Influence of Zr contents on high-temperature magnetic performance of Sm(CoFeCuZr)(x=0.025,0.03,0.035,0.04) magnets were investigated.As x increases from 0.025 to 0.04,the temperature coefficient of intrinsic coercivit...Influence of Zr contents on high-temperature magnetic performance of Sm(CoFeCuZr)(x=0.025,0.03,0.035,0.04) magnets were investigated.As x increases from 0.025 to 0.04,the temperature coefficient of intrinsic coercivity(H) is optimized from-0.1673% K^(-1)to-0.1382% K^(-1)and the Hat 773 K gradually increases from 556.32 kA m^(-1)to 667 kA m^(-1).The microstructure and microchemistry of different Zr-content magnets were revealed by a transmission electron microscope equipped with EDS.The increasing Zr content induces that the average size of cells decreases from ~76 nm to ~56 nm and the weight fraction of 1:5 H cell boundary phase increases from ~25% to ~37% as well,resulting decreasing of the average Cu content at cell boundaries from 13.59 at% to ~8.52 at%.It is found that the Cu-lean characteristic at cell boundary phase is the reason that gives rise to higher magnetic properties at elevated temperatures for x=0.04 magnet.展开更多
In this paper, Ni/Zr–Yb–O catalysts with different sodium contents are prepared by a co-precipitation method, using aqueous Na2CO3 solution as a precipitant, and the effect of sodium on the catalyst structure and ca...In this paper, Ni/Zr–Yb–O catalysts with different sodium contents are prepared by a co-precipitation method, using aqueous Na2CO3 solution as a precipitant, and the effect of sodium on the catalyst structure and catalytic performance for syngas methanation is extensively investigated using five Ni/Zr–Yb–O catalysts, containing 0, 0.5, 1.5,4.5 and 13.5 wt% Na^+, those are denoted as Cat-1, Cat-2, Cat-3, Cat-4 and Cat-5 respectively. It is found that the interaction between Ni and support determines the catalytic performance of Ni/Zr–Yb–O and the residual sodium content negatively affects the interaction between Ni and support. Cat-1 exhibits an excellent catalytic performance.During a long run time of 380 h, no deactivation is observed and both CO conversion and CH4 selectivity maintain a level above 90%. However, Cat-3 and Cat-5 suffer rapid deactivation under the same reaction condition. The characterization results indicate the strong interaction between Ni and support enables Cat-1 to possess well dispersed Ni species, resistance to sintering and carbon deposition and thus the excellent catalytic performance. However, the presence of sodium ions over Ni/Zr–Yb–O degrades the interaction between Ni and support and the catalytic performance, especially for the stability. The relative weak interaction between Ni and support results in severe sintering of both ZrO2 and Ni under the reaction condition, carbon deposition and the poor catalytic performance.展开更多
In order to research the influence of Zr content （ below 15 wt. % ） on the properties of the filler metal. Ti-5Zr- 15Cu-15Ni-La, Ti-lOZr-15Cu-15Ni-La and Ti-15Zr-15Cu-15Ni-La filler metals were prepared. The wettabi...In order to research the influence of Zr content （ below 15 wt. % ） on the properties of the filler metal. Ti-5Zr- 15Cu-15Ni-La, Ti-lOZr-15Cu-15Ni-La and Ti-15Zr-15Cu-15Ni-La filler metals were prepared. The wettability of the filler metals on Ti-6Al-4V was evaluated and the melting temperatures of the filler metals were tested by differential scanning calorimetry （DSC）. The microstructures and mechanical properties of the brazed joints were investigated. The results show that the wettability of the filler metals improves as the Zr content increases. Zr content has great influence on the melting temperature of the filler metals. When Zr content changes from 5 wt. % to 10 wt. % and 15 wt. % , the melting temperature decreases about 80 ℃. The brazed joint with Ti-5Zr-15Cu-15Ni-La filler metal shows aciculate phase on the interfizce. The brazed joints with Ti-lOZr-15Cu-15Ni-La and Ti-15Zr-15Cu-15Ni-La filler metals consist of three zones, a segregated center zonc, diffusion reaction zone and acicular zone. The brazed joint with Ti-5Zr-15Cu-15Ni-La filler metal achieves the maximum shear strength 313.9 MPa.展开更多
