Rate Law for Photoelectrochemical Water Splitting Over CuO

Photocatalytic splitting of water over p-type semiconductors is a promising strategy for production of hydrogen.However,the determination of rate law is rarely reported.To this purpose,copper oxide(CuO)is selected as a model photocathode in this study,and the photogenerated surface charge density,interfacial charge transfer rate constant and their relation to the water reduction rate(in terms of photocurrent)were investigated by a combination of(photo)electrochemical techniques.The results showed that the charge transfer rate constant is exponential-dependent on the surface charge density,and that the photocurrent equals to the product of the charge transfer rate constant and surface charge density.The reaction is first-order in terms of surface charge density.Such an unconventional rate law contrasts with the reports in literature.The charge density-dependent rate constant results from the Fermi level pinning(i.e.,Galvani potential is the main driving force for the reaction)due to accumulation of charge in the surface states and/or Frumkin behavior(i.e.,chemical potential is the main driving force).This study,therefore,may be helpful for further investigation on the mechanism of hydrogen evolution over a CuO photocathode and for designing more efficient CuO-based photocatalysts.

Rate transient analysis methods for water-producing gas wells in tight reservoirs with mobile water

Tight gas reservoirs with mobile water exhibit multi-phase flow and high stress sensitivity.Accurately analyzing the reservoir and well parameters using conventional single-phase rate transient analysis methods proves challenging.This study introduces novel rate transient analysis methods incorporating evaluation processes based on the conventional flowing material balance method and the Blasingame type-curve method to examine fractured gas wells producing water.By positing a gas-water two-phase equivalent homogenous phase that considers characteristics of mobile water,gas,and high stress sensitivity,the conventional single-phase rate transient analysis methods can be applied by integrating the phase's characteristics and defining the phase's normalized parameters and material balance pseudotime.The rate transient analysis methods based on the equivalent homogenous phase can be used to quantitatively assess the parameters of wells and gas reservoirs,such as original gas-in-place,fracture half-length,reservoir permeability,and well drainage radius.This facilitates the analysis of production dynamics of fractured wells and well-controlled areas,subsequently aiding in locating residual gas and guiding the configuration of well patterns.The specific evaluation processes are detailed.Additionally,a numerical simulation mechanism model was constructed to verify the reliability of the developed methods.The methods introduced have been successfully implemented in field water-producing gas wells within tight gas reservoirs containing mobile water.

Numerical Simulation on Radon Retardation Behavior of Covering Floats in Radon-Containing Water

Objective This study aimed to efficiently reduce the release of radon from water bodies to protect the environment.Methods Based on the sizes of the experimental setup and modular float,computational fluid dynamics(CFD)was used to assess the impact of the area coverage rate,immersion depth,diffusion coefficient,and radon transfer velocity at the gas–liquid interface on radon migration and exhalation of radon-containing water.Based on the numerical simulation results,an estimation model for the radon retardation rate was constructed.The effectiveness of the CFD simulation was evaluated by comparing the experimental and simulated variation values of the radon retardation rate with the coverage area rates.Results The effect of radon transfer velocity on radon retardation in water bodies was minor and insignificant according to the appropriate value;therefore,an estimation model of the radon retardation rate of the coverage of a radon-containing water body was constructed using the synergistic impacts of three factors:area coverage rate,immersion depth,and diffusion coefficient.The deviation between the experimental and simulated results was<4.3%.Conclusion Based on the numerical simulation conditions,an estimation model of the radon retardation rate of covering floats in water bodies under the synergistic effect of multiple factors was obtained,which provides a reference for designing covering floats for radon retardation in radoncontaining water.

