A new zinc hydrogen phosphite C4H8N2H4·Zn（HPO3）2 was prepared by hydrothermal method in the presence of piperazine as a structure-directing agent and the crystal structure was determined by single-crystal X-ray...A new zinc hydrogen phosphite C4H8N2H4·Zn（HPO3）2 was prepared by hydrothermal method in the presence of piperazine as a structure-directing agent and the crystal structure was determined by single-crystal X-ray diffraction analysis and further characterized by X-ray powder diffraction, IR, ICP, elemental analysis and TG analysis. This compound has one-dimensional anionic chains containing four-membered rings built from corner-sharing linked alternating ZnO4 tetrahedra and HPO3 pseudo pyramids. The zinc hydrogen phosphite chains are interacted with the templates of diprotonated piperazine by N—H…O hydrogen bond. Crystal data for C4H8N2H4·Zn（HPO3）2∶monoclinic, space group C2/c. a=1.774 8（2） nm, b=0.724 28（9） nm, c=0.880 87（11） nm, β= 105.345（3）°, V=1.091 9（2） nm 3, Z=4, Dc=1^907 Mg/m 3, R1=0.022 9, wR2=0.058 8.展开更多
Using THF and water as solvent, piperazine as a template, a novel two dimensional layered zinc phosphate 1.5[Zn2(PO4)(HPO4)2]·H2O has been prepared solvothermally, and its structure is determined at 293K by Sieme...Using THF and water as solvent, piperazine as a template, a novel two dimensional layered zinc phosphate 1.5[Zn2(PO4)(HPO4)2]·H2O has been prepared solvothermally, and its structure is determined at 293K by Siemens Smart 1000 CCD diffractometer monoclinic, P21/c, a=0.81244(3)nm, b=2.61706(12)nm, c=0.83775(3)nm, β=110.981(2)°, V=1.66313(11)nm3, Z=4, R=0.0285, wR=0.0719. The structure con sists of vertex sharing ZnO4, HPO4, and PO4 tetrahedra, and double protonated organic cations, which results in formation of undulating 4 ring chains and 12 ring sheets. A network of hydrogen bonds involving both layer to layer and layer to amine interaction holds the phosphate layer together. CCDC: 200374.展开更多
The title complex was prepared from self-assembly reaction of La（NO3）3(6H2O, Zn（NO3）2(6H2O, m-cyanobenzoic acid （m-CNC6H4COOH） and pyridine （Py） in refluxing ethanol and its structure was determined by single-...The title complex was prepared from self-assembly reaction of La（NO3）3(6H2O, Zn（NO3）2(6H2O, m-cyanobenzoic acid （m-CNC6H4COOH） and pyridine （Py） in refluxing ethanol and its structure was determined by single-crystal X-ray diffraction. Crystallographic data: C94H62N12La2O22Zn2, Mr = 2120.12, triclinic space group P, a = 13.2219（5）, b = 13.2713（5）, c = 14.1987（6） ?, (???69.156（1）, ( = 84.034（1）, ( = 89.400（1） (, V = 2314.9（2） ?3, Z = 1, Dc = 1.521 g/cm3, F（000） = 1060, ( (MoK（） = 14.94 cm－1, the final R = 0.043 and wR = 0.117 for 6381 unique reflections with I > 2(（I）. Crystal structure determination shows that the neighboring lanthanum（III） and zinc（II） ions are bridged by three bidentate m-cyanobenzonate ligands in the syn-syn fashion to form a pair of dinuclear [LaZn（m-CNC6H4COO）3（Py）（C2H5OH）] subunits, being linked together by two bidentate and two tridentate m-cyanobenzonate groups in the syn-syn and syn-anti modes, respectively, to construct a tetranuclear La-Zn complex [La2Zn2（m-CNC6H4COO）10（Py）2（C2H5OH）2].展开更多
The zinc 3-hydroxy-2-mercaptopyridine complex was prepared by self-assemby reaction of Zn(NO3)2 and 3-hydroxy-2-mercaptopyridine (hmp). Single-crystal X-ray diffraction analysis indicates that it crystallizes in a tet...The zinc 3-hydroxy-2-mercaptopyridine complex was prepared by self-assemby reaction of Zn(NO3)2 and 3-hydroxy-2-mercaptopyridine (hmp). Single-crystal X-ray diffraction analysis indicates that it crystallizes in a tetragonal system, space group (No. 122) with a = 13.4562(6), c = 13.6860(8) , V = 2478.1(2) 3, Z = 8, Mr = 317.67, Dc = 1.703 g/cm3, m(Mo-Ka) = 2.308 mm-1 and F(000) = 1280. R = 0.0289 and wR = 0.0676 for 1040 observed reflections (I > 2s(I)). The crystal structure consists of a neutral molecule with a distorted tetrahedral cis-ZnS2O2 core, in which the mononuclear Zn2+ ion is coordinated by two O and two S atoms from two hmp ligands with the average bond distances of 2.301(1) ?for ZnS and 1.986(3) ?for ZnO. The 1H . NMR and IR spectra of the compound are discussed.展开更多
