A superhydrophobic Zn−Fe alloy coating was prepared on the surface of a reactive magnesium alloy using a simple,low-cost,eco-friendly method.Firstly,the Zn−Fe coating was obtained in a neutral glycerol Zn−Fe plating s...A superhydrophobic Zn−Fe alloy coating was prepared on the surface of a reactive magnesium alloy using a simple,low-cost,eco-friendly method.Firstly,the Zn−Fe coating was obtained in a neutral glycerol Zn−Fe plating solution,which is green,compositionally stable,and non-corrosive to the equipment.And then the superhydrophobic surface with a flower-like microstructure was obtained by grafting myristic acid onto the Zn−Fe coating via a chelation reaction.The water contact angle was>150°and the rolling angle was 3°−4°.The corrosion rate of the two groups of superhydrophobic magnesium alloy samples with electrodeposition time of 30 and 50 min,respectively,was reduced by about 87%compared to that of the bare magnesium alloy.The prepared superhydrophobic coatings exhibit high performance in self-cleaning,abrasion resistance,and corrosion resistance.展开更多
The Zn and Fe modified /ZrO<sub>2</sub>-Al<sub>2</sub>O<sub>3</sub> catalyst (Zn-Fe-SZA) was prepared and mechanisms of deactivation and methods for regeneration of as-prepared cata...The Zn and Fe modified /ZrO<sub>2</sub>-Al<sub>2</sub>O<sub>3</sub> catalyst (Zn-Fe-SZA) was prepared and mechanisms of deactivation and methods for regeneration of as-prepared catalyst were explored with n-pentane isomerization as a probe reaction. The results indicated that the isopentane yield of the fresh Zn-Fe-SZA-F catalyst was about 57% at the beginning of the run, and declined gradually to 50% within 1500 min, then fell rapidly from 50% to 40% between 1500 and 2500 minutes. The deactivation of Zn-Fe-SZA catalyst may be caused by carbon formation on surface of the catalyst, sulfate group attenuation owing to reduction by hydrogen, removal of sulfur species and the loss of strong acid sites. It was found that the initial catalytic activity over Zn-Fe-SZA-T catalyst was 48%, which recovered by 84.3% as compared to that of fresh catalyst (57%). However, it showed a sharp decrease in isopentane yield from 48% to 29% within 1500 minutes, showing poor stability. This is associated to the loss of acidity caused by removal of sulfur species cannot be basically restored by thermal treatment. Resulfating the calcined catalyst could improve the acidity of catalyst significantly, especially strong acid sites, as compared with the calcined sample. The improved stability of the resulfated catalyst can be explained by: 1) eliminaton of carbon deposition to some extent by calcination process, 2) formation of improved acidic nature by re-sulfation, favoring isomerization on acidic sites, 3) restructuring of the acid and metal sites via the calcination-re-sulfation procedure.展开更多
采用自制的析磷助剂EA P作为Zn Fe P合金镀层中的磷源 ,研究了Zn Fe P合金镀液组成及工艺条件对镀层中磷、铁含量的影响。在最佳工艺条件下 ,可得到磷、铁含量分别为 0 .6 %左右和 0 .4%Zn Fe P合金镀层。腐蚀试验证明 ,经银白色钝化后...采用自制的析磷助剂EA P作为Zn Fe P合金镀层中的磷源 ,研究了Zn Fe P合金镀液组成及工艺条件对镀层中磷、铁含量的影响。在最佳工艺条件下 ,可得到磷、铁含量分别为 0 .6 %左右和 0 .4%Zn Fe P合金镀层。腐蚀试验证明 ,经银白色钝化后的Zn Fe P合金镀层的耐蚀性能是Zn Fe合金镀层的 2倍以上。展开更多
基金supports from the National Natural Science Foundation of China(No.22178242).
文摘A superhydrophobic Zn−Fe alloy coating was prepared on the surface of a reactive magnesium alloy using a simple,low-cost,eco-friendly method.Firstly,the Zn−Fe coating was obtained in a neutral glycerol Zn−Fe plating solution,which is green,compositionally stable,and non-corrosive to the equipment.And then the superhydrophobic surface with a flower-like microstructure was obtained by grafting myristic acid onto the Zn−Fe coating via a chelation reaction.The water contact angle was>150°and the rolling angle was 3°−4°.The corrosion rate of the two groups of superhydrophobic magnesium alloy samples with electrodeposition time of 30 and 50 min,respectively,was reduced by about 87%compared to that of the bare magnesium alloy.The prepared superhydrophobic coatings exhibit high performance in self-cleaning,abrasion resistance,and corrosion resistance.
文摘The Zn and Fe modified /ZrO<sub>2</sub>-Al<sub>2</sub>O<sub>3</sub> catalyst (Zn-Fe-SZA) was prepared and mechanisms of deactivation and methods for regeneration of as-prepared catalyst were explored with n-pentane isomerization as a probe reaction. The results indicated that the isopentane yield of the fresh Zn-Fe-SZA-F catalyst was about 57% at the beginning of the run, and declined gradually to 50% within 1500 min, then fell rapidly from 50% to 40% between 1500 and 2500 minutes. The deactivation of Zn-Fe-SZA catalyst may be caused by carbon formation on surface of the catalyst, sulfate group attenuation owing to reduction by hydrogen, removal of sulfur species and the loss of strong acid sites. It was found that the initial catalytic activity over Zn-Fe-SZA-T catalyst was 48%, which recovered by 84.3% as compared to that of fresh catalyst (57%). However, it showed a sharp decrease in isopentane yield from 48% to 29% within 1500 minutes, showing poor stability. This is associated to the loss of acidity caused by removal of sulfur species cannot be basically restored by thermal treatment. Resulfating the calcined catalyst could improve the acidity of catalyst significantly, especially strong acid sites, as compared with the calcined sample. The improved stability of the resulfated catalyst can be explained by: 1) eliminaton of carbon deposition to some extent by calcination process, 2) formation of improved acidic nature by re-sulfation, favoring isomerization on acidic sites, 3) restructuring of the acid and metal sites via the calcination-re-sulfation procedure.
文摘采用自制的析磷助剂EA P作为Zn Fe P合金镀层中的磷源 ,研究了Zn Fe P合金镀液组成及工艺条件对镀层中磷、铁含量的影响。在最佳工艺条件下 ,可得到磷、铁含量分别为 0 .6 %左右和 0 .4%Zn Fe P合金镀层。腐蚀试验证明 ,经银白色钝化后的Zn Fe P合金镀层的耐蚀性能是Zn Fe合金镀层的 2倍以上。