Influence of O-O formation pathways and charge transfer mediator on lipid bilayer membrane-like photoanodes for water oxidation

Inspired by the function of crucial components in photosystemⅡ(PSⅡ),electrochemical and dyesensitized photoelectrochemical(DSPEC)water oxidation devices were constructed by the selfassembly of well-designed amphipathic Ru(bda)-based catalysts(bda=2,2'-bipyrdine-6,6'-dicarbonoxyl acid)and aliphatic chain decorated electrode surfaces,forming lipid bilayer membrane(LBM)-like structures.The Ru(bda)catalysts on electrode-supported LBM films demonstrated remarkable water oxidation performance with different O-O formation mechanisms.However,compared to the slow charge transfer process,the O-O formation pathways did not determine the PEC water oxidation efficiency of the dyesensitized photoanodes,and the different reaction rates for similar catalysts with different catalytic paths did not determine the PEC performance of the DSPECs.Instead,charge transfer plays a decisive role in the PEC water oxidation rate.When an indolo[3,2-b]carbazole derivative was introduced between the Ru(bda)catalysts and aliphatic chain-modified photosensitizer in LBM films,serving as a charge transfer mediator for the tyrosine-histidine pair in PSⅡ,the PEC water oxidation performance of the corresponding photoanodes was dramatically enhanced.

Towards a new avenue for rapid synthesis of electrocatalytic electrodes via laser-induced hydrothermal reaction for water splitting

Electrochemical production of hydrogen from water requires the development ofelectrocatalysts that are active,stable,and low-cost for water splitting.To address these challenges,researchers are increasingly exploring binder-free electrocatalytic integratedelectrodes (IEs) as an alternative to conventional powder-based electrode preparation methods,for the former is highly desirable to improve the catalytic activity and long-term stability for large-scale applications of electrocatalysts.Herein,we demonstrate a laser-inducedhydrothermal reaction (LIHR) technique to grow NiMoO4nanosheets on nickel foam,which is then calcined under H2/Ar mixed gases to prepare the IE IE-NiMo-LR.This electrode exhibits superior hydrogen evolution reaction performance,requiring overpotentials of 59,116 and143 mV to achieve current densities of 100,500 and 1000 mA·cm-2.During the 350 h chronopotentiometry test at current densities of 100 and 500 m A·cm-2,the overpotentialremains essentially unchanged.In addition,NiFe-layered double hydroxide grown on Ni foam is also fabricated with the same LIHR method and coupled with IE-NiMo-IR to achieve water splitting.This combination exhibits excellent durability under industrial current density.The energy consumption and production efficiency of the LIHR method are systematicallycompared with the conventional hydrothermal method.The LIHR method significantly improves the production rate by over 19 times,while consuming only 27.78%of the total energy required by conventional hydrothermal methods to achieve the same production.

Gas-Water Production of a Continental Tight-Sandstone Gas Reservoir under Different Fracturing Conditions

A numerical model of hydraulic fracture propagation is introduced for a representative reservoir(Yuanba continental tight sandstone gas reservoir in Northeast Sichuan).Different parameters are considered,i.e.,the interlayer stress difference,the fracturing discharge rate and the fracturing fluid viscosity.The results show that these factors affect the gas and water production by influencing the fracture size.The interlayer stress difference can effectively control the fracture height.The greater the stress difference,the smaller the dimensionless reconstruction volume of the reservoir,while the flowback rate and gas production are lower.A large displacement fracturing construction increases the fracture-forming efficiency and expands the fracture size.The larger the displacement of fracturing construction,the larger the dimensionless reconstruction volume of the reservoir,and the higher the fracture-forming efficiency of fracturing fluid,the flowback rate,and the gas production.Low viscosity fracturing fluid is suitable for long fractures,while high viscosity fracturing fluid is suitable for wide fractures.With an increase in the fracturing fluid viscosity,the dimensionless reconstruction volume and flowback rate of the reservoir display a non-monotonic behavior,however,their changes are relatively small.

