Progress on Transition Metal Ions Dissolution Suppression Strategies in Prussian Blue Analogs for Aqueous Sodium-/Potassium-Ion Batteries

Aqueous sodium-ion batteries(ASIBs)and aqueous potassium-ion batteries(APIBs)present significant potential for large-scale energy storage due to their cost-effectiveness,safety,and environmental compatibility.Nonetheless,the intricate energy storage mechanisms in aqueous electrolytes place stringent require-ments on the host materials.Prussian blue analogs(PBAs),with their open three-dimensional framework and facile synthesis,stand out as leading candidates for aqueous energy storage.However,PBAs possess a swift capacity fade and limited cycle longevity,for their structural integrity is compromised by the pronounced dis-solution of transition metal(TM)ions in the aqueous milieu.This manuscript provides an exhaustive review of the recent advancements concerning PBAs in ASIBs and APIBs.The dissolution mechanisms of TM ions in PBAs,informed by their structural attributes and redox processes,are thoroughly examined.Moreover,this study delves into innovative design tactics to alleviate the dissolution issue of TM ions.In conclusion,the paper consolidates various strategies for suppressing the dissolution of TM ions in PBAs and posits avenues for prospective exploration of high-safety aqueous sodium-/potassium-ion batteries.

Experimental and computational optimization of Prussian blue analogues as high-performance cathodes for sodium-ion batteries:A review

In this review,we discuss the electrochemical properties of Prussian blue(PB)for Na^(+)storage by combining structural engineering and electrolyte modifications.We integrated experimental data and density functional theory(DFT)in sodium-ion battery(SIB)research to refine the atomic arrangements and crystal lattices and introduce substitutions and dopants.These changes affect the lattice stability,intercalation,electronic and ionic conductivities,and electrochemical performance.We unraveled the intricate structure-electrochemical behavior relationship by combining experimental data with computational models,including first-principles calculations.This holistic approach identified techniques for optimizing PB and Prussian blue analog(PBA)structu ral properties for SIBs.We also discuss the tuning of electrolytes by systematically adjusting their composition,concentration,and additives using a combination of molecular dynamics(MD)simulations and DFT computations.Our review offers a comprehensive assessment of strategies for enhancing the electrochemical properties of PB and PBAs through structural engineering and electrolyte modifications,combining experimental insights with advanced computational simulations,and paving the way for next-generation energy storage systems.

An Adaptive Control Strategy for Energy Storage Interface Converter Based on Analogous Virtual Synchronous Generator

In the DC microgrid,the lack of inertia and damping in power electronic converters results in poor stability of DC bus voltage and low inertia of the DC microgrid during fluctuations in load and photovoltaic power.To address this issue,the application of a virtual synchronous generator(VSG)in grid-connected inverters control is referenced and proposes a control strategy called the analogous virtual synchronous generator(AVSG)control strategy for the interface DC/DC converter of the battery in the microgrid.Besides,a flexible parameter adaptive control method is introduced to further enhance the inertial behavior of the AVSG control.Firstly,a theoretical analysis is conducted on the various components of the DC microgrid,the structure of analogous virtual synchronous generator,and the control structure’s main parameters related to the DC microgrid’s inertial behavior.Secondly,the voltage change rate tracking coefficient is introduced to adjust the change of the virtual capacitance and damping coefficient flexibility,which further strengthens the inertia trend of the DC microgrid.Additionally,a small-signal modeling approach is used to analyze the approximate range of the AVSG’s main parameters ensuring system stability.Finally,conduct a simulation analysis by building the model of the DC microgrid system with photovoltaic(PV)and battery energy storage(BES)in MATLAB/Simulink.Simulation results from different scenarios have verified that the AVSG control introduces fixed inertia and damping into the droop control of the battery,resulting in a certain level of inertia enhancement.Furthermore,the additional adaptive control strategy built upon the AVSG control provides better and flexible inertial support for the DC microgrid,further enhances the stability of the DC bus voltage,and has a more positive impact on the battery performance.

