In a previous greenhouse experiment, we showed that there was an interaction between Cu and Zn, which affected growth and metal uptake by young barley plants grown on soil to which Cd, Cu, Pb, and Zn had been added. W...In a previous greenhouse experiment, we showed that there was an interaction between Cu and Zn, which affected growth and metal uptake by young barley plants grown on soil to which Cd, Cu, Pb, and Zn had been added. We suggested that the underlying mechanism was the control of the amount of plant-available Zn by competitive adsorption between Cu and Zn. In order to test this hypothesis, the adsorption of Zn alone, and in the presence of added Cd, Cu and Pb, has been measured using the same soil. Following adsorption, the extractability of the Zn in CaCl2 solution was measured. The adsorption isotherms showed that of the added metals only Cu had a large effect on Zn adsorption. The effect of Cu was to reduce Zn adsorption and to increase the amount of CaCl2-extractable (i.e. plant-available) Zn, in agreement with the conclusions from the greenhouse experiment. The magnitude of the effect of Cu on plant-available Zn was similar in both experiments.展开更多
文摘In a previous greenhouse experiment, we showed that there was an interaction between Cu and Zn, which affected growth and metal uptake by young barley plants grown on soil to which Cd, Cu, Pb, and Zn had been added. We suggested that the underlying mechanism was the control of the amount of plant-available Zn by competitive adsorption between Cu and Zn. In order to test this hypothesis, the adsorption of Zn alone, and in the presence of added Cd, Cu and Pb, has been measured using the same soil. Following adsorption, the extractability of the Zn in CaCl2 solution was measured. The adsorption isotherms showed that of the added metals only Cu had a large effect on Zn adsorption. The effect of Cu was to reduce Zn adsorption and to increase the amount of CaCl2-extractable (i.e. plant-available) Zn, in agreement with the conclusions from the greenhouse experiment. The magnitude of the effect of Cu on plant-available Zn was similar in both experiments.