Al-Zn-Si-RE coating with high Al content was deposited on mild steel by arc spraying. The electrochemical behavior of Al-Zn-Si-RE coating in 3.5%NaCl solution was systematically studied by potentiodynamic polarization...Al-Zn-Si-RE coating with high Al content was deposited on mild steel by arc spraying. The electrochemical behavior of Al-Zn-Si-RE coating in 3.5%NaCl solution was systematically studied by potentiodynamic polarization, corrosion potential (φcor ) and electrochemical impedance spectroscopy techniques (EIS). The impedance data were fitted to appropriate equivalent circuits to explain the different electrochemical processes occurring at the electrode-electrolyte interface. The results indicate that Al-Zn-Si-RE coating reveals the similar polarization behavior as Zn-15Al coating. The coating has no passive region in the anodic polarization, but far lower corrosion current and much higher corrosion potential. Al-Zn-Si-RE coating provides effective sacrificial protection for steel substrate and the sacrificial anodic protection plays dominant role during the immersion process. In addition, theφcor evolution and EIS plots indicate that the corrosion process can be divided into five stages: pitting-dissolution-redeposition, activation corrosion, cathodic protection, physical barriers and the coating failure.展开更多
Most hulls of the ships are protected with paintings, sacrificial anode, and impressed current cathodic protection methods against corrosion problems. However, these conventional methods are not very effective because...Most hulls of the ships are protected with paintings, sacrificial anode, and impressed current cathodic protection methods against corrosion problems. However, these conventional methods are not very effective because the rudder of ships stern are exposed to very severe corrosive environment such as tides, speeds of ships, cavitations and erosion corrosion. The environmental factors such as cavitation and corrosion will cause damage for materials with the shock wave by the creation and destruction of bubble. To solve these problems, the cavitation and electrochemical experiments are executed for thermal spray coating with Al-Zn alloy wire material. Thereafter, and sealed specimens with F-Si sealer on Al-Zn alloy coated specimen are executed to improve electrochemical and anti-cavitation characteristics in sea water. The application of fluorine silicon sealing after spray coating of 15%Al-85%Zn seems to be appropriate not only in static environment but also in dynamic environment.展开更多
基金Project(CXLX12_0149)supported by Funding of Jiangsu Innovation Program for Graduate Education,ChinaProject(BA2011029)supported by Special Fund of Transformation of Sci-tech Achievements of Jiangsu Province,China+1 种基金Project(BY2011101)supported by the Creative Fund of Combination of Industry,Academia and Research of Jiangsu Province,China-Prospective Joint Research ProjectProject(kfjj120217)supported by Open Funds of NUAA Innovation Base(Laboratory)for Graduate Students
文摘Al-Zn-Si-RE coating with high Al content was deposited on mild steel by arc spraying. The electrochemical behavior of Al-Zn-Si-RE coating in 3.5%NaCl solution was systematically studied by potentiodynamic polarization, corrosion potential (φcor ) and electrochemical impedance spectroscopy techniques (EIS). The impedance data were fitted to appropriate equivalent circuits to explain the different electrochemical processes occurring at the electrode-electrolyte interface. The results indicate that Al-Zn-Si-RE coating reveals the similar polarization behavior as Zn-15Al coating. The coating has no passive region in the anodic polarization, but far lower corrosion current and much higher corrosion potential. Al-Zn-Si-RE coating provides effective sacrificial protection for steel substrate and the sacrificial anodic protection plays dominant role during the immersion process. In addition, theφcor evolution and EIS plots indicate that the corrosion process can be divided into five stages: pitting-dissolution-redeposition, activation corrosion, cathodic protection, physical barriers and the coating failure.
文摘Most hulls of the ships are protected with paintings, sacrificial anode, and impressed current cathodic protection methods against corrosion problems. However, these conventional methods are not very effective because the rudder of ships stern are exposed to very severe corrosive environment such as tides, speeds of ships, cavitations and erosion corrosion. The environmental factors such as cavitation and corrosion will cause damage for materials with the shock wave by the creation and destruction of bubble. To solve these problems, the cavitation and electrochemical experiments are executed for thermal spray coating with Al-Zn alloy wire material. Thereafter, and sealed specimens with F-Si sealer on Al-Zn alloy coated specimen are executed to improve electrochemical and anti-cavitation characteristics in sea water. The application of fluorine silicon sealing after spray coating of 15%Al-85%Zn seems to be appropriate not only in static environment but also in dynamic environment.