基金partially supported by the National Natural Science Foundation of China (No. 51871063)the Key Technology Research and Development Program of Shandong (No. 2019JZZY020210)。
文摘Influence of Zr contents on high-temperature magnetic performance of Sm(CoFeCuZr)(x=0.025,0.03,0.035,0.04) magnets were investigated.As x increases from 0.025 to 0.04,the temperature coefficient of intrinsic coercivity(H) is optimized from-0.1673% K^(-1)to-0.1382% K^(-1)and the Hat 773 K gradually increases from 556.32 kA m^(-1)to 667 kA m^(-1).The microstructure and microchemistry of different Zr-content magnets were revealed by a transmission electron microscope equipped with EDS.The increasing Zr content induces that the average size of cells decreases from ~76 nm to ~56 nm and the weight fraction of 1:5 H cell boundary phase increases from ~25% to ~37% as well,resulting decreasing of the average Cu content at cell boundaries from 13.59 at% to ~8.52 at%.It is found that the Cu-lean characteristic at cell boundary phase is the reason that gives rise to higher magnetic properties at elevated temperatures for x=0.04 magnet.
基金Supported by the National Natural Science Foundation of China(21673187,21336009,21576228)National Key Technology Support Program of China(2014BAC10B01).
文摘In this paper, Ni/Zr–Yb–O catalysts with different sodium contents are prepared by a co-precipitation method, using aqueous Na2CO3 solution as a precipitant, and the effect of sodium on the catalyst structure and catalytic performance for syngas methanation is extensively investigated using five Ni/Zr–Yb–O catalysts, containing 0, 0.5, 1.5,4.5 and 13.5 wt% Na^+, those are denoted as Cat-1, Cat-2, Cat-3, Cat-4 and Cat-5 respectively. It is found that the interaction between Ni and support determines the catalytic performance of Ni/Zr–Yb–O and the residual sodium content negatively affects the interaction between Ni and support. Cat-1 exhibits an excellent catalytic performance.During a long run time of 380 h, no deactivation is observed and both CO conversion and CH4 selectivity maintain a level above 90%. However, Cat-3 and Cat-5 suffer rapid deactivation under the same reaction condition. The characterization results indicate the strong interaction between Ni and support enables Cat-1 to possess well dispersed Ni species, resistance to sintering and carbon deposition and thus the excellent catalytic performance. However, the presence of sodium ions over Ni/Zr–Yb–O degrades the interaction between Ni and support and the catalytic performance, especially for the stability. The relative weak interaction between Ni and support results in severe sintering of both ZrO2 and Ni under the reaction condition, carbon deposition and the poor catalytic performance.
基金the financial supports from the Major Project of Science and Technology of Gansu Province,China(No.17ZD2GC011)the Hongliu First-class Discipline Construction Plan of Lanzhou University of Technology,China(No.CGZH001).
文摘In order to research the influence of Zr content （ below 15 wt. % ） on the properties of the filler metal. Ti-5Zr- 15Cu-15Ni-La, Ti-lOZr-15Cu-15Ni-La and Ti-15Zr-15Cu-15Ni-La filler metals were prepared. The wettability of the filler metals on Ti-6Al-4V was evaluated and the melting temperatures of the filler metals were tested by differential scanning calorimetry （DSC）. The microstructures and mechanical properties of the brazed joints were investigated. The results show that the wettability of the filler metals improves as the Zr content increases. Zr content has great influence on the melting temperature of the filler metals. When Zr content changes from 5 wt. % to 10 wt. % and 15 wt. % , the melting temperature decreases about 80 ℃. The brazed joint with Ti-5Zr-15Cu-15Ni-La filler metal shows aciculate phase on the interfizce. The brazed joints with Ti-lOZr-15Cu-15Ni-La and Ti-15Zr-15Cu-15Ni-La filler metals consist of three zones, a segregated center zonc, diffusion reaction zone and acicular zone. The brazed joint with Ti-5Zr-15Cu-15Ni-La filler metal achieves the maximum shear strength 313.9 MPa.