Advances in Research on Water and Fertilizer Coupling and Its Effects on Rice Growth and Utilization Rate of Nitrogen

At present, the shortage of agricuItural water resources is worsening. In order to reduce the rice irrigation water and improve the utiIization of fertiIizers so as to achieve the high and stabIe yielding of rice, this report reviewed the research advances in water and fertiIizer coupIing, the conception of water and fertiIizer cou-pIing and its three kinds of effects （synergy, antagonism, superposition）, mechanism of water and fertiIizer coupIing, effects of water and fertiIizer coupIing on growth, deveIopment, yield and quality of rice and effects of water and fertiIizer coupIing on utiIization rate of nitrogen in rice. In addition, the deveIopment prospects of water and fertiIizer coupIing in China were described. It was proposed that the water and fertiIizer coupIing mode is an effective measure to achieve the high yield and quality of rice. According to actual demand, referring to the ideas of promoting fertiIizer with water and reguIating water with fertiIizer, reasonabIe water and fertiIizer cou-pIing mode can be estabIished, thereby improving the utiIization efficiencies of water and fertiIizer. In the premise of saving irrigation water and no increasing fertiIization amount, both high yielding and Iess poI ution can be achieved, providing theoretical and technical basis for water-saving agricuIture and cuItivation and management of rice in future.

Effect of water stress on N_2O emission rate of 5 tree species

The N2O emission rates, photosynthesis, respiration and stomatal conductance of the dominant tree species from broadleaf/Korean pine forest in Changbai Mountain were measured by simulated water stress with the closed bag-gas chromatography. A total of five species seedlings were involved in this study, i.e.,Pinus koraiensis Sieb. et Zucc,Fraxinus mandshurica Rupr,Juglans mandshurica Maxim,Tilia amurensis Rupr, andQuercus mongolica Fisch. ex Turcz.. The results showed that the stomatal conductance, net photosynthetic rate and N2O emission of leaves were significantly reduced under the water stress. The stoma in the leaves of trees is the main pathway of N2O emission. N2O emission in the trees mainly occurred during daytime. N2O emission rates were different in various tree specie seedlings at the same water status. In the same tree species, N2O emission rates decreased as the reduction of soil water contents. At different soil water contents (MW, LW) the N2O emission rates ofPinus koraiensis decreased by 34.43% and 100.6% of those in normal water condition, respectively. In broadleaf arbor decreased by 31.93% and 86.35%, respectively. Under different water stresses N2O emission rates in five tree species such asPinus koraiensis, Fraxinus mandshurica, Juglans mandshurica, Tilia amurensis, andQuercus mongolica were 38.22, 14.44, 33.02, 16.48 and 32.33 ngN2O·g?1DW·h?1, respectively. Keywords Trees - N2O emission rate - Soil water stress - broadleaf/Korean pine forest - Changbai Mountain CLC number S718.55 Document code A Foundation item: This project was supported by the National Natural Science Foundation of China (No. 30271068), the grant of the Knowledge Innovation Program of Chinese Academy of Sciences (KZ-CX-SW-01-01B-10), and the Special Funds for Major State Basic Research Program of China (No. G1999043407)Biography: Wang Miao (1964-), male, associate professor in Institute of Applied Ecology, Chinese Academy of Science, Shenyang 110016, P. R. China.Responsible editor: Song Funan

Optimization of sowing date and seeding rate for high winter wheat yield based on pre-winter plant development and soil water usage in the Loess Plateau,China

