An evaluation of the bioavailability and bioaccumulation of selected metalso ccurring in a wetland area on the volcanic island of Guam,Western Pacific Ocean

This initial research examined the presence, distribution and bioavailability of Cu, Cr, Ni, Mn and Fe in a wetland area of southern Guam. The research sites are within an area covered with saporite, a soil type derived from volcanic deposits on the island. Leaf tissue of Pandanus tectorius was extracted and analysed to determine the bioaccumulation of the target metals. Metal accumulation at sites considered aerobic and anaerobic was investigated together with an attempt to correlate actual accumulation of the target metals in the plant tissue with a recognised bioavailability indicator, in this case, three step sequential extraction scheme. Manganese was found to be accumulated in relatively high concentrations and to a lesser extent Cu was also accumulated. Chromium, Ni and Fe however exhibited very low accumulation factors. Accumulation of Mn in particular was significantly affected by aerobic conditions whereas the converse effect was experienced by Cu. Significant correlation between various steps of a Sequential Extraction Scheme and actual accumulation was not achieved although the degree of aerobic conditions at each site and soil pH did affect concentrations of metals extracted by differing steps of SES. Results obtained suggest that further research in the area should be undertaken using different plant species and tissues.

Accumulation of heavy metals in stemwood of forest tree plantations fertilized with different sewage sludge doses

The levels of heavy metals that accumulated in stemwood of mature trees grown for 20 years in a plantation in an abandoned peat quarry in areas that were fertilized with different amounts of domestic sewage sludge(180,360,and720 Mg ha-1on a dry basis) were compared with trees grown in a reference nonfertilized area.Included in the study was a hybrid poplar(Populus tremula x Populus tremuloides) developed for use as an energy crop,three local tree species and one introduced tree species.The concentrations of Cd,Cr,Cu,Ni,Pb and Zn in the stemwood of the trees grown in the fertilized and nonfertilized fields were determined,and found to be significantly lower than their respective concentrations in the soil.Cd and Cr were found only in several wood samples at concentrations close to the limits of detection or qualification; therefore,they were not analyzed further.A correlation analysis suggested that 75%of the correlations between the concentrations of heavy metals in the stemwood and the concentrations in the soil were negative.The ability of trees to accumulate the metals from soil in most cases decreased for Cu and Ni; however,the correlations were not as clear for Pb and Zn.The followingsequence for the levels of heavy metals found in the stemwood of the analysed trees was Zn [ Pb [ Ni [ Cu [(Cr,Cd).The results of this study showed that the levels of heavy metals in the studied wood would not exceed the permitted limits of heavy metal pollution in the air and ash when used for energy production.

Pollution characteristics of the recent sediments in the Hangzhou section of the Grand Canal,China

Spatial distribution of heavy metals, arsenic and organic matter in recent sediments in the Hangzhou section of the Grand Canal and their relationships were analyzed. The results showed that the concentrations of heavy metals and organic matters varied widely along the canal, and the average geological accumulation factors decreased in the following orders: organic carbon(2.6), zinc(2.1), cadmium(2.0), copper(1.5), lead(1.1), nitrogen(0.9), mercury (0.8), phosphorus(0.4), arsenic(0.2) and chromium(0). Content of heavy metals and organic carbon in the top 10 cm layer were lower than that of lower layers, except for mercury and organic carbon in the S9 section. Contents of organic carbon in the top 50 cm layer of the mud sediments are significantly higher than those underneath. In the bottom mud layer, there is a concentration peak of the pollutants. In the mud sediments of the canal, cadmium mainly occurred in the Fe and Mn oxide fraction, copper in the organic fraction, lead in the Fe and Mn oxide fraction, and zinc in the carbonate and the Fe and Mn oxide fraction.

Advances and problems in hydrocarbon exploration in the Tazhong area, Tarim Basin

Located in the middle of the Tarim Basin, Tazhong is a typical area of compound reservoirs rich in oil and gas found in the Carboniferous, Silurian and Ordovician strata. The proved, probable and possible reserves （3P reserves） in the area amount to 5×108 tons, so it is of great significance to study the advances and problems in hydrocarbon exploration in the Tazhong area. On the basis of exploration history and analysis of scientific problems, we outline eight achievements： distribution characteristics of reservoirs, stages of reservoir formation, different sources of oil and gas and their respective contributions, the effective regional caprock and reservoir-caprock combinations dominating the vertical distribution of hydrocarbon reservoirs, the control of the Tazhong Palaeo-uplift on reservoir formation and establishing geologic models, structure balance belts influencing the reconstruction and residual potential of reservoirs after accumulation, the rules and mechanisms of fractures controlling oil and gas, and the types of favorable reservoirs and their characteristics of controlling oil and gas distribution. We further point out the main problems about the oil and gas exploration in the Tazhong area and put forward some relevant proposals.

An Improved Analytic Hierarchy Process and Application in Grain Production

Value analysis of grain production influencing factors is a complex decision problem. This paper introduced a modified Analytic Hierarchy Process （AHP） accumulation factor, namely Solving Weight by AHP＇s Accumulation Factor Sequence Evaluating Data. We used the arithmetical average to replace the expert marking, so that the possible decision mistakes by the subjective judgments could be avoided. We computed the case with this method, which obtained attribute value of 17 influencing factors of the potential food production in Heilongjiang Province, and the result of which was reasonable

Accumulation and relationship of metals in different soil aggregate fractions along soil profiles

Different aggregates vary in their ability to retain or adsorb metals in soil.Five soil profiles were sampled from different soil horizons and grouped,and the concentrations of Al,Mg,Ca,Fe,Mn,Cd,Cu and Pb were determined in six sizes of aggregates(>2,2-1,1-0.6,0.6-0.25,0.25-0.053,<0.053 mm).Significantly high(p<0.05)structural stability indexes(SSI)and ag-gregate stability indexes(ASI)were recorded in the topsoil horizon,which may be attributed to the high soil organic matter(SOM)content in aggregates from topsoil.In addition,ASI and SSI were positively correlated(r=0.569,p<0.05)with each other,which indicated that the stability of soil aggregates could contribute to the structural stability of bulk soil.Moreover,accumulation factors(AF),principal component analysis(PCA)and Pearson's correlation co-efficients were used for metal element assessment.The results indicated that SOM was not a key factor affecting the accumulation of Ca,Mg,Al,Fe,Mn,Pb,Cd and Cu in soil aggre-gates.In general,AF values for metal elements in microaggregates(<0.25 mm)were high,which showed that metals preferred to accumulate in fine soil aggregates.The PCA and Pearson's correlation coefficients indicated that soil parent materials primarily controlled the distribution of Al,Ca,Fe,Mg and Mn,while materials derived from technogenic sources have important impacts on the distribution of Cd,Cu and Pb in soil aggregates along the soil profile.