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Shear localization behavior in hat-shaped specimen of near-αTi−6Al−2Zr−1Mo−1V titanium alloy loaded at high strain rate 被引量:4
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作者 Yu-xuan DU Xin-liang YANG +6 位作者 Zu-shu LI Fang HAO You-chuan MAO Shao-qiang LI Xiang-hong LIU Yong FENG Zhi-ming YAN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第6期1641-1655,共15页
The microstructure characteristics in early stage shear localization of near-αTi−6Al−2Zr−1Mo−1V titanium alloy were investigated by split Hopkinson pressure bar(SHPB)tests using hat-shaped specimens.The microstructur... The microstructure characteristics in early stage shear localization of near-αTi−6Al−2Zr−1Mo−1V titanium alloy were investigated by split Hopkinson pressure bar(SHPB)tests using hat-shaped specimens.The microstructural evolution and deformation mechanisms of hat-shaped specimens were revealed by electron backscattered diffraction(EBSD)method.It is found that the nucleation and expansion of adiabatic shear band(ASB)are affected by both geometric and structural factors.The increase of dislocation density,structure fragment and temperature rise in the deformation-affected regions provide basic microstructural conditions.In addition to the dislocation slips,the extension twins detected in shear region also play a critical role in microstructural fragmentation due to twin-boundaries effect.Interestingly,the sandwich structure imposes a crucial influence on ASB,which finally becomes a mature wide ASB in the dynamic deformation.However,due to much larger width,the sandwich structure in the middle of shear region is also possible to serve as favorable nucleation sites for crack initiation. 展开更多
关键词 Ti−6Al−2Zr−1Mo−1V alloy adiabatic shear band split Hopkinson pressure bar hat-shaped specimen sandwich structure
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Characteristics of Faigue Crack Initiation in Ti-5Al-4Sn-2Zr-1Mo-0.7Nd-0.25Si Alloy
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作者 Jiafeng LEP Yuyin LIU +3 位作者 Shaoxuan GUAN Qingjiang WANG Zhongguang WANG Dong LI and Zhuangqi HU(State Key Lab. for Fatigue and Fracture of Materials, Institute of Metal Research, Chinese Academy of Sciences,Shenyan 110015, China) 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1997年第3期238-240,共3页
The characteristics of fatigue crack initiation in Ti-5AI-4Sn-2Zr1Mo-O.7Nd-O.25Si alloy wereStudied. Two modes Of fatigue crack initiation were found. The Nd-rich phase particles displaybetter resistance to fatigue cr... The characteristics of fatigue crack initiation in Ti-5AI-4Sn-2Zr1Mo-O.7Nd-O.25Si alloy wereStudied. Two modes Of fatigue crack initiation were found. The Nd-rich phase particles displaybetter resistance to fatigue crack initiation than the matrix at lower stress. 展开更多
