To improve the oxidation resistance and corrosion resistance of Zr-4 alloy, titanium nitride(TiN) coatings were prepared on the Zr-4 alloy with a TiN ceramic target with different ratios of N_2. Microstructure and hig...To improve the oxidation resistance and corrosion resistance of Zr-4 alloy, titanium nitride(TiN) coatings were prepared on the Zr-4 alloy with a TiN ceramic target with different ratios of N_2. Microstructure and high-temperature properties of the TiN coated samples were studied by scanning electron microscopy(SEM), energy dispersive spectrometer(EDS), X-ray diffraction meter(XRD), X-ray photoelectron spectroscopy(XPS), heat treatment furnace and autoclaves, respectively. The x value of the TiN coatings(TiN_x) ranges from 0.96 to 1.33. After the introduction of N_2, TiN coating exhibits a weak(200) plane and a preferred(111) orientation. The coating prepared with an N_2 flow ratio of 15% shows an optimal oxidation resistance in the atmospheric environment at 800 °C. In either 1 200 °C steam environment for one hour, or deionized water at 360 °C and a pressure of 18.6 Mpa for 16 d, the opitimized TiN coated samples have no delamination or spallation; and the gains in the masses of samples are much smaller than Zr-4 alloy. These results demonstrate the effectiveness of the optimized TiN coating as the protective coating on the Zr-4 alloy under extreme conditons.展开更多
This study employs advanced electrochemical and surface characterization techniques to investigate the impact of electrochemical hydrogen charging on the corrosion behavior and surface film of the Ti-6Al-4V alloy.The ...This study employs advanced electrochemical and surface characterization techniques to investigate the impact of electrochemical hydrogen charging on the corrosion behavior and surface film of the Ti-6Al-4V alloy.The findings revealed the formation ofγ-TiH andδ-TiH_(2) hydrides in the alloy after hydrogen charging.Prolonging hydrogen charging resulted in more significant degradation of the alloy microstructure,leading to deteriorated protectiveness of the surface film.This trend was further confirmed by the electrochemical measurements,which showed that the corrosion resistance of the alloy progressively worsened as the hydrogen charging time was increased.Consequently,this work provides valuable insights into the mechanisms underlying the corrosion of Ti-6Al-4V alloy under hydrogen charging conditions.展开更多
Laser powder bed fusion(LPBF)is an advanced manufacturing technology;however,inappropriate LPBF process parameters may cause printing defects in materials.In the present work,the LPBF process of Ti-6.5Al-3.5Mo-1.5Zr-0...Laser powder bed fusion(LPBF)is an advanced manufacturing technology;however,inappropriate LPBF process parameters may cause printing defects in materials.In the present work,the LPBF process of Ti-6.5Al-3.5Mo-1.5Zr-0.3Si alloy was investigated by a two-step optimization approach.Subsequently,heat transfer and liquid flow behaviors during LPBF were simulated by a well-tested phenomenological model,and the defect formation mechanisms in the as-fabricated alloy were discussed.The optimized process parameters for LPBF were detected as laser power changed from 195 W to 210 W,with scanning speed of 1250 mm/s.The LPBF process was divided into a laser irradiation stage,a spreading flow stage,and a solidification stage.The morphologies and defects of deposited tracks were affected by liquid flow behavior caused by rapid cooling rates.The findings of this research can provide valuable support for printing defect-free metal components.展开更多
To protect the AM60B magnesium alloy from corrosion,a sol-gel coating containing hydroxylated g-C_(3)N_(4)nanoplates was applied.The chemical composition of the hydroxylated g-C_(3)N_(4)nanoplates was investigated usi...To protect the AM60B magnesium alloy from corrosion,a sol-gel coating containing hydroxylated g-C_(3)N_(4)nanoplates was applied.The chemical composition of the hydroxylated g-C_(3)N_(4)nanoplates was investigated using X-ray photoelectron spectroscopy(XPS).The hydroxylation process did not affect the crystal size,specific surface area,pore volume,average pore diameter,and thermal stability of the g-C_(3)N_(4)nanoplates.After incorporating pristine and hydroxylated g-C_(3)N_(4)nanoplates,dense sol-gel coatings were obtained.Transmission electron microscopy(TEM)revealed the uniform distribution of the modified g-C_(3)N_(4)in the coating.The average roughness of the coating was also reduced after adding the modified nanoplates due to the decreased aggregation tendency.Electrochemical impedance spectroscopy(EIS)examinations in simulated acid rain revealed a significant improvement in the anticorrosion properties of the sol-gel film after the addition of the modified g-C_(3)N_(4)due to the chemical bonding of the coating to the nanoplates.展开更多