Sowing date and seeding rate are critical for productivity of winter wheat(Triticum aestivum L.).A three-year field experiment was conducted with three sowing dates(20 September(SD1),1 October(SD2),and 10 October(SD3)) and three seeding rates(SR67.5,SR90,and SR112.5) to determine suitable sowing date and seeding rate for high wheat yield.A large seasonal variation in accumulated temperature from sowing to winter dormancy was observed among three growing seasons.Suitable sowing dates for strong seedlings before winter varied with the seasons,that was SD2 in 2012–2013,SD3 in 2013–2014,and SD2 as well as SD1 in 2014–2015.Seasonal variation in precipitation during summer fallow also had substantial effects on soil water storage,and consequently influenced grain yield through soil water consumption from winter dormancy to maturity stages.Lower consumption of soil water from winter dormancy to booting stages could make more water available for productive growth from anthesis to maturity stages,leading to higher grain yield.SD2 combined with SR90 had the lowest soil water consumption from winter dormancy to booting stages in 2012–2013 and 2014–2015; while in 2013–2014,it was close to that with SR67.5 or SR112.5.For productive growth from anthesis to maturity stages,SD2 with SR90 had the highest soil water consumption in all three seasons.The highest water consumption in the productive growth period resulted in the best grain yield in both low and high rainfall years.Ear number largely contributed to the seasonal variation in grain yield,while grain number per ear and 1 000-grain weight also contributed to grain yield,especially when soil water storage was high.Our results indicate that sowing date and seeding rate affect grain yield through seedling development before winter and also affect soil water consumption in different growth periods.By selecting the suitable sowing date(1 October) in combination with the proper seeding rate of 90 kg ha–1,the best yield was achieved.Based on these results,we recommend that the current sowing date be delayed from 22 or 23 September to 1 October.

Effects of water intrusion and loading rate on mechanical properties of and crack propagation in coal–rock combinations

Tackling the problems of underground water storage in collieries in arid regions requires knowledge of the effect of water intrusion and loading rate on the mechanical properties of and crack development in coal–rock combinations. Fifty-four coal–rock combinations were prepared and split equally into groups containing different moisture contents(dry, natural moisture and saturated) to conduct acoustic emission testing under uniaxial compression with loading rates ranging from 0.1 mm/min to 0.6 mm/min. The results show that the peak stress and strength-softening modulus, elastic modulus, strain-softening modulus, and post-peak modulus partly decrease with increasing moisture content and loading rate. In contrast, peak strain increases with increasing moisture content and fluctuates with rising loading rate. More significantly, the relationship between stiffness and stress, combined with accumulated counts of acoustic emission, can be used to precisely predict all phases of crack propagation. This is helpful in studying the impact of moisture content and loading rate on crack propagation and accurately calculating mechanical properties. We also determined that the stress thresholds of crack closure, crack initiation, and crack damage do not vary with changes of moisture content and loading rate, constituting 15.22%, 32.20%, and 80.98% of peak stress, respectively. These outcomes assist in developing approaches to water storage in coal mines, determining the necessary width of waterproof coal–rock pillars, and methods of supporting water-enriched roadways, while also advances understanding the mechanical properties of coal–rock combinations and laws of crack propagation.

Relationship between Formation Water Rate,Equivalent Penetration Rate and Volume Flow Rate of Air in Air Drilling

Formation water invasion is the most troublesome problem associated with air drilling. However, it is not economical to apply mist drilling when only a small amount of water flows into wellbore from formation during air drilling. Formation water could be circulated out of the wellbore through increasing the gas injection rate. In this paper, the Angel model was modified by introducing Nikurade friction factor for the flow in coarse open holes and translating formation water rate into equivalent penetration rate. Thus the distribution of annular pressure and the relationship between minimum air injection rate and formation water rate were obtained. Real data verification indicated that the modified model is more accurate than the Angel model and can provide useful information for air drilling.

