U,Nb,REE,Sr and Ba endowments.According to the mineral assemblages,the main carbonatite ore stage can be divided into three substages,i.e.,sulfate(Ba-Sr),alkali-rich U and REE-U mineralization.Main-stage titanite from the Huayangchuan igneous carbonatite are rich in high field strength elements(HFSEs,e.g.,Zr,Nb and REEs),and show clear elemental substitutions(e.g.,Ti vs.Nb+Fe+Al and Ca+Ti vs.Fe+Al+REE).High-precision LA-ICP-MS titanite dating yielded a U-Pb age of 209.0±2.9 Ma,which represents the mainstage mineralization age at Huayangchuan,and is coeval with the local carbonatite dyke intrusion.This mineralization age is further constrained by the Re-Os dating of molybdenite from the Huayangchuan carbonatite,which yielded a weighted mean age of 196.8±2.4 Ma.Molybdenite Re contents(337.55-392.75 ppm)and C-OSr-Nd-Pb isotopic evidence of the Huayangchuan carbonatite both suggest a mantle origin for the carbonatite.Our study supports that the Late Triassic carbonatite magmatism was responsible for the world-class U-Mo-REE mineralization in the Qinling Orogen,and that the regional magmatism and ore formation was likely caused by the closure of the Mianlue ocean and the subsequent North China-South China continent-continent collision. 展开更多
关键词 Carbonatite-hosted U-Polymetallic deposits Titanite U–pb dating Molybdenite Re–Os dating Huayangchuan deposit Qinling orogen
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Geochronology and Genetic Model for Early Cretaceous Volcanic Rocks from the Southern Qiangtang Terrane,Northern Tibet,China: Constraints from U-Pb Zircon Dating, Whole-Rock Geochemical and Sr-Nd Isotopic Data 被引量:2
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作者 LIU Shen FENG Caixia +6 位作者 M.Santosh FENG Guangying XU Mengjing Ian M.COULSON GUO Xiaolei GUO Zhuang FAN Yan 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2018年第6期2157-2178,共22页
Post-collisional volcanic rocks of Mesozoic age occur in the regions adjacent to Gerze, part of the southern Qiangtang Terrane of northern Tibet, China. Geochronological, geochemical, and wholerock Sr-Nd isotopic anal... Post-collisional volcanic rocks of Mesozoic age occur in the regions adjacent to Gerze, part of the southern Qiangtang Terrane of northern Tibet, China. Geochronological, geochemical, and wholerock Sr-Nd isotopic analyses were performed on the volcanic rocks to better characterize their emplacement age and models for their origin. Laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS) U-Pb zircon analyses yielded consistent ages ranging from 123.1±0.94 Ma to 124.5±0.89 Ma for six volcanic rocks from the study area. The intermediate volcanic rocks belong to the alkaline and sub-alkaline magma series in terms of K2 O+Na2 O contents(5.9%–9.0%), and to the shoshonitic and calc-alkaline series on the basis of their high K2 O contents(1.4%–3.3%). The Gerze volcanic rocks are characterized by the enrichment of light rare earth elements [(La/Yb)N=34.9–49.5] and large–ion lithophile elements(e.g., Rb, Ba, Th, U, K, Pb, and Sr), slightly negative Eu anomalies(Eu/Eu*=0.19–0.24), and negative anomalies in high field strength elements(e.g., Nb, Ta, Hf and Ti), relative to primitive mantle. The samples show slightly elevated(87 Sr/86 Sr)i values that range from 0.7049 to 0.7057, and low εNd(t) values from-0.89 to-2.89. These results suggest that the volcanic rocks studied derived from a compositionally heterogeneous mantle source and that their parent magmas were basaltic. The more mafic, parental magmas to the Gerze volcanic rocks likely underwent fractional crystallization of clinopyroxene, hornblende, biotite, and potassium feldspar, during ascent, with little to no crustal contamination, prior to their eruption/emplacement. While these volcanic rocks exhibit geochemical signatures typical of magmas formed in a destructive plate-margin setting, it is plausible that their mantle source might also have acquired such characteristics in an earlier episode of subduction. 展开更多
关键词 volcanic rock U–pb age–dating origin Qiangtang Terrane northern Tibet
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西秦岭郎木寺组火山岩锆石U-Pb年龄及其构造意义 被引量:6
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作者 冉亚洲 陈涛 +3 位作者 梁文天 李阳 申琪 李传志 《西北地质》 CSCD 北大核心 2024年第1期110-121,共12页
西秦岭郎木寺地区发育了大量的火山岩,是探讨秦岭造山带印支期岩浆作用的重要窗口。目前,关于郎木寺组火山岩的形成时代尚未有很好的约束。据此,笔者对郎木寺组角闪安山岩开展了详细的LA-ICP-MS锆石U-Pb年代学研究。CL图像显示,郎木寺... 西秦岭郎木寺地区发育了大量的火山岩,是探讨秦岭造山带印支期岩浆作用的重要窗口。目前,关于郎木寺组火山岩的形成时代尚未有很好的约束。据此,笔者对郎木寺组角闪安山岩开展了详细的LA-ICP-MS锆石U-Pb年代学研究。CL图像显示,郎木寺组角闪安山岩的锆石结构表现出典型的岩浆成因特征。锆石U-Pb定年结果显示,角闪安山岩具略有差异的两组年龄,加权平均年龄分别为(221.8±1.2)Ma和(210.6±2.1)Ma。因此,郎木寺组角闪安山岩的形成时代为晚三叠世。结合前人已有成果,笔者认为郎木寺组火山岩代表了秦岭印支期造山作用重要的岩浆事件产物,形成于同碰撞挤压的构造环境。 展开更多
