The subsolidus phase relations of a ZnO-V2O5-K2O system are investigated by X-ray powder diffraction. There is 1 ternary compound, 11 binary compounds and 14 three-phase regions in this system. The phase diagrams of V...The subsolidus phase relations of a ZnO-V2O5-K2O system are investigated by X-ray powder diffraction. There is 1 ternary compound, 11 binary compounds and 14 three-phase regions in this system. The phase diagrams of V2O5- K2O with the K2O content ranging from 0 to 71 mol% and pseudo-binary system of ZnO-K2ZnV2O7 are also studied by X-ray powder diffraction and differential thermal analysis methods.展开更多
The subsolidus phase relations of the ZnO-BaO-V2O5 ternary systems were investigated by means of X-ray diffraction analysis. There are three ternary compounds, nine binary compounds and sixteen 3-phase regions found i...The subsolidus phase relations of the ZnO-BaO-V2O5 ternary systems were investigated by means of X-ray diffraction analysis. There are three ternary compounds, nine binary compounds and sixteen 3-phase regions found in this system. The crystal structure of the ternary compound Ba2ZnV2O8 was refined by Rietveld profile fitting method and the powder diffraction pattern is given. A new ternary compound Ba3.4Zn0.8V4O14.2 has been found by the powder diffraction pattern.展开更多
The effect of Mn_(3)O_(4)addition on microhardness,microstructure and electrical properties of vanadium oxide doped zinc oxide varistor ceramics is systematically investigated.The Vicker’s microhardness HV has decrea...The effect of Mn_(3)O_(4)addition on microhardness,microstructure and electrical properties of vanadium oxide doped zinc oxide varistor ceramics is systematically investigated.The Vicker’s microhardness HV has decreased with increasing the amount of Mn3O4.Also,the average grain size has decreased from 27.51μm to 19.55μm with increasing the amount of Mn_(3)O_(4) up to 0.50 mol%,whereas an increase in Mn_(3)O_(4) up to 0.75 mol%has caused the average grain size to increase and then it decreases with increasing Mn_(3)O_(4)from 0.75 mol%to 1.00 mol%.The sintered density has decreased from 5.38 g/cm3 to 5.31 g/cm3 with increasing the amount of Mn_(3)O_(4).The varistor ceramic modified with 0.50 mol%Mn_(3)O_(4) has exhibited excellent nonlinear properties,with 16.29 for the nonlinear coefficient and 441.9μA/cm2 for the leakage current density.Furthermore,the sample doped with 0.50 mol%Mn_(3)O_(4) has been found to possess donor density as 0.77×10^(18) cm^(-3) and 0.916 eV barrier height.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No.50672123)
文摘The subsolidus phase relations of a ZnO-V2O5-K2O system are investigated by X-ray powder diffraction. There is 1 ternary compound, 11 binary compounds and 14 three-phase regions in this system. The phase diagrams of V2O5- K2O with the K2O content ranging from 0 to 71 mol% and pseudo-binary system of ZnO-K2ZnV2O7 are also studied by X-ray powder diffraction and differential thermal analysis methods.
基金supported by the National Natural Science Foundation of China(20971123,51002153,21007070,51102232,61106004 and 21103191)the National Basic Research Program of China(973Program,2010CB933501)+1 种基金the Natural Science Foundation of Fujian Province(2010J01054,2010J06006 and 2010J05038)the NSF of Outstanding Youth Fund(21125730)
文摘The subsolidus phase relations of the ZnO-BaO-V2O5 ternary systems were investigated by means of X-ray diffraction analysis. There are three ternary compounds, nine binary compounds and sixteen 3-phase regions found in this system. The crystal structure of the ternary compound Ba2ZnV2O8 was refined by Rietveld profile fitting method and the powder diffraction pattern is given. A new ternary compound Ba3.4Zn0.8V4O14.2 has been found by the powder diffraction pattern.
文摘The effect of Mn_(3)O_(4)addition on microhardness,microstructure and electrical properties of vanadium oxide doped zinc oxide varistor ceramics is systematically investigated.The Vicker’s microhardness HV has decreased with increasing the amount of Mn3O4.Also,the average grain size has decreased from 27.51μm to 19.55μm with increasing the amount of Mn_(3)O_(4) up to 0.50 mol%,whereas an increase in Mn_(3)O_(4) up to 0.75 mol%has caused the average grain size to increase and then it decreases with increasing Mn_(3)O_(4)from 0.75 mol%to 1.00 mol%.The sintered density has decreased from 5.38 g/cm3 to 5.31 g/cm3 with increasing the amount of Mn_(3)O_(4).The varistor ceramic modified with 0.50 mol%Mn_(3)O_(4) has exhibited excellent nonlinear properties,with 16.29 for the nonlinear coefficient and 441.9μA/cm2 for the leakage current density.Furthermore,the sample doped with 0.50 mol%Mn_(3)O_(4) has been found to possess donor density as 0.77×10^(18) cm^(-3) and 0.916 eV barrier height.