关键词 SN Mo Characteristics of Faigue Crack Initiation in Ti-5Al-4Sn-2Zr-1Mo-0.7Nd-0.25Si alloy ZR TI Al Nd Si
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Experiment and modeling of TiB_(2)/TiB boride layer of Ti−6Al−2Zr−1Mo−1V alloy
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作者 De-lai OUYANG Sheng-wei HU +3 位作者 Cheng TAO Xia CUI Zhi-shou ZHU Shi-qiang LU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第12期3752-3761,共10页
The influence of the boriding conditions on the boride layers was examined by boriding Ti−6Al−2Zr−1Mo−1V alloy in the temperature range of 920−1120℃.The experimental results show that the boride layers were composed ... The influence of the boriding conditions on the boride layers was examined by boriding Ti−6Al−2Zr−1Mo−1V alloy in the temperature range of 920−1120℃.The experimental results show that the boride layers were composed of a continuous thin outer layer of TiB_(2) and a thick inner layer of TiB with whiskers or needle-like morphologies that extended into the substrate.Thick and compact boride layers were obtained when the boriding temperatures were 1000−1080℃,and the treatment time exceeded 8 h.The boride layer depth increased with the boriding temperature and time,and the growth kinetics of the boride layers was characterized by a parabolic curve.The growth kinetics of the boride layers,including both TiB_(2) and TiB layers,were predicted by establishing a diffusion model,which presented satisfactory consistency with the experimental data.As a result,the activation energies of boron in the TiB_(2) and TiB layers were estimated to be 223.1 and 246.9 kJ/mol,respectively. 展开更多
关键词 Ti−6Al−2Zr−1Mo−1V alloy BORIDING MICROSTRUCTURE modeling
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微结构对Zr_(0.7)Ti_(0.3)V_2合金氢化过程的影响 被引量:2
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作者 杨晓伟 李金山 +3 位作者 张铁邦 王旭峰 钟宏 薛祥义 《中国有色金属学报》 EI CAS CSCD 北大核心 2011年第5期1106-1110,共5页
采用SEM、EDS及XRD等分析手段研究Zr0.7Ti0.3V2合金的微观组织及相结构,通过定容法于673~823 K测试合金的吸氢性能。结果表明:合金吸氢前主要由C15型ZrV2相、α-Zr及具有BCC结构的富V的固溶体相组成,吸氢后生成V16Zr8H36.29、ZrH1.801... 采用SEM、EDS及XRD等分析手段研究Zr0.7Ti0.3V2合金的微观组织及相结构,通过定容法于673~823 K测试合金的吸氢性能。结果表明:合金吸氢前主要由C15型ZrV2相、α-Zr及具有BCC结构的富V的固溶体相组成,吸氢后生成V16Zr8H36.29、ZrH1.801和VH2.01等3种氢化物;压力-组成-温度(PCT)曲线显示,合金吸氢曲线具有较宽且平坦的平台特征。BCC相改善了吸氢动力学性能,HCP相使吸氢PCT曲线平台宽化,合金的多相结构有助于改善其吸氢性能。 展开更多
关键词 zr0.7ti0.3v2合金 AB2型 多相结构 吸氢动力学 PCT曲线