复杂企业网服务器端Analogy Factory设计模式

利用servlet良好的可扩展性 ,提出一种全新的Web服务器端设计模式———AnalogyFactory模式 ,将企业的业务逻辑从servlet中剥离 ,以独立的接口继承体系实现 ,并用动态加载方式获得其实例 ,可以在不重新编译服务器端控制逻辑的前提下更新功能 ,甚至加入新模块 ,从而适应企业复杂多变的网络环境和应用需求 .本设计模式运用于实际系统的开发 ,较好地解决了复杂网络的网络拥塞。

The tectonic fracture modeling of an ultra-low permeability sandstone reservoir based on an outcrop analogy: A case study in the Wangyao Oilfield of Ordos Basin, China

Due to inherent limits of data acquisition and geophysical data resolution, there are large uncertainties in the characterization of subsurface fractures. However, outcrop analogies can provide qualitative and quantitative information on a large number of fractures, based on which the accuracy of subsurface fracture characterization can be improved. Here we take the tectonic fracture modeling of an ultra-low permeability sandstone reservoir based on an outcrop analogy, a case study of the Chang6t~ Formation of the Upper Triassic Yanchang Group of the Wangyao Oilfield in the Ordos Basin of China. An outcrop at the edge of the basin is a suitable analog for the reservoir, but the prerequisite is that they must have equivalent previous stress fields, similar final structural characteristics, relative timing and an identical depositional environment and diagenesis. The relationship among fracture density, rock type and bed thickness based on the outcrop is one of the most important fracture distribution models, and can be used to interpret fracture density in individual wells quantitatively. Fracture orientation, dip, geometry and scale, also should be described and measured in the outcrop, and can be used together with structure restoration and single well fracture density interpretation to guide fracture intensity prediction on bed surfaces and to constrain the construction of the 3D fracture geometry model of the subsurface reservoir. The application of the above principles shows the outcrop-based tectonic fracture models of the target ultra-low permeability sandstone reservoir are consistent with fractures inferred from microseismic interpretation and tracer tests. This illustrated that the fracture modeling based on the outcrop analogy is reliable and can reduce the uncertainty in stochastic fracture modeling.

Immune Recognition Method Based on Analogy Reasoning in Intrusion Detection System

In this paper, we propose an analogy based immune recognition method that focuses on the implement of the clone selection process and the negative selection process by means of analogy similarity. This method is applied in an IDS （Intrusion Detection System） following several steps. Firstly, the initial abnormal behaviours sample set is optimized through the combining of the AIS （Artificial Immune System） and the genetic algorithm. Then, the abnormity probability algorithm is raised considering the two sides of abnormality and normality. Finally, an intrusion detection system model is established based on the above algorithms and models.

Surface integral analogy approaches for predicting noise from 3D high-lift low-noise wings

Three surface integral approaches of the acoustic analogies are studied to predict the noise from three concep- tual configurations of three-dimensional high-lift low-noise wings. The approaches refer to the Kirchhoff method, the Ffowcs Williams and Hawkings （FW-H） method of the permeable integral surface and the Curle method that is known as a special case of the FW-H method. The first two approaches are used to compute the noise generated by the core flow region where the energetic structures exist. The last approach is adopted to predict the noise specially from the pressure perturbation on the wall. A new way to con- struct the integral surface that encloses the core region is proposed for the first two methods. Considering the local properties of the flow around the complex object-the actual wing with high-lift devices-the integral surface based on the vorticity is constructed to follow the flow structures. The surface location is discussed for the Kirchhoff method and the FW-H method because a common surface is used for them. The noise from the core flow region is studied on the basis of the dependent integral quantities, which are indicated by the Kirchhoff formulation and by the FW-H formulation. The role of each wall component on noise contribution is analyzed using the Curle formulation. Effects of the volume integral terms of Lighthill＇s stress tensors on the noise pre-diction are then evaluated by comparing the results of the Curle method with the other two methods.

Design by Analogy:Achieving More Patentable Ideas from One Creative Design

A patent is a kind of technical document to protect intellectual property for individuals or enterprises. Patentable idea generation is a crucial step for patent application and analogy is confirmed to be an effective technique to inspire creative ideas. Analogy?based design usually starts from representation of an analogy source and is followed by the retrieval of appropriate analogs, mapping of design knowledge and adaptation of target solution. To diffuse one core idea into other new contexts and achieve more patentable ideas, this paper mainly centered on the first two stages of analogy?based design and proposed a patentable ideation framework. The analogical information of the source system, including source design problems and solution, was mined comprehensively through International Patent Classification analysis and represented in the form of function, behavior and structure. Three heuristics were suggested for searching the set of candidate target systems with a similar design problem, where the source design could be transferred. To systematize the process of source representation, analogs retrieval, idea transfer, and solution generation, an ideation model was put forward. Finally, the bladeless fan was selected as a source design to illustrate the application of this work. The design output shows that the representation and heuristics are beneficial, and this systematic ideation method can help the engineer or designer enhance creativity and discover more patentable opportunities.

