Soap-free poly（methyl methacrylate-ethyl acrylate-methacrylic acid） latex particles with narrow size distribution were synthesized by seeded emulsion polymerization, and the porous particles were created by a stepwi...Soap-free poly（methyl methacrylate-ethyl acrylate-methacrylic acid） latex particles with narrow size distribution were synthesized by seeded emulsion polymerization, and the porous particles were created by a stepwise alkali/acid treatment method. Effects of acid treatment conditions on the particle morphology were investigated. Results show that one to three pores were formed inside most of particles after post-treatment. At pH 7.0, when the treatment temperature was lower than 70℃, the size of particles and the volume of pores remained almost unchanged, and these two values increased significantly when the temperature was higher than 70℃. Both the particle size and the pore volume decreased with the increase of initial pH value and treatment time in the acid treatment. As the pH was below 4.0 and the treatment time was longer than 180 min, the particles shrunk in size.展开更多
The aim of this study was to select sheep fat from Tsetserleg sum of Arkhangai aimag as raw material and to produce liquid soap. The oil was extracted from raw materials such as sheep’s tail fat (TF), outer fat (OF),...The aim of this study was to select sheep fat from Tsetserleg sum of Arkhangai aimag as raw material and to produce liquid soap. The oil was extracted from raw materials such as sheep’s tail fat (TF), outer fat (OF), and inner fat (IF), which were analyzed by chemical methods, and the liquid soap was obtained by cold methods. Liquid soap was prepared from three types of raw materials, each of which was mixed with 70% fat oil and 30% liquid oil. The ratio was chosen to dilute the liquid soap to 2% of the product. The most suitable oil for preparing liquid soaps from raw materials such as TFO, OFO, and IFO was the tail fat oil (TFO). The highest unsaturated fatty acid content in crude fats and oils was 41.23%, the highest content of saturated fatty acids was 22.3%, and the highest content of methyl-stearate was 33.65% by the GC-MS analytical method.展开更多
基金The research was supported by the National 863 Project of China(No.2001AA242041).
文摘Soap-free poly（methyl methacrylate-ethyl acrylate-methacrylic acid） latex particles with narrow size distribution were synthesized by seeded emulsion polymerization, and the porous particles were created by a stepwise alkali/acid treatment method. Effects of acid treatment conditions on the particle morphology were investigated. Results show that one to three pores were formed inside most of particles after post-treatment. At pH 7.0, when the treatment temperature was lower than 70℃, the size of particles and the volume of pores remained almost unchanged, and these two values increased significantly when the temperature was higher than 70℃. Both the particle size and the pore volume decreased with the increase of initial pH value and treatment time in the acid treatment. As the pH was below 4.0 and the treatment time was longer than 180 min, the particles shrunk in size.
文摘The aim of this study was to select sheep fat from Tsetserleg sum of Arkhangai aimag as raw material and to produce liquid soap. The oil was extracted from raw materials such as sheep’s tail fat (TF), outer fat (OF), and inner fat (IF), which were analyzed by chemical methods, and the liquid soap was obtained by cold methods. Liquid soap was prepared from three types of raw materials, each of which was mixed with 70% fat oil and 30% liquid oil. The ratio was chosen to dilute the liquid soap to 2% of the product. The most suitable oil for preparing liquid soaps from raw materials such as TFO, OFO, and IFO was the tail fat oil (TFO). The highest unsaturated fatty acid content in crude fats and oils was 41.23%, the highest content of saturated fatty acids was 22.3%, and the highest content of methyl-stearate was 33.65% by the GC-MS analytical method.