The true stress-sWain relationships of Ti-5A1-2Sn-2Zr-4Mo-4Cr(TC17) alloy with a wide range of strain rates were investigated by tmiaxial quasi-static and dynamic compression tests, respectively. Quasi- static compr...The true stress-sWain relationships of Ti-5A1-2Sn-2Zr-4Mo-4Cr(TC17) alloy with a wide range of strain rates were investigated by tmiaxial quasi-static and dynamic compression tests, respectively. Quasi- static compression tests were carried out with Instron 8874 test machine, while dynamic compression tests were performed with the split Hopkinson pressure bar (SHPB) which was installed with heating device and synchro- assembly system. The dynamic mechanical behaviors tests of TC17 were carded out from room temperature to 800 ℃ at intervals of 200 ℃ and at high sWain rates (5 500-1 9200 s-l). The stress-strain curves considering temperature-sWain rate coupling actions were obtained. The Johnson-Cook constitutive model was developed through data fitting of the stress-sWain curves. The material constants in the developed constitutive model can be determined using isothermal and adiabatic stress-strain curves at different strain rates. The Johnson-Cook constitutive model provided satisfied prediction of the plastic flow stress for TC17 alloy.展开更多
A CrZr-alloyed layer was prepared through a pre-zirconizing and subsequent chromizing treatment on a Ti6Al4V substrate.After the removal of the top Cr deposit and Ti4Cr layers,a(Cr,Zr)-Ti solidsolution layer was obt...A CrZr-alloyed layer was prepared through a pre-zirconizing and subsequent chromizing treatment on a Ti6Al4V substrate.After the removal of the top Cr deposit and Ti4Cr layers,a(Cr,Zr)-Ti solidsolution layer was obtained.The microstructure,composition,microhardness and toughness of the(Cr,Zr)-Ti solid-solution layer were evaluated.The results showed that the pre-addition of Zr played an important role in inhibiting the precipitation of the soft Ti4Cr phase,which in turn allowed us to obtain a material characterized by a remarkable hardness.Wear and fatigue tests showed that the(Cr,Zr)-Ti solid-solution layer could coordinately improve the properties of the Ti6Al4V alloy.This was mainly due to the good match of hardness and toughness of the(Cr,Zr)-Ti solid-solution layer.In addition,the gradual change in composition and mechanical properties was conducive to the coordinated deformation between the(Cr,Zr)-Ti solid-solution layer and the Ti6Al4V substrate during fatigue tests.This reduced the stress concentration in correspondence of the interface between the two materials.展开更多
The characteristics of fatigue crack initiation in Ti-5AI-4Sn-2Zr1Mo-O.7Nd-O.25Si alloy wereStudied. Two modes Of fatigue crack initiation were found. The Nd-rich phase particles displaybetter resistance to fatigue cr...The characteristics of fatigue crack initiation in Ti-5AI-4Sn-2Zr1Mo-O.7Nd-O.25Si alloy wereStudied. Two modes Of fatigue crack initiation were found. The Nd-rich phase particles displaybetter resistance to fatigue crack initiation than the matrix at lower stress.展开更多
The Sr/F co-doped CaP(Sr/F-CaP)coatings were prepared by micro-arc oxidation(MAO)under different voltages to modify the microstructure and corrosion behavior of Mg-4Zn-1Mn alloy.The surface and interface characteristi...The Sr/F co-doped CaP(Sr/F-CaP)coatings were prepared by micro-arc oxidation(MAO)under different voltages to modify the microstructure and corrosion behavior of Mg-4Zn-1Mn alloy.The surface and interface characteristics investigated using scanning electron microscopy(SEM)and energy dispersive X-ray spectrometer(EDS)showed that the MAO coatings displayed uneven crater-like holes and tiny cracks under lower voltage,while they exhibited relatively homogeneous crater-like holes without cracks under higher voltage.The thickness of MAO coatings increased with increasing voltage.The corrosion behavior of Mg-4Zn-1Mn alloy was improved by the MAO coatings.The MAO coatings prepared under 450 V and 500 V voltages possessed the best corrosion resistance with regard to the electrochemical corrosion tests and immersion corrosion tests,respectively.The MAO coatings fabricated under 450-500 V could provide a better corrosion protection effect for the substrate.展开更多