Max-plus代数中analogy-transitive矩阵及其本征问题

定义一类analogy-transitive矩阵,讨论其基本性质,给出判定一个矩阵是否为analogytransitive矩阵的判定定理及算法,最后讨论关于analogy-transitive矩阵的本征问题.对于analogytransitive矩阵,存在一个O(n2)的算法计算其唯一本征值λ(A)和所有本征向量x=(x1,…,xn)使得max j=1,…,n(aij+xj)=λ+xi(i=1,…,n).该结果较一般情况下O(n3)的算法有所改进.

Modeling of the Earth’s Planetary Heat Balance with Electrical Circuit Analogy

The integral heat model for the system of the Earth’s surface—the atmosphere—the open space based on the electrical circuit analogy is presented. Mathematical models of the heat balance for this system are proposed. Heat circuit which is analog of the electrical circuit for investigating the temperature dependencies on the key parameters in the clear form is presented.

Evaluation of natural gas hydrate resources in the South China Sea using a new genetic analogy method

Natural gas hydrate(NGH)has attracted much attention as a new alternative energy globally.However,evaluations of global NGH resources in the past few decades have casted a decreasing trend,where the estimate as of today is less than one ten-thousandth of the estimate forty years ago.The NGH researches in China started relatively late,but achievements have been made in the South China Sea(SCS)in the past two decades.Thirty-five studies had been carried out to evaluate NGH resource,and results showed a flat trend,ranging from 60 to 90 billion tons of oil equivalent,which was 2-3 times of the evaluation results of technical recoverable oil and gas resources in the SCS.The big difference is that the previous 35 group of NGH resource evaluations for the SCS only refers to the prospective gas resource with low grade level and high uncertainty,which cannot be used to guide exploration or researches on development strategies.Based on the analogy with the genetic mechanism of conventional oil and gas resources,this study adopts the newly proposed genetic method and geological analogy method to evaluate the NGH resource.Results show that the conventional oil and gas resources are 346.29×10^(8)t,the volume of NGH and free dynamic field are 25.19×10^(4)km^(3) and(2.05-2.48)×10^(6)km^(3),and the total amount of in-situ NGH resources in the SCS is about(4.47-6.02)×10^(12)m^(3).It is considered that the resource of hydrate should not exceed that of conventional oil and gas,so it is 30 times lower than the previous estimate.This study provides a more reliable geological basis for further NGH exploration and development.

A CONCISE M-METRIC LEAST SQUARE FORMULA FOR POLYNOMIAL ANALOGY

An M-metric least square method for polynomial analogy is presented. The relative normal eqUation is of diagonal form, such that the concise solution formula is explicit, and it is suitable to Parallel computation. On the other hand, by error analysis of a typical example, we can see that the presented method is reliable.

Geological Analogy Expert System of Oil-Generating Depressions

The geologic analogy expert system of oil-generating depressions (GAESOD) constructed on IBM 386 by using GCLISP language is a tool-type expert system for geologic analogy .GAESOD consists of eight parts: (1) illustrating module of system; (2) general controlling module; (3) knowledge base; (4 (reasoning module; (5 )data base; (6)explanation module; (7)gaining and managing module of knowledge; (8) managing module of data base .There are 36 known models of oil-generating depressions of the eastern part and the continental shelf of China in the knowledge base .Three values,such as resemblance coefficient ,certainty factor and fine-poor coefficient ,will be acquired if this system is applied to any two on-generating depressions .Finally,GAESOD are applied to the analysis of some data from Xichang depression ,Hepu basin and the conclusions from this system are consistent with the results from geologic experts.

Calculation of Sound Ray’s Trajectories by the Method of Analogy to Mechanics at Ocean

In this paper, one of analogies available in the literature between movement of a material particle and ray propagation of a sound in liquid is used. By means of the equations of Hamilton describing movement of a material particle, analytical expression of a tangent to a trajectory of a sound ray at non-uniform ocean on depth is received. The received expression for a tangent differs from traditional one, defined under law Snelius. Calculation of trajectories, and also other characteristics of a sound field is carried out by two methods: first—traditional, under law Snelius, and second—by the analogy to mechanics method. Calculations are made for canonical type of the sound channel. In the region near to horizontal rays, both methods yield close results, and in the region of steep slope, the small distinction is observed.

