The title complex [ZN8II(4-APha)8(CH3COO)8(CH3CH2OH)2]n (1, 4-APha = 4-ami- nophenylhydroxamic acid) has been prepared under solvothermal conditions. It has been characterized by X-ray single-crystal diffracti...The title complex [ZN8II(4-APha)8(CH3COO)8(CH3CH2OH)2]n (1, 4-APha = 4-ami- nophenylhydroxamic acid) has been prepared under solvothermal conditions. It has been characterized by X-ray single-crystal diffraction, IR and elemental analysis. The crystal belongs to the monoclinic system, space group C2/c with a = 39.074(4), b = 9.9645(8), c=38.846(3) A, β = 136.438°, V= 10423.1(14) A3, C84H118N16O39Zn8, Mr = 2498.90, Z = 4, Dc = 1.592 g/cm3,μ= 1.900 mm-1, F(000) = 5144, the final R = 0.1036 and wR = 0.2953. This complex possesses a 3-D structure which is constructed from 1-D chain motifs linked by the 4-APha" ligands. The luminescent property of the title complex has been investigated.展开更多
基金Supported by Department of Education of Shaanxi Province(2013JK0664)
文摘The title complex [ZN8II(4-APha)8(CH3COO)8(CH3CH2OH)2]n (1, 4-APha = 4-ami- nophenylhydroxamic acid) has been prepared under solvothermal conditions. It has been characterized by X-ray single-crystal diffraction, IR and elemental analysis. The crystal belongs to the monoclinic system, space group C2/c with a = 39.074(4), b = 9.9645(8), c=38.846(3) A, β = 136.438°, V= 10423.1(14) A3, C84H118N16O39Zn8, Mr = 2498.90, Z = 4, Dc = 1.592 g/cm3,μ= 1.900 mm-1, F(000) = 5144, the final R = 0.1036 and wR = 0.2953. This complex possesses a 3-D structure which is constructed from 1-D chain motifs linked by the 4-APha" ligands. The luminescent property of the title complex has been investigated.