关键词 郎木寺组 角闪安山岩 锆石U-pb定年 构造环境 秦岭造山带
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Geochronologic Constraints on the Magmatic Underplating of the Gangdisê Belt in the India-Eurasia Collision: Evidence of SHRIMP II Zircon U-Pb Dating 被引量:53
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作者 DONG Guochen MO Xuanxue +3 位作者 ZHAO Zhidan GUO Tieying WANG Liangliang CHEN Tao 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2005年第6期787-794,共8页
Abundant small mafic intrusions occur associated with granitoids along the Gangdise^ magmatic belt. In addition to many discrete gabbro bodies within the granitoid plutons, a gabbro-pyroxenite zone occurs along the so... Abundant small mafic intrusions occur associated with granitoids along the Gangdise^ magmatic belt. In addition to many discrete gabbro bodies within the granitoid plutons, a gabbro-pyroxenite zone occurs along the southern margin of the Gangdise^ belt to the north of the Yarlung Zangbo suture. The mafic intrusion zone spatially corresponds to a strong aeromagnetic anomaly, which extends -1400 km. The mafic intrusions consist of intermittently distributed small bodies and dikes of gabbro and dolerite with accumulates of pyroxenite, olivine pyroxenite, pegmatitic pyroxenite and amphibolite. Much evidence indicates that the Gangdise^ gabbro-pyroxenite assemblage is most likely a result of underplating of mantle-derived magma. Detailed field investigation and systematic sampling of the mafic rocks was conducted at six locations along the Lhasa-Xigaze^ segment of the mafic intrusive zone, and was followed by zircon SHRIMP Ⅱ U-Pb dating. In addition to the ages of two samples previously published (47.0±1 Ma and 48.9±1.1 Ma), the isotopic ages of the remaining four gabbro samples are 51.6±1.3Ma, 52.5±3.0 Ma, 50.2±4.2Ma and 49.9±1.1Ma. The range of these ages (47-52.5 Ma) provide geochronologic constraints on the Eocene timing of magma underplating beneath the Gangdise^ belt at ca. 50 Ma. This underplating event post-dated the initiation of the India-Eurasia continental collision by 15 million years and was contemporaneous with a process of magma mixing. The SHRIMP Ⅱ U-Pb isotopic analysis also found several old ages from a few zircon grains, mostly in a range of 479-526 Ma (weighted average age 503±10 Ma), thus yielding information about the pre-existing lower crust when underplating of mafic magma took place. It is believed that magma underplating was one of the major mechanisms for crustal growth during the Indian-Eurasia collision, possibly corresponding in time to the formation of the 14-16 km-thick "crnst-mantle transitional zone" characterized by Vp=6.85-6.9 km/s. 展开更多
关键词 SHRIMP U-pb dating mafic intrusion GABBRO UNDERPLATING the Gangdise^ Tibet
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Chronology and Sources of Mesozoic Intrusive Complexes in the Xuzhou-Huainan Region, Central China: Constraints from SHRIMP Zircon U-Pb Dating 被引量:47
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作者 XUWenliang WANGQinghai +2 位作者 LIUXiaochun WANGDongyan GUOJinghui 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2004年第1期96-106,共11页
SHRIMP zircon U-Pb dating in the Liguo and Jiagou intrusives indicates that they were formed at -130 Ma in the Early Cretaceous. Most inherited zircons in the Liguo intrusive were formed at 2509±43 Ma. Most inher... SHRIMP zircon U-Pb dating in the Liguo and Jiagou intrusives indicates that they were formed at -130 Ma in the Early Cretaceous. Most inherited zircons in the Liguo intrusive were formed at 2509±43 Ma. Most inherited and detrital zircons in the Jiagou intrusive were formed at -2500 Ma, -2000 Ma and -1800 Ma. The SHRIMP zircon U-Pb dating in two gneiss xenoliths from the Jiagou intrusive yields the ages of 2461±22 Ma and 2508±15 Ma, respectively. The dating results from inherited and detrital zircons in the intrusives and the gneiss xenoliths imply that the magmas could be derived from the partial melting of the basement of the North China Block (NCB). The magmatism is strong and extensive in the periods from 115 to 132 Ma, which is of typical bimodal characteristics. It is suggested that the lithospheric thinning in the eastern North China Block reached its peak in 115-132 Ma. 展开更多
关键词 MESOZOIC intrusive complex zircon U-pb dating source of magma Xuzhou-Huainana region China
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Geological Characteristics and Zircon U-Pb Dating of Volcanic Rocks from the Beizhan Iron Deposit in Western Tianshan Mountains, Xinjiang, NW China 被引量:32
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作者 ZHANG Zuoheng HONG Wei +5 位作者 JIANG Zongsheng DUAN Shigang XU Lingang LI Fengming GUO Xincheng ZHAO Zhengang 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2012年第3期737-747,共11页
The Beizhan large iron deposit located in the east part of the Awulale metallogenic belt in the western Tianshan Mountains is hosted in the Unit 2 of the Dahalajunshan Formation as lens, veinlets and stratoid, and bot... The Beizhan large iron deposit located in the east part of the Awulale metallogenic belt in the western Tianshan Mountains is hosted in the Unit 2 of the Dahalajunshan Formation as lens, veinlets and stratoid, and both of the hanging wall and footwall are quartz-monzonite; the dip is to the north with thick and high-grade ore bodies downwards. Ore minerals are mainly magnetite with minor sulfides, such as pyrite, pyrrhotite, chalcopyrite and sphalerite. Skarnization is widespread around the ore bodies, and garnet, diopside, wollastonite, actinolite, epidote, uralite, tourmaline sericite and calcite are ubiquitous as gangues. Radiating outwards from the center of the ore body the deposit can be classified into skarn, calcite, serpentinite and marble zones. LA-ICP-MS zircon U-Pb dating of the rhyolite and dacite from the Dahalajunshan Formation indicates that they were formed at 301.3±0.8 Ma and 303.7±0.9 Ma, respectively, which might have been related to the continental arc magmatism during the late stage of subduction in the western Tianshan Mountains. Iron formation is genetically related with volcanic eruption during this interval. The Dahalajunshan Formation and the quartz-monzonite intrusion jointly control the distribution of ore bodies. Both ore textures and wall rock alteration indicate that the Beizhan iron deposit is probably skarn type. 展开更多
关键词 iron ore Zircon U-pb dating SKARNIZATION Beizhan Western Tianshan Mountains
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U-Th-Pb behavior of zircons under high-grade metamorphic conditions:A case study of zircon dating of meta-diorite near Qixia,eastern Shandong 被引量:27
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作者 Yusheng Wan Dunyi Liu +2 位作者 Chunyan Dong Shoujie Liu Shijin Wang 《Geoscience Frontiers》 SCIE CAS 2011年第2期137-146,共10页
This paper carried out a study on U--Th--Pb behavior of zircons in a "dry" rock system during high-grade metamorphism in the Archean basement of eastern Sbandong. The studied sample has a mineral assemblage of plagi... This paper carried out a study on U--Th--Pb behavior of zircons in a "dry" rock system during high-grade metamorphism in the Archean basement of eastern Sbandong. The studied sample has a mineral assemblage of plagioclase + K-feldspar + clinopyroxene + biotite + quartz and its pro- tolith is considered to be diorite. The zircons are stubby, equant or irregular in shape and show fir-leaf, sectorial, banded or oscillatory zoning. They contain inclusions, including mineral assemblages of clinopyroxene + orthopyroxene + hornblende + quartz and plagioclase + K-feldspar + biotite + quartz. Fifty SHRIMP analyses were performed on 34 zircon grains, which commonly yielded high Th/U ratios (mostly 〉0.5). Most analyses are distributed along concordia from 2.54 to 2.25 Ga, with the youngest age being - 1.95 Ga. Compositions and ages show large variations even in a same zircon grain. Combined with early studies, conclusions can be drawn as follows: 1) the diorite underwent two episodes of high-grade metamorphism, at the end of the Neoarchean and the Paleoproterozoic (-2.50 Ga and 1.95 Ga or slightly later); 2) high-grade metamorphism in a "dry" rock system may partially reset the U--Th--Pb system of zircons and, in this case, the ages between the oldest and youngest are chronologically meaningless; and 3) high Th/U ratios may be common features of zircons formed during high-grade metamorphic conditions. 展开更多
关键词 Zirco/Is U-Th--pb systemReset High-grademetamorphism SHRIMP dating Early Precambrian
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Zircon U-Pb Dating on Granitoids from the Northern South China Sea and its Geotectonic Relevance 被引量:15
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作者 SHI Hesheng XU Changhai +1 位作者 ZHOU Zuyi MA Changqian 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2011年第6期1359-1372,共14页
Zircon U-Pb ages of 163.8-100.4 Ma and 146.6-134.5 Ma are obtained for the granitoids from the Pearl River mouth basin, and from southern Guangdong Province, respectively. These new dating data accord well with the cr... Zircon U-Pb ages of 163.8-100.4 Ma and 146.6-134.5 Ma are obtained for the granitoids from the Pearl River mouth basin, and from southern Guangdong Province, respectively. These new dating data accord well with the crystallization ages of Yanshanian granitoids broadly in the Nanling. The active continental margin of South China, as revealed by a combination of zircon U-Pb data, underwent a key granitoid-dominated magmatism in 165-100 Ma. Its evolution varied temporally, and spatially, registering under control of the paleo-Pacific slab subduction. The granitoids that occurred in 165-150 Ma broadly from the South China Sea to the Nanling are preferably related to two settings from volcanic-arc to back-arc extension, respectively. The activities of Cretaceous granitoids migrated from the southeastern Guangdong (148-130 Ma) to the Pearl River Mouth basin (127-112 Ma), corresponding to the model of a retreating subduction. The subduction-related granitoid magmatism in South China continued until 108-97 Ma. A tectonic transformation from slab-subduction to extension should occur at -100 Ma. 展开更多
关键词 GRANITOID zircon U-pb dating active continental margin South China
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An Important Spreading Event of the Neo-Tethys Ocean during the Late Jurassic and Early Cretaceous: Evidence from Zircon U-Pb SHRIMP Dating on Diabase in Nagarze, Southern Tibet 被引量:27
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作者 JIANG Sihong NIE Fengjun HU Peng LIU Yan 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2006年第4期522-527,共6页
Widely distributed in Gyangzê-Chigu area, southern Tibet, NW- and nearly E-W-trending diabase(gabbro)-gabbro diorite dykes are regarded as the product of the large-scale spreading of the late Neo-Tethys Ocean. ... Widely distributed in Gyangzê-Chigu area, southern Tibet, NW- and nearly E-W-trending diabase(gabbro)-gabbro diorite dykes are regarded as the product of the large-scale spreading of the late Neo-Tethys Ocean. In order to constrain the emplacement age of these dykes, zircons of two samples from diabases in Nagarzê were dated by using the U-Pb SHRIMP method. Two nearly the same weighted mean ^206pb/^23SU ages were obtained in this paper, which are 134.9±1.8 Ma (MSWD=0.65) and 135.5 ± 2.1 Ma (MSWD=1.40), respectively. They not only represent the crystallization age of the diabase, but also documented an important spreading event of the Neo-Tethys Ocean during the late Jurassic and early Cretaceous. This dating result is of great significance to reconstruct the temporal framework of the late Neo-Tethys Ocean in the Qinghai-Tibet Plateau. 展开更多
关键词 DIABASE zircon U-pb SHRIMP dating spreading event NEO-TETHYS Nagarzê southern Tibet
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LA-ICP-MS U-Pb zircon dating of the Bozhushan granite in Southeast Yunnan 被引量:5
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作者 LI Kaiwen ZHANG Qian +2 位作者 WANG Dapeng CAI Yi LIU Yuping 《Chinese Journal Of Geochemistry》 EI CAS CSCD 2013年第2期170-180,共11页
The LA-ICP-MS U-Pb zircon dating of eight typical samples from four units of the Bozhushan granite intrusion in southeastern Yunnan Province, constrains the age of acidic magmatic intrusion in this area. Both the osci... The LA-ICP-MS U-Pb zircon dating of eight typical samples from four units of the Bozhushan granite intrusion in southeastern Yunnan Province, constrains the age of acidic magmatic intrusion in this area. Both the oscillatory zoning and chondrite-normalized REE patterns characterized by LREE-depletion and HREE-enrichment with positive Ce anomaly and negative Eu anomaly indicate the magmatic genesis of these zircons. Eight zircon samples from the Bozhushan granite yielded a mean 206 Pb/ 238 U age of (85.58±1.0) Ma (MSWD=4.1) to (88.10±0.66) Ma (MSWD=1.8). These chronology data suggest an accurate isotopic age for the intrusion of the Bozhushan granite, and are different from the published age data of 48 to 111.5 Ma. The geochronology data of the Gejiu, Dulong and Dachang super-large deposits and related Yanshanian granites indicated that there occurred large-scale granitic magmatism and mineralization events in western Nanling region during the Late Cretaceous. 展开更多
关键词 U-pb同位素定年 LA-ICP-MS 燕山期花岗岩 锆石 滇东南 同位素年龄 典型样本 稀土富集
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