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(Ti_(0.7)Zr_(0.2)V_(0.1))Ni贮氢合金的电化学性能及氢致相变研究 被引量:3
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作者 王福山 王春生 +3 位作者 陈立新 雷永泉 王启东 吕光烈 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 1999年第2期73-76,共4页
研究了(Ti0.7Zr0.2V0.1)Ni合金的相结构和电化学性能。结果表明:在比较快的冷却条件下(真空电弧炉熔化,水冷铜坩埚凝固),合金铸态组织为具有B2结构(CsCl型)的单一奥氏体相;充氢使B2结构的奥氏体相转... 研究了(Ti0.7Zr0.2V0.1)Ni合金的相结构和电化学性能。结果表明:在比较快的冷却条件下(真空电弧炉熔化,水冷铜坩埚凝固),合金铸态组织为具有B2结构(CsCl型)的单一奥氏体相;充氢使B2结构的奥氏体相转变为单斜结构的马氏体相;反复电化学充放氢使Ti2Ni和Zr9Ni11相逐渐从母相中析出。在50mA/g放电倍率下,(Ti0.7Zr0.2V0.1)Ni合金的电化学容量可达380mAh/g,是TiNi二元合金的两倍。但经10次充放电循环后合金容量迅速衰退至200mAh/g。研究表明,(Ti0.7Zr0.2V0.1)Ni合金具有较高电化学容量主要是由于在TiNi相的催化作用下,具有高贮氢量的Ti2Ni相和Zr9Ni11相能可逆地吸放氢所致,而其较快的容量衰退则主要与Ti2Ni相的氧化有关。 展开更多
关键词 贮氢合金 电化学性能 氢致相变
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掺杂方式对Mg:Ba_(0.3)Sr_(0.7)Zr_(0.18)Ti_(0.82)O_3陶瓷微结构及性能的影响 被引量:1
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作者 孙晓剑 樊明雷 +2 位作者 张小山 曾静 余萍 《湖北大学学报(自然科学版)》 CAS 2013年第2期176-179,共4页
采用溶胶-凝胶法制备Ba0.3Sr0.7Zr0.18Ti0.82O3陶瓷粉末,以传统陶瓷制备工艺制备Mg元素掺杂的Ba0.3Sr0.7Zr0.18Ti0.82O3陶瓷.研究MgO掺杂量为1.6%(质量分数)时,MgO固相掺杂和Mg2+湿化学法掺杂两种不同的掺杂方式对Mg掺杂的Ba0.3Sr0.7Zr0... 采用溶胶-凝胶法制备Ba0.3Sr0.7Zr0.18Ti0.82O3陶瓷粉末,以传统陶瓷制备工艺制备Mg元素掺杂的Ba0.3Sr0.7Zr0.18Ti0.82O3陶瓷.研究MgO掺杂量为1.6%(质量分数)时,MgO固相掺杂和Mg2+湿化学法掺杂两种不同的掺杂方式对Mg掺杂的Ba0.3Sr0.7Zr0.18Ti0.82O3陶瓷显微结构及电学性能的影响.研究结果表明,当Mg掺杂量相同时,掺杂方式对Mg掺杂的Ba0.3Sr0.7Zr0.18Ti0.82O3陶瓷的显微结构和电学特性有显著的影响,相比纯的Ba0.3Sr0.7Zr0.18Ti0.82O3陶瓷,两种掺杂方式中,Mg2+湿化学法掺杂相对于MgO固相掺杂,在BSZT陶瓷中的分布更均匀,替位程度更高,所以其对介电常数的影响也相对更大.而MgO固相掺杂相对于Mg2+湿化学法掺杂明显地促进了陶瓷晶粒的生长,提高了陶瓷的致密性,同时其击穿电场和电阻率也有较大提高.1 350℃下烧结的固相MgO掺杂的Ba0.3Sr0.7Zr0.18Ti0.82O3陶瓷性能较优,介电常数约为590,介电损耗低于0.000 5,电阻率为7.78×1013Ω.mm,击穿场强为6.56kV/mm. 展开更多
关键词 Ba0.3Sr0.7Zr0.18Ti0.82O3陶瓷 MgO掺杂 Mg2+掺杂 介电性能
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球磨制备Ti_(0.8)Zr_(0.2)V_(2.7)Mn_(0.5)Cr_(0.7)Ni_(1.75)-15wt%A_2B_7复合储氢材料及其电化学性能研究 被引量:1
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作者 刘夏 罗永春 宋宏儒 《热加工工艺》 CSCD 北大核心 2008年第20期40-42,共3页
采用球磨和表面改性方法制备了复合储氢材料Ti0.8Zr0.2V2.7Mn0.5Cr0.7Ni1.75-15wt%La1.5Mg0.5Ni6.7Al0.3。研究和分析表明,钒基Ti0.8Zr0.2V2.7Mn0.5Cr0.7Ni1.7铸态合金由bcc结构固溶体相和六方晶系C14型Laves相构成三维网状组织,球磨改... 采用球磨和表面改性方法制备了复合储氢材料Ti0.8Zr0.2V2.7Mn0.5Cr0.7Ni1.75-15wt%La1.5Mg0.5Ni6.7Al0.3。研究和分析表明,钒基Ti0.8Zr0.2V2.7Mn0.5Cr0.7Ni1.7铸态合金由bcc结构固溶体相和六方晶系C14型Laves相构成三维网状组织,球磨改性后钒基合金与La1.5Mg0.5Ni6.7Al0.3之间并未发生合金化反应。电化学性能研究表明,经球磨改性后复合材料Ti0.8Zr0.2V2.7Mn0.5Cr0.7Ni1.75-15wt%La1.5Mg0.5Ni6.7Al0.3能明显增加合金的电极放电容量。铸态钒基合金和球磨复合材料均具有良好的电化学循环稳定性,其中球磨1h后电极最大放电容量为300.1mA/g,经100次循环后的电化学容量保持率为97.2%,球磨5h后试样的循环稳定性高达99%。 展开更多
关键词 机械球磨 球磨制备Ti0.8Zr0.2V2.7Mn0.5Cr0.7Ni1.75-15wt%Mg0.5Ni6.7Al0.3合金 储氢 改性 电化学性能
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