Variability of subduction rates of the subtropical North Pacific mode waters

The climatology subduction rate for the entire Pacific is known, but the mechanism of interannual to decadal variation remains unclear. In this study, we calculated the annual subduction rates of three types of North Pacific subtropical mode waters using a general circulation model (LICOM1.0) for the period of 1958-2001. The model experiments focused on interannual variations of ocean dynamical processes under daily wind forcings and seasonal heat fluxes. The mode water formation region was defined by a potential vorticity minimum at outcrop locations. The model results show that two subduction rate maxima (>100 m/a) were located in the Subtropical Mode Water (STMW) and the Central Mode Water (CMW) formation regions. These regions are consistent with a climatologically calculated value. The subduction rate in the Eastern Subtropical Mode Water (ESTMW) formation region was smaller at about 75 m/a. The subduction rate shows clear interannual and decadal variations associated with oceanic dynamic variabilities. The average subduction rate of the STMW was much smaller during the period of 1981-1990 compared with other periods, while that of the CMW had a negative anomaly before 1975 and a positive anomaly after 1978. The variability agreed with Ekman and geostrophic advections and mixed layer depths. The interannual variability of the subduction rate for the ESTMW was smallest during 1970-1990, as a result of a weak wind stress curl. This paper explores how interannual signals from the atmosphere are stored in different parts of the ocean, and thus may contribute to a better understanding of feedback mechanisms for the Pacific Decadal Oscillation (PDO) event.

Prediction of Trend between Water Environment Pollution of D Lake and Death Rate of Malignancy in Population

Grey system analysis method was used to study the correlation between water pollution in D Lake area and death rate of malignancy with death rate of malignancy as effect sequence and a variety of water pollution index as factor sequence. On the basis of grey correlation analysis, grey system predication model was established for death rate of malignancy in population in D Lake area including GM (1, N) model for death rate of malignancy [ MR (t+1) =(9.9987E 1+5.0001E 2 +10.8994E 3+1.1114E 4+165.1029) ·e -0.0070t -9.9987E 1-5.0001E 2-10.8994E 3-1.1114E 4 ] and GM (1, 1) model for related factors [ E 1(t+1) =52.1214-46.9468e -0.0058t , E 2(t+1) =4.6114-4.5664e 0.0015t, E 3(t+1) =1.1389-1.1212e 0.0065t , E 4(t+1) = 554.5867-549.8006e 0.0016t ], and the trend of death rate of malignancy from 2000 to 2010 was predicted.

EFFECTS OF TEMPERATURE AND DISSOLVED OXYGEN CONTENT ONOXYGEN CONSUMPTION RATE OF CHINESE PRAWN, GIANT TIGER PRAWN AND GIANT FRESHWATER PRAWN

temperature and the diasolved oxygen content affect the oxygen consumption of juveniles of Chinese prawn (Penaeus chinensis), giant tiger prawn (P. monodon) and giant freshwater prawn(Macrobrachium rosenbergii). There is good correlation between the oxygen consumption rate (V, mg/g·h) of the above three prawn species and the water temperature, and dissolved oxygen. In the range of test temperature, V increased with water temperature and diassolved oxygen content. The V of the above three prawn species increased 0.085 mg/g·h, 0. 093 mg/g·h and 0. 08 mg/g·h respectively with each ℃ of rising temperature. The comatose point and stifling point of the juveniles rose obviously at unsuitable temperature.

Leakage Rate Model of Urban Water Supply Networks Using Principal Component Regression Analysis

To analyze the factors affecting the leakage rate of water distribution system, we built a macroscopic "leakage rate–leakage factors"(LRLF) model. In this model, we consider the pipe attributes(quality, diameter,age), maintenance cost, valve replacement cost, and annual average pressure. Based on variable selection and principal component analysis results, we extracted three main principle components—the pipe attribute principal component(PAPC), operation management principal component, and water pressure principal component. Of these, we found PAPC to have the most influence. Using principal component regression, we established an LRLF model with no detectable serial correlations. The adjusted R2 and RMSE values of the model were 0.717 and 2.067, respectively.This model represents a potentially useful tool for controlling leakage rate from the macroscopic viewpoint.