基金Funded by the National Science and Technology Major Project of the Ministry of Science and Technology of China(2015ZX06004001-002)the Postgraduate Research and Innovation Project of the University of South China(2017XCX11)
文摘To improve the oxidation resistance and corrosion resistance of Zr-4 alloy, titanium nitride(TiN) coatings were prepared on the Zr-4 alloy with a TiN ceramic target with different ratios of N_2. Microstructure and high-temperature properties of the TiN coated samples were studied by scanning electron microscopy(SEM), energy dispersive spectrometer(EDS), X-ray diffraction meter(XRD), X-ray photoelectron spectroscopy(XPS), heat treatment furnace and autoclaves, respectively. The x value of the TiN coatings(TiN_x) ranges from 0.96 to 1.33. After the introduction of N_2, TiN coating exhibits a weak(200) plane and a preferred(111) orientation. The coating prepared with an N_2 flow ratio of 15% shows an optimal oxidation resistance in the atmospheric environment at 800 °C. In either 1 200 °C steam environment for one hour, or deionized water at 360 °C and a pressure of 18.6 Mpa for 16 d, the opitimized TiN coated samples have no delamination or spallation; and the gains in the masses of samples are much smaller than Zr-4 alloy. These results demonstrate the effectiveness of the optimized TiN coating as the protective coating on the Zr-4 alloy under extreme conditons.
基金Key Project of uclear Safety and Advanced Nuclear Technology,China(No.2019YFB1901002)Project supported by the State Key Laboratory of Powder Metallurgy,Central South University,China。
基金Supported by National Natural Science Foundation of China(Grant Nos.52001142,52005228,51801218,51911530211,51905110)Young Scientists Sponsorship Program by CAST(Grant No.2022QNRC001).
文摘This study employs advanced electrochemical and surface characterization techniques to investigate the impact of electrochemical hydrogen charging on the corrosion behavior and surface film of the Ti-6Al-4V alloy.The findings revealed the formation ofγ-TiH andδ-TiH_(2) hydrides in the alloy after hydrogen charging.Prolonging hydrogen charging resulted in more significant degradation of the alloy microstructure,leading to deteriorated protectiveness of the surface film.This trend was further confirmed by the electrochemical measurements,which showed that the corrosion resistance of the alloy progressively worsened as the hydrogen charging time was increased.Consequently,this work provides valuable insights into the mechanisms underlying the corrosion of Ti-6Al-4V alloy under hydrogen charging conditions.
基金Supported by Development of a Verification Platform for Product Design,Process and Information Exchange Standards in Additive Manufacturing (Grant No.2019-00899-1-1)Ministry of Science and Technology of the People’s Republic of China (Grant No.2017YFB1103000)+1 种基金National Natural Science Foundation of China (Grant No.51375242)Natural Science Foundation of Jiangsu Province (Grant No.BK20180483)。
文摘Laser powder bed fusion(LPBF)is an advanced manufacturing technology;however,inappropriate LPBF process parameters may cause printing defects in materials.In the present work,the LPBF process of Ti-6.5Al-3.5Mo-1.5Zr-0.3Si alloy was investigated by a two-step optimization approach.Subsequently,heat transfer and liquid flow behaviors during LPBF were simulated by a well-tested phenomenological model,and the defect formation mechanisms in the as-fabricated alloy were discussed.The optimized process parameters for LPBF were detected as laser power changed from 195 W to 210 W,with scanning speed of 1250 mm/s.The LPBF process was divided into a laser irradiation stage,a spreading flow stage,and a solidification stage.The morphologies and defects of deposited tracks were affected by liquid flow behavior caused by rapid cooling rates.The findings of this research can provide valuable support for printing defect-free metal components.
