As a kind of efficient photocatalyst,coordination polymers(CPs) have gained much attention in recent years.However,their safety issue and time-consuming synthesis impede their practical application.Here in this paper ...As a kind of efficient photocatalyst,coordination polymers(CPs) have gained much attention in recent years.However,their safety issue and time-consuming synthesis impede their practical application.Here in this paper we first demonstrate the facile synthesis and photocatalytic degradation performance of 1D α-ferrous oxalate dihydrate(α-FOD),which is one of the simplest CPs.A unique two-pathway photocatalytic mechanism which combines traditional photocatalytic and photo-initiated Fenton oxidations has been proposed.The excellent photocatalytic performance and cost-effective fabrication make α-FOD a new promising candidate for the photocatalytic degradation of organic pollutants in practical applications.展开更多
基金supported by the National Key Basic Research Program of China(2013CB933200)the National High-tech R&D Program of China(2012AA062703)+1 种基金Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM)the Youth Innovation Promotion Association CAS(2012200)
文摘As a kind of efficient photocatalyst,coordination polymers(CPs) have gained much attention in recent years.However,their safety issue and time-consuming synthesis impede their practical application.Here in this paper we first demonstrate the facile synthesis and photocatalytic degradation performance of 1D α-ferrous oxalate dihydrate(α-FOD),which is one of the simplest CPs.A unique two-pathway photocatalytic mechanism which combines traditional photocatalytic and photo-initiated Fenton oxidations has been proposed.The excellent photocatalytic performance and cost-effective fabrication make α-FOD a new promising candidate for the photocatalytic degradation of organic pollutants in practical applications.