Surface warming patterns dominate the uncertainty in global water vapor plus lapse rate feedback

Climate feedbacks have been usually estimated using changes in radiative effects associated with increased global-mean surface temperature. Feedback uncertainties, however, are not only functions of global-mean surface temperature increase. In projections by global climate models, it has been demonstrated that the geographical variation of sea surface temperature change brings significant uncertainties into atmospheric circulation and precipitation responses at regional scales. Here we show that the spatial pattern of surface warming is a major contributor to uncertainty in the combined water vapour-lapse rate feedback. This is demonstrated by computing the global-mean radiative effects of changes in air temperature and relative humidity simulated by 31 climate models using a methodology based on radiative kernels. Our results highlight the important contribution of regional climate change to the uncertainty in climate feedbacks, and identify the regions of the world where constraining surface warming patterns would be most effective for higher skill of climate projections.

Effects of water saturation and loading rate on direct shear tests of andesite

For estimating the long-term stability of underground framework,it is vital to learn the mechanical and rheological characteristics of rock in multiple water saturation conditions.However,the majority of previous studies explored the rheological properties of rock in air-dried and water saturated conditions,as well as the water effects on compressive and tensile strengths.In this study,andesite was subjected to direct shear tests under five water saturation conditions,which were controlled by varying the wetting and drying time.The tests were conducted at alternating displacement rates under three vertical stresses.The results reveal that the shear strength decreases exponentially as water saturation increases,and that the increase in shear strength with a tenfold increase in displacement rate is nearly constant for each of the vertical stresses.Based on the findings of the shear tests in this study and the compression and tension tests in previous studies,the influences of both water saturation and loading rate on the Hoek-Brown failure criterion for the andesite was examined.These results indicate that the brittleness index of the andesite,which is defined as the ratio of uniaxial compressive strength to tensile strength,is independent of both water saturation and loading rate and that the influences of the water saturation dependence and the loading rate dependence of the failure criterion can be converted between each other.

Metabolic rate and evaporative water loss in the silky starling （Sturnus sericeus）

To better understand the physiological characteristics of the silky starling（Sturnus sericeus）, its body temperature（Tb）, basal metabolic rate（BMR）, evaporative water loss（EWL） and thermal conductance（C） elicited by different ambient temperatures（Ta）（5-30 ℃） were determined in the present study. Our results showed that they have a high Tb（41.6±0.1 ℃）, a wide thermal neutral zone（TNZ）（20-27.5 ℃） and a relatively low BMR within the TNZ（3.37±0.17 mL O2/g·h）. The EWL was nearly stable below the TNZ（0.91±0.07 mg H2O/g·h） but increased remarkably within and above the TNZ. The C was constant below the TNZ, with a minimum value of 0.14±0.01 mL O2/g·h·℃. These findings indicate that the BMR, Tb and EWL of the silky starling were all affected by Ta, especially when Ta was below 20℃ and the EWL plays an important role in thermal regulation.

The critical rate of horizontal wells in bottom-water reservoirs with an impermeable barrier

Barrier impacts on water cut and critical rate of horizontal wells in bottom water-drive reservoirs have been recognized but not investigated quantitatively. Considering the existence of impermeable barriers in oil formations, this paper developed a horizontal well flow model and obtained mathematical equations for the critical rate when water cresting forms in bottom-water reservoirs. The result shows that the barrier increases the critical rate and delays water breakthrough. Further study of the barrier size and location shows that increases in the barrier size and the distance between the barrier and oil-water contact lead to higher critical rates. The critical rate gradually approaches a constant as the barrier size increases. The case study shows the method presented here can be used to predict the critical rate in a bottom-water reservoir and applied to investigate the water cresting behavior of horizontal wells.

Reuse rate of treated wastewater in water reuse system

A water quality model for water reuse was made by mathematics induction. The relationship among the reuse rate of treated wastewater（R）, pollutant concentration of reused water（ Cs ）, pollutant concentration of influent（ C0）, removal efficiency of pollutant in wastewater（ E）, and the standard of reuse water were discussed in this study. According to the experiment result of a toilet wastewater treatment and reuse with membrane bioreactors, R would be set at less than 40%, on which all the concerned parameters could meet with the reuse water standards. To raise R of reuse water in the toilet, an important way was to improve color removal of the wastewater.