文摘To protect the AM60B magnesium alloy from corrosion,a sol-gel coating containing hydroxylated g-C_(3)N_(4)nanoplates was applied.The chemical composition of the hydroxylated g-C_(3)N_(4)nanoplates was investigated using X-ray photoelectron spectroscopy(XPS).The hydroxylation process did not affect the crystal size,specific surface area,pore volume,average pore diameter,and thermal stability of the g-C_(3)N_(4)nanoplates.After incorporating pristine and hydroxylated g-C_(3)N_(4)nanoplates,dense sol-gel coatings were obtained.Transmission electron microscopy(TEM)revealed the uniform distribution of the modified g-C_(3)N_(4)in the coating.The average roughness of the coating was also reduced after adding the modified nanoplates due to the decreased aggregation tendency.Electrochemical impedance spectroscopy(EIS)examinations in simulated acid rain revealed a significant improvement in the anticorrosion properties of the sol-gel film after the addition of the modified g-C_(3)N_(4)due to the chemical bonding of the coating to the nanoplates.
基金Funded by the National Basic Research Program of China(No.2009CB724401)the Major Science and Technology Program of High-end CNC Machine Tools and Basic Manufacturing Equipment(No.2012ZX04003-041)
文摘The true stress-sWain relationships of Ti-5A1-2Sn-2Zr-4Mo-4Cr(TC17) alloy with a wide range of strain rates were investigated by tmiaxial quasi-static and dynamic compression tests, respectively. Quasi- static compression tests were carried out with Instron 8874 test machine, while dynamic compression tests were performed with the split Hopkinson pressure bar (SHPB) which was installed with heating device and synchro- assembly system. The dynamic mechanical behaviors tests of TC17 were carded out from room temperature to 800 ℃ at intervals of 200 ℃ and at high sWain rates (5 500-1 9200 s-l). The stress-strain curves considering temperature-sWain rate coupling actions were obtained. The Johnson-Cook constitutive model was developed through data fitting of the stress-sWain curves. The material constants in the developed constitutive model can be determined using isothermal and adiabatic stress-strain curves at different strain rates. The Johnson-Cook constitutive model provided satisfied prediction of the plastic flow stress for TC17 alloy.
基金Funded by the National Natural Science Foundation of China(Nos.51171154,51101127,51771155)Natural Science Foundation of Shaanxi Province(No.2018JQ5135)
文摘A CrZr-alloyed layer was prepared through a pre-zirconizing and subsequent chromizing treatment on a Ti6Al4V substrate.After the removal of the top Cr deposit and Ti4Cr layers,a(Cr,Zr)-Ti solidsolution layer was obtained.The microstructure,composition,microhardness and toughness of the(Cr,Zr)-Ti solid-solution layer were evaluated.The results showed that the pre-addition of Zr played an important role in inhibiting the precipitation of the soft Ti4Cr phase,which in turn allowed us to obtain a material characterized by a remarkable hardness.Wear and fatigue tests showed that the(Cr,Zr)-Ti solid-solution layer could coordinately improve the properties of the Ti6Al4V alloy.This was mainly due to the good match of hardness and toughness of the(Cr,Zr)-Ti solid-solution layer.In addition,the gradual change in composition and mechanical properties was conducive to the coordinated deformation between the(Cr,Zr)-Ti solid-solution layer and the Ti6Al4V substrate during fatigue tests.This reduced the stress concentration in correspondence of the interface between the two materials.
文摘The characteristics of fatigue crack initiation in Ti-5AI-4Sn-2Zr1Mo-O.7Nd-O.25Si alloy wereStudied. Two modes Of fatigue crack initiation were found. The Nd-rich phase particles displaybetter resistance to fatigue crack initiation than the matrix at lower stress.
文摘The Sr/F co-doped CaP(Sr/F-CaP)coatings were prepared by micro-arc oxidation(MAO)under different voltages to modify the microstructure and corrosion behavior of Mg-4Zn-1Mn alloy.The surface and interface characteristics investigated using scanning electron microscopy(SEM)and energy dispersive X-ray spectrometer(EDS)showed that the MAO coatings displayed uneven crater-like holes and tiny cracks under lower voltage,while they exhibited relatively homogeneous crater-like holes without cracks under higher voltage.The thickness of MAO coatings increased with increasing voltage.The corrosion behavior of Mg-4Zn-1Mn alloy was improved by the MAO coatings.The MAO coatings prepared under 450 V and 500 V voltages possessed the best corrosion resistance with regard to the electrochemical corrosion tests and immersion corrosion tests,respectively.The MAO coatings fabricated under 450-500 V could provide a better corrosion protection effect for the substrate.