Low-temperature heat capacities of the solid compound Zn（C4H7O5）2（s） were measured in a temperature range from 78 to 374 K, with an automated adiabatic calorimeter. A solid-to-solid phase transition occurred in th...Low-temperature heat capacities of the solid compound Zn（C4H7O5）2（s） were measured in a temperature range from 78 to 374 K, with an automated adiabatic calorimeter. A solid-to-solid phase transition occurred in the temperature range of 295？322 K. The peak temperature, the enthalpy, and entropy of the phase transition were determined to be （316.269±1.039） K, （11.194±0.335） kJ？mol-1, and （35.391±0.654） J？K-1？mol-1, respectively. The experimental values of the molar heat capacities in the temperature regions of 78？295 K and 322？374 K were fitted to two polynomial equations of heat capacities（Cp,m） with reduced temperatures（X） and [X = f（T）], with the help of the least squares method, respectively. The smoothed molar heat capacities and thermodynamic functions of the compound, relative to that of the standard reference temperature 293.15 K, were calculated on the basis of the fitted polynomials and tabulated with an interval of 5 K. In addition, the possible mechanism of thermal decomposition of the compound was inferred by the result of TG-DTG analysis.展开更多
The space group of [(H2O)(C3H4N2)(O2CCH=CHCO2Zn)]n, which was originally described in the acentric Pc space group (Liu et al., Chin. J. Struct. Chem. 2004, 23, 160～163), is re-described in the centric P21/c space g...The space group of [(H2O)(C3H4N2)(O2CCH=CHCO2Zn)]n, which was originally described in the acentric Pc space group (Liu et al., Chin. J. Struct. Chem. 2004, 23, 160～163), is re-described in the centric P21/c space group.展开更多
The anode material Zn4SO4（OH）6·5H2O for nickle/zinc batteries was synthesized by hydrothermal method and was identified by XRD techniques. TG/DAT measurements reveal that the products lose lattice water at 145 ...The anode material Zn4SO4（OH）6·5H2O for nickle/zinc batteries was synthesized by hydrothermal method and was identified by XRD techniques. TG/DAT measurements reveal that the products lose lattice water at 145 ℃ and decompose to 3ZnO·ZnSO4 at 274 ℃. Cyclic voltammetry and recharging/discharging results show that CV curves have good symmetry, the ratio of oxidation area to reduction area for each curve is about 1, and the peak potential EPa and EPc have little change with the scanning rate. At 50th circle, more than 65% of theoretical capacity is obtained while at the same condition, zinc oxide electrode only remains 35% of theoretical capacity.展开更多
A novel coordination polymer, [Fe(C 5H 4NCOO) 2] n, was synthesized by hydrothermal reaction and characterized by elemental analysis as well as IR spectroscopy. The crystal structure (with a novel 3-D network) of this...A novel coordination polymer, [Fe(C 5H 4NCOO) 2] n, was synthesized by hydrothermal reaction and characterized by elemental analysis as well as IR spectroscopy. The crystal structure (with a novel 3-D network) of this compound belongs to monoclinic, space group P2 1/n, a=0.49544(1) nm, b=1.32443(2) nm, c=1.04983(1) nm, β=101.586(1)°. The diffuse reflectance spectra (200～2500 nm) showed that the polymer had strong absorbance in 375～563 nm (E g≈2.5 eV) region and weak absorbance from 720 to 2500 nm (near infrared spectra).展开更多
文摘A new zinc hydrogen phosphite C4H8N2H4·Zn（HPO3）2 was prepared by hydrothermal method in the presence of piperazine as a structure-directing agent and the crystal structure was determined by single-crystal X-ray diffraction analysis and further characterized by X-ray powder diffraction, IR, ICP, elemental analysis and TG analysis. This compound has one-dimensional anionic chains containing four-membered rings built from corner-sharing linked alternating ZnO4 tetrahedra and HPO3 pseudo pyramids. The zinc hydrogen phosphite chains are interacted with the templates of diprotonated piperazine by N—H…O hydrogen bond. Crystal data for C4H8N2H4·Zn（HPO3）2∶monoclinic, space group C2/c. a=1.774 8（2） nm, b=0.724 28（9） nm, c=0.880 87（11） nm, β= 105.345（3）°, V=1.091 9（2） nm 3, Z=4, Dc=1^907 Mg/m 3, R1=0.022 9, wR2=0.058 8.
文摘Using THF and water as solvent, piperazine as a template, a novel two dimensional layered zinc phosphate 1.5[Zn2(PO4)(HPO4)2]·H2O has been prepared solvothermally, and its structure is determined at 293K by Siemens Smart 1000 CCD diffractometer monoclinic, P21/c, a=0.81244(3)nm, b=2.61706(12)nm, c=0.83775(3)nm, β=110.981(2)°, V=1.66313(11)nm3, Z=4, R=0.0285, wR=0.0719. The structure con sists of vertex sharing ZnO4, HPO4, and PO4 tetrahedra, and double protonated organic cations, which results in formation of undulating 4 ring chains and 12 ring sheets. A network of hydrogen bonds involving both layer to layer and layer to amine interaction holds the phosphate layer together. CCDC: 200374.