Sludge Filtration Resistance Model Based on Electrical Resistance Analogy

In this study, a model for sludge filtration resistance (SFR) was developed using electrical resistance analogy by relating the rate at which water flows to the current of charge to determine Sludge Filtration Resistance using a typical single Electrical Resistance from a Direct Current Circuit. Synthetic sludge was successfully formulated for experimental purposes. The advantage of using synthetic sludge was that they permitted experiments to be performed on stable samples with known physical and chemical properties not subject to degradation by microbial activity. The result from the present study indicates the effect of conditioner on synthetic sludge filtration at variable pressure for sludge filtration resistance (SFR) and the trends in the results indicated that SFR reduces with increase in the concentration of dissolved salt (CaCl2). The linearity observed between plot of volume of filtrate versus time of filtration by correlation coefficient of R2 = 0.9292 (Figure 1) for 10 g of CaCl2 and R2 = 0.9294 (Figure 2) for 18 g of CaCl2. It is evident from the calculated values that they are very strong and have testified that the effect of conditioner on synthetic sludge filtration at variable pressure for sludge filtration resistance (SFR) using electrical resistance analogy is very satisfactory. When compared the existing data from SFR with other measure of filterability calculated using Carman’s equation to validate the model, it was observed that specific resistance decreases as the concentration of CaCl2 (dissolved salt) increases which agrees with SFR.

Use of Analogy by Public Health Nurses in Problem Solving for Individual Consultations in Japan: A Multiple Case Study

Aim: Nurses must develop good problem-solving skills (PSS) to work in the complex health care environment. This study explored PHNs’ use of analogy in PSS development. The purposes of the study were to clarify how PSS developed in one area (i.e., mental health) could be applied to another area (i.e., maternal health) and whether new PSS could develop in response to PSS gained in another area. Methods: A multiple case study was conducted using interviews. We interviewed 27 consultations from eight Japanese PHNs who consulted in mental health departments before transferring to maternal health departments. The data on how PHNs applied PSS in the selection, mapping, evaluation, and learning stages of the analogy process were extracted from transcribed interviewed data and compared. Results: PHNs provided 59 PSS used in 27 consultations. All PHNs applied past mental health PSS to solve new problems in maternal health. They tended to select past PSS based on structural similarity and to apply PSS via low-level abstraction in serious situations or preventively to avoid causing the current situation to worsen. Notably, PHNs developed maternal health PSS by using past mental health PSS;these new PSS were derived through analogy from various failures and successes. Conclusions: PSS developed in one area can be applied in another area, and new PSS can develop through applying these previous PSS. Identification of structural similarities and preventive analogies must be included in nursing education, especially for nurses working in public health fields.

The Continuous Analogy of Newton’s Method for Solving a System of Linear Algebraic Equations

We propose a continuous analogy of Newton’s method with inner iteration for solving a system of linear algebraic equations. Implementation of inner iterations is carried out in two ways. The former is to fix the number of inner iterations in advance. The latter is to use the inexact Newton method for solution of the linear system of equations that arises at each stage of outer iterations. We give some new choices of iteration parameter and of forcing term, that ensure the convergence of iterations. The performance and efficiency of the proposed iteration is illustrated by numerical examples that represent a wide range of typical systems.

Geometric Analogy and Products of Vectors in <i>n</i>Dimensions

The cross product in Euclidean space IR3 is an operation in which two vectors are associated to generate a third vector, also in space IR3. This product can be studied rewriting its basic equations in a matrix structure, more specifically in terms of determinants. Such a structure allows extending, for analogy, the ideas of the cross product for a type of the product of vectors in higher dimensions, through the systematic increase of the number of rows and columns in determinants that constitute the equations. So, in a n-dimensional space with Euclidean norm, we can associate n – 1 vectors and to obtain an n-th vector, with the same geometric characteristics of the product in three dimensions. This kind of operation is also a geometric interpretation of the product defined by Eckman [1]. The same analogies are also useful in the verification of algebraic properties of such products, based?on known properties of determinants.

Analogy Theory and Application of Pressure Difference of Wind Turbine Blade Profile

This paper aims to design an optimized blade for Horizontal Axis Wind Turbine(HWAT).Since airfoil is a basic component of blade design,an optimized airfoil(referred as SJX)was proposed based on the line theory through the weight analogy to pressure distribution of air flow.Its lift,drag,lift⁃to⁃drag ratio were compared with those NACA2409⁃34,NACA2410,and RK40 airfoils by using Profili software at fixed wind velocity and under different angles of attack.The NACA2409⁃34 airfoil was found to be greatly similar with the SJX airfoil.Based on the Wilson method,blades using SJX and NACA2490⁃34 airfoils were developed and different performance parameters such as velocity distribution,pressure distribution,and power were compared under variable wind velocities and different angles of attack ranging from-4°to 6°at different radius from the center of rotor using computational fluid dynamics(CFD)in ANSYS FLUENT.Results of the study suggested that the performance of the SJX based airfoil and blade was much more optimized.