In order to investigate how to enhance the teeth fracture resistance after the post and core treatment, an in vitro study was conducted to measure the fracture resistance of endodontically treated teeth restored with ...In order to investigate how to enhance the teeth fracture resistance after the post and core treatment, an in vitro study was conducted to measure the fracture resistance of endodontically treated teeth restored with cast post and core with two kinds of surface treatment technology and acid etching preparation on the dentinal surface. Sixty-four recently extracted human single-rooted first premolars were endodontically treated and sectioned approximately 1.5 mm above the cementoenamel junction to remove the coronal portion. Each specimen received a cast post, core build-up and a metal alloy crown restoration. All teeth were randomly divided into the smooth surface post, core repair group, the sand blasting surface post, and core repair group, each group was divided into 10 s, 30 s, 60 s acid corrosion treatment group and control group. In acid test groups, an acid etching solution was applied for 10, 30 and 60 seconds, respectively, to the root canal wall surface. Each specimen was embedded in acrylic resin block and tested in an electronic universal testing machine. Fracture loads results showed that canal acid etching could increase teeth fracture resistance strength both in smooth groups and sandblasting group, and achieved the best effect when acid etching for 30 s. Sand spray treatment on the surface of the cast metal post can improve the flexural strength of the teeth after postcrown restoration. Acid etching on the root canal wall surfaces and sand spray treatment on the surface of the cast metal post can improve the flexural strength of the root after post-crown restoration. Therefore, these two methods could be used to strengthen the tooth fracture resistance, and maintain the long-term therapeutic effect of cast post and core restoration.展开更多
The sea ice core (1. 6m) and lake ice core (1. 5m) were taken respectively from sea sampling site and Ace Lake near Davis Station, Vestfold Hills, Antarctica in November and October, 1988. The concentrations of amino ...The sea ice core (1. 6m) and lake ice core (1. 5m) were taken respectively from sea sampling site and Ace Lake near Davis Station, Vestfold Hills, Antarctica in November and October, 1988. The concentrations of amino acids in each 10cm of ice cores were determined by High Pressure Liquid Chromatography (HPLC). The results showed that the concentrations of amino acids revealed seasonal variation during the year. The highest concentration of amino acids, which was 30. 92 /μmol/ml, were found in the bottom of sea ice core, and it was approximately 45 μmol/ml in the lake ice core. The lowest concentration was approximately 8. 0μmol/ml which is presented in surface of the sea ice core, but it was 14.0μmol/ml which was found in 60cm section of lake ice core.The seasonal variation process of concentration of amino acids were much similar to that of phytoplankton cells number in sea ice core, and the distribution and seasonal variation rate of individual amino acids were also much similar in each ice core sections. We suggest that the uniform spectrum of amino acids is probably derived from a peptide cell source and those amino acids were not utilized by organism.展开更多
In this study, a novel core-shell structure of ZSM-5@Mg(Al)O(abbreviated as Z@MA) was designed by using the sol-gel method, and the influence of different weight ratios of Mg(Al)O/ZSM-5 on the structure and catalytic ...In this study, a novel core-shell structure of ZSM-5@Mg(Al)O(abbreviated as Z@MA) was designed by using the sol-gel method, and the influence of different weight ratios of Mg(Al)O/ZSM-5 on the structure and catalytic performance was investigated. The as-obtained materials were characterized by XRD, N_2-physisorption, SEM, FT-IR, NH_3-TPD and XPS analyses. The results showed that, with the increase of the weight ratio of Mg(Al)O/ZSM-5, the thickness of Mg(Al)O shell was improved, and the pore structure and physiochemical properties of core-shell materials were directly modified. After introduction of Mg(Al)O, the acidity properties of different materials were significantly suppressed. Meanwhile, more Sn oxide species in Z@MA could facilitate the anchoring of Pt on the support. By effectively employing these modifications, the capacity of the catalysts to accommodate coke was significanty improved and the carbon deposits were migrated from active metal to the carrier. When the weight ratio was equal to 3, the catalyst PtSnNa/Z@MA showed a highest conversion and high selectivity in propane dehydrogenation.展开更多
基金Funded by the Construction Engineering Special Fund of Taishan Scholars(No.201511106)the Youth Scientific Research Funds of School of Stomatology,Shandong University(No.2018QNJJ01)+1 种基金Shandong Medical and Health Science and Technology Development Plan(No.2017WS112)National Key Research and Development Program of China(No.2016YFC1102705)
文摘In order to investigate how to enhance the teeth fracture resistance after the post and core treatment, an in vitro study was conducted to measure the fracture resistance of endodontically treated teeth restored with cast post and core with two kinds of surface treatment technology and acid etching preparation on the dentinal surface. Sixty-four recently extracted human single-rooted first premolars were endodontically treated and sectioned approximately 1.5 mm above the cementoenamel junction to remove the coronal portion. Each specimen received a cast post, core build-up and a metal alloy crown restoration. All teeth were randomly divided into the smooth surface post, core repair group, the sand blasting surface post, and core repair group, each group was divided into 10 s, 30 s, 60 s acid corrosion treatment group and control group. In acid test groups, an acid etching solution was applied for 10, 30 and 60 seconds, respectively, to the root canal wall surface. Each specimen was embedded in acrylic resin block and tested in an electronic universal testing machine. Fracture loads results showed that canal acid etching could increase teeth fracture resistance strength both in smooth groups and sandblasting group, and achieved the best effect when acid etching for 30 s. Sand spray treatment on the surface of the cast metal post can improve the flexural strength of the teeth after postcrown restoration. Acid etching on the root canal wall surfaces and sand spray treatment on the surface of the cast metal post can improve the flexural strength of the root after post-crown restoration. Therefore, these two methods could be used to strengthen the tooth fracture resistance, and maintain the long-term therapeutic effect of cast post and core restoration.
文摘The sea ice core (1. 6m) and lake ice core (1. 5m) were taken respectively from sea sampling site and Ace Lake near Davis Station, Vestfold Hills, Antarctica in November and October, 1988. The concentrations of amino acids in each 10cm of ice cores were determined by High Pressure Liquid Chromatography (HPLC). The results showed that the concentrations of amino acids revealed seasonal variation during the year. The highest concentration of amino acids, which was 30. 92 /μmol/ml, were found in the bottom of sea ice core, and it was approximately 45 μmol/ml in the lake ice core. The lowest concentration was approximately 8. 0μmol/ml which is presented in surface of the sea ice core, but it was 14.0μmol/ml which was found in 60cm section of lake ice core.The seasonal variation process of concentration of amino acids were much similar to that of phytoplankton cells number in sea ice core, and the distribution and seasonal variation rate of individual amino acids were also much similar in each ice core sections. We suggest that the uniform spectrum of amino acids is probably derived from a peptide cell source and those amino acids were not utilized by organism.
文摘In this study, a novel core-shell structure of ZSM-5@Mg(Al)O(abbreviated as Z@MA) was designed by using the sol-gel method, and the influence of different weight ratios of Mg(Al)O/ZSM-5 on the structure and catalytic performance was investigated. The as-obtained materials were characterized by XRD, N_2-physisorption, SEM, FT-IR, NH_3-TPD and XPS analyses. The results showed that, with the increase of the weight ratio of Mg(Al)O/ZSM-5, the thickness of Mg(Al)O shell was improved, and the pore structure and physiochemical properties of core-shell materials were directly modified. After introduction of Mg(Al)O, the acidity properties of different materials were significantly suppressed. Meanwhile, more Sn oxide species in Z@MA could facilitate the anchoring of Pt on the support. By effectively employing these modifications, the capacity of the catalysts to accommodate coke was significanty improved and the carbon deposits were migrated from active metal to the carrier. When the weight ratio was equal to 3, the catalyst PtSnNa/Z@MA showed a highest conversion and high selectivity in propane dehydrogenation.