基金the Natural Science Foundation of China, Fujian Province and Chinese Academy of Sciences.
文摘The title complex was prepared from self-assembly reaction of La（NO3）3(6H2O, Zn（NO3）2(6H2O, m-cyanobenzoic acid （m-CNC6H4COOH） and pyridine （Py） in refluxing ethanol and its structure was determined by single-crystal X-ray diffraction. Crystallographic data: C94H62N12La2O22Zn2, Mr = 2120.12, triclinic space group P, a = 13.2219（5）, b = 13.2713（5）, c = 14.1987（6） ?, (???69.156（1）, ( = 84.034（1）, ( = 89.400（1） (, V = 2314.9（2） ?3, Z = 1, Dc = 1.521 g/cm3, F（000） = 1060, ( (MoK（） = 14.94 cm－1, the final R = 0.043 and wR = 0.117 for 6381 unique reflections with I > 2(（I）. Crystal structure determination shows that the neighboring lanthanum（III） and zinc（II） ions are bridged by three bidentate m-cyanobenzonate ligands in the syn-syn fashion to form a pair of dinuclear [LaZn（m-CNC6H4COO）3（Py）（C2H5OH）] subunits, being linked together by two bidentate and two tridentate m-cyanobenzonate groups in the syn-syn and syn-anti modes, respectively, to construct a tetranuclear La-Zn complex [La2Zn2（m-CNC6H4COO）10（Py）2（C2H5OH）2].
基金the Innovative Project (No. IP01007)the Introduction of Overseas Elitists Program (No. IB990168) of the Chinese Academy of Sciences
文摘The zinc 3-hydroxy-2-mercaptopyridine complex was prepared by self-assemby reaction of Zn(NO3)2 and 3-hydroxy-2-mercaptopyridine (hmp). Single-crystal X-ray diffraction analysis indicates that it crystallizes in a tetragonal system, space group (No. 122) with a = 13.4562(6), c = 13.6860(8) , V = 2478.1(2) 3, Z = 8, Mr = 317.67, Dc = 1.703 g/cm3, m(Mo-Ka) = 2.308 mm-1 and F(000) = 1280. R = 0.0289 and wR = 0.0676 for 1040 observed reflections (I > 2s(I)). The crystal structure consists of a neutral molecule with a distorted tetrahedral cis-ZnS2O2 core, in which the mononuclear Zn2+ ion is coordinated by two O and two S atoms from two hmp ligands with the average bond distances of 2.301(1) ?for ZnS and 1.986(3) ?for ZnO. The 1H . NMR and IR spectra of the compound are discussed.
基金the National Natural Science Foundation of China(No.20673050).
文摘Low-temperature heat capacities of the solid compound Zn（C4H7O5）2（s） were measured in a temperature range from 78 to 374 K, with an automated adiabatic calorimeter. A solid-to-solid phase transition occurred in the temperature range of 295？322 K. The peak temperature, the enthalpy, and entropy of the phase transition were determined to be （316.269±1.039） K, （11.194±0.335） kJ？mol-1, and （35.391±0.654） J？K-1？mol-1, respectively. The experimental values of the molar heat capacities in the temperature regions of 78？295 K and 322？374 K were fitted to two polynomial equations of heat capacities（Cp,m） with reduced temperatures（X） and [X = f（T）], with the help of the least squares method, respectively. The smoothed molar heat capacities and thermodynamic functions of the compound, relative to that of the standard reference temperature 293.15 K, were calculated on the basis of the fitted polynomials and tabulated with an interval of 5 K. In addition, the possible mechanism of thermal decomposition of the compound was inferred by the result of TG-DTG analysis.
文摘The space group of [(H2O)(C3H4N2)(O2CCH=CHCO2Zn)]n, which was originally described in the acentric Pc space group (Liu et al., Chin. J. Struct. Chem. 2004, 23, 160～163), is re-described in the centric P21/c space group.
文摘The anode material Zn4SO4（OH）6·5H2O for nickle/zinc batteries was synthesized by hydrothermal method and was identified by XRD techniques. TG/DAT measurements reveal that the products lose lattice water at 145 ℃ and decompose to 3ZnO·ZnSO4 at 274 ℃. Cyclic voltammetry and recharging/discharging results show that CV curves have good symmetry, the ratio of oxidation area to reduction area for each curve is about 1, and the peak potential EPa and EPc have little change with the scanning rate. At 50th circle, more than 65% of theoretical capacity is obtained while at the same condition, zinc oxide electrode only remains 35% of theoretical capacity.
文摘A novel coordination polymer, [Fe(C 5H 4NCOO) 2] n, was synthesized by hydrothermal reaction and characterized by elemental analysis as well as IR spectroscopy. The crystal structure (with a novel 3-D network) of this compound belongs to monoclinic, space group P2 1/n, a=0.49544(1) nm, b=1.32443(2) nm, c=1.04983(1) nm, β=101.586(1)°. The diffuse reflectance spectra (200～2500 nm) showed that the polymer had strong absorbance in 375～563 nm (E g≈2.5 eV) region and weak absorbance from 720 to 2500 nm (near infrared